Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy
A series of lanthanide metallocenium cations [Ln(Cpttt)2]+ (Ln = Y, Gd, Dy, Ho, Er, Tm, Yb, Lu; Cpttt = C5H2tBu3-1,2,4) were recently prepared, but curiously the Tb analogue was elusive. Here we access [Tb(Cpttt)2]+via an alternative strategy, completing the heavy [Ln(Cpttt)2]+ family.
1991 ◽
2018 ◽
Vol 13
(4)
◽
pp. 93-119
Keyword(s):
2021 ◽
Vol 57
(4)
◽
pp. 243-245