Isolation of two bis(silyl)nickel complexes with Si–Si bond formation in a single-crystal-to-single-crystal fashion

2019 ◽  
Vol 48 (10) ◽  
pp. 3433-3439 ◽  
Author(s):  
Sen-Yu Zhang ◽  
Jie Li ◽  
Sheng-Ze Zhao ◽  
Shi Wang ◽  
Min-Ming Lu ◽  
...  
Keyword(s):  
Single Crystal ◽  
Bond Formation ◽  
Nickel Complexes ◽  
New Si ◽  
Single Bonds

Two unique silyl nickel complexes that generate two new Si–Si single bonds have been prepared unprecedentedly, which exhibit reversible single-crystal-to-single-crystal transformations upon the removal and rebinding of the coordinating PEt3 molecule.

Reactions of Phenylhydrosilanes with Pincer–Nickel Complexes: Evidence for New Si–O and Si–C Bond Formation Pathways

2015 ◽  
Vol 137 (48) ◽  
pp. 15287-15298 ◽  
Author(s):  
Jingjun Hao ◽  
Boris Vabre ◽  
Davit Zargarian
Keyword(s):  
Bond Formation ◽  
Nickel Complexes ◽  
New Si

scholarly journals Nickel Complexes in C‒P Bond Formation

Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5283
Author(s):  
Almaz A. Zagidullin ◽  
Il’yas F. Sakhapov ◽  
Vasili A. Miluykov ◽  
Dmitry G. Yakhvarov
Keyword(s):  
Bond Formation ◽  
Nickel Complexes ◽  
Catalytic Reactions ◽  
Comprehensive Account ◽  
Phosphorus Chemistry

This review is a comprehensive account of reactions with the participation of nickel complexes that result in the formation of carbon–phosphorus (C‒P) bonds. The catalytic and non-catalytic reactions with the participation of nickel complexes as the catalysts and the reagents are described. The various classes of starting compounds and the products formed are discussed individually. The several putative mechanisms of the nickel catalysed reactions are also included, thereby providing insights into both the synthetic and the mechanistic aspects of this phosphorus chemistry.

scholarly journals Binuclear, High-Valent Nickel Complexes: Ni−Ni Bonds in Aryl-Halogen Bond Formation

2017 ◽  
Vol 129 (13) ◽  
pp. 3689-3693 ◽  
Author(s):  
Justin B. Diccianni ◽  
Chunhua Hu ◽  
Tianning Diao
Keyword(s):  
Halogen Bond ◽  
Bond Formation ◽  
Nickel Complexes ◽  
High Valent

scholarly journals Enantioselective CC Bond Formation as a Result of the Oriented Prochirality of an Achiral Aldehyde at the Single-Crystal Face upon Treatment with a Dialkyl Zinc Vapor

2011 ◽  
Vol 50 (30) ◽  
pp. 6796-6798 ◽  
Author(s):  
Tsuneomi Kawasaki ◽  
Sayaka Kamimura ◽  
Ai Amihara ◽  
Kenta Suzuki ◽  
Kenso Soai
Keyword(s):  
Single Crystal ◽  
Bond Formation ◽  
Zinc Vapor ◽  
Crystal Face

Synthese, Struktur und thermisches Verhalten von Thiophosphorsäuretriamid SP(NH2)3 [1] / Synthesis, Structure, and Thermal Behaviour of Phosphorothionic Triamide SP(ΝΗ2)3 [1]

1989 ◽  
Vol 44 (8) ◽  
pp. 942-945 ◽  
Author(s):  
Wolfgang Schnick
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Thermal Properties ◽  
Single Crystal ◽  
Melting Temperature ◽  
Intermolecular Hydrogen Bonding ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Ray Methods ◽  
Single Bonds

Phosphorothionic triamide SP(NH2)3 is obtained by slow addition of SPCl3 dissolved in dry CH2Cl2 to a satured solution of NH3 in CH2Cl2 at —50°C. Ammonium chloride is removed from the resulting precipitate by treatment with HNEt2 followed by extraction with CH2Cl2. Coarse crystalline SP(NH2)3 is obtained after recrystallization from dry methanol. The crystal structure of SP(NH2)3 has been determined by single crystal X-ray methods (Pbca; a = 922.3(1), b = 953.8(1), c = 1058.4(2) pm, Z = 8). In the crystals the molecules show non-crystallographic point symmetry C8. The P—S bond (195.4(1) pm) is slightly longer than in SPCl3. From P—N bond lengths of about 166 pm a significant electrostatic strengthening of the P—N single bonds is assumed. Weak intermolecular hydrogen bonding interactions (N —H · · · N ≥ 329.5 pm; N — H · · · S ≥ 348.3 pm) are observed.Investigation of thermal properties shows a melting temperature of 115°C for SP(NH2)3. According to combined DTA/TG and MS investigations above this temperature the compound decomposes by evolution of H2S and NH3 to yield amorphous phosphorus(V)nitride.

Isolation of Dinuclear (μ-Silylene)(silyl)nickel Complexes and Si−Si Bond Formation on a Dinuclear Nickel Framework

2001 ◽  
Vol 40 (1) ◽  
pp. 213-216 ◽  
Author(s):  
Shigeru Shimada ◽  
Maddali L. N. Rao ◽  
Teruyuki Hayashi ◽  
Masato Tanaka
Keyword(s):  
Bond Formation ◽  
Nickel Complexes

ONO pincer type Pd(ii) complexes: synthesis, crystal structure and catalytic activity towards C-2 arylation of quinoline scaffolds

RSC Advances ◽  
2015 ◽  
Vol 5 (95) ◽  
pp. 77948-77957 ◽  
Author(s):  
Vignesh Arumugam ◽  
Werner Kaminsky ◽  
Dharmaraj Nallasamy
Keyword(s):  
Crystal Structure ◽  
Catalytic Activity ◽  
Single Crystal ◽  
Bond Formation ◽  
Xrd Analysis ◽  
Single Crystal Xrd ◽  
Hydrazone Ligands ◽  
Single Crystal Xrd Analysis

Four new palladium(ii) complexes featuring ONO pincer type hydrazone ligands were synthesized and characterized by spectroscopic and single-crystal XRD analysis. Utility of these complexes to catalyze C–C bond formation in quinoline scaffolds were assessed.

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