Highly efficient electrochemical reduction of CO2 into formic acid over lead dioxide in an ionic liquid–catholyte mixture

2018 ◽  
Vol 20 (8) ◽  
pp. 1765-1769 ◽  
Author(s):  
Haoran Wu ◽  
Jinliang Song ◽  
Chao Xie ◽  
Yue Hu ◽  
Buxing Han
Keyword(s):  
Ionic Liquid ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Lead Dioxide ◽  
Highly Efficient ◽  
Reduction Of Co2

The combination of commercial lead dioxide and ionic liquid based catholytes showed highly efficient electrochemical reduction of CO2 into formic acid.

scholarly journals Highly efficient electrochemical reduction of CO2 to CH4 in an ionic liquid using a metal–organic framework cathode

2016 ◽  
Vol 7 (1) ◽  
pp. 266-273 ◽  
Author(s):  
Xinchen Kang ◽  
Qinggong Zhu ◽  
Xiaofu Sun ◽  
Jiayin Hu ◽  
Jianling Zhang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Electrochemical Reduction ◽  
Metal Organic Framework ◽  
Selective Reduction ◽  
Highly Efficient ◽  
Metal Organic ◽  
Reduction Of Co2 ◽  
Organic Framework

It has been discovered that Zn metal-organic framework (Zn-MOF) electrodes and ionic liquids are an excellent combination for the efficient and selective reduction of CO2 to CH4.

scholarly journals The inchoate horizon of electrolyzer designs, membranes and catalysts towards highly efficient electrochemical reduction of CO2 to formic acid

RSC Advances ◽  
2022 ◽  
Vol 12 (3) ◽  
pp. 1287-1309
Author(s):  
P. Senthilkumar ◽  
Mamata Mohapatra ◽  
Suddhasatwa Basu
Keyword(s):  
Formic Acid ◽  
Electrochemical Reduction ◽  
Energy Efficient ◽  
Highly Efficient ◽  
Recent Advances ◽  
Reduction Of Co2

This review explores the recent advances in CO2 reactor configurations, components, membranes and electrocatalysts for HCOOH generation and draw readers attention to construct the economic, scalable and energy efficient CO2R electrolyzers.

scholarly journals Structural Dynamics and Evolution of Bismuth Electrodes during Electrochemical Reduction of CO2 in Imidazolium-Based Ionic Liquid Solutions

ACS Catalysis ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 7285-7295 ◽  
Author(s):  
Jonnathan Medina-Ramos ◽  
Sang Soo Lee ◽  
Timothy T. Fister ◽  
Aude A. Hubaud ◽  
Robert L. Sacci ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Electrochemical Reduction ◽  
Structural Dynamics ◽  
Liquid Solutions ◽  
Reduction Of Co2 ◽  
Bismuth Electrodes

Continuous Semi-Micro Reactor Prototype for the Electrochemical Reduction of CO2 into Formic Acid

2020 ◽  
Vol 59 (5) ◽  
pp. 1737-1745 ◽  
Author(s):  
Rupam Sinha ◽  
Agam Bisht ◽  
Saptak Rarotra ◽  
Tapas K. Mandal
Keyword(s):  
Formic Acid ◽  
Electrochemical Reduction ◽  
Reduction Of Co2 ◽  
Micro Reactor

Principal Descriptors of Ionic Liquid Co-catalysts for the Electrochemical Reduction of CO2

2020 ◽  
Vol 3 (5) ◽  
pp. 4690-4698 ◽  
Author(s):  
Dmitry V. Vasilyev ◽  
Serhii Shyshkanov ◽  
Erfan Shirzadi ◽  
Sergey A. Katsyuba ◽  
Mohammad Khaja Nazeeruddin ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Electrochemical Reduction ◽  
Co Catalysts ◽  
Reduction Of Co2

scholarly journals Low-Overpotential Electrochemical Reduction of CO2 to Formic Acid on Surface-Modified Doped Tin Oxide Pellets

2019 ◽  
Author(s):  
Emmanuel Abdul ◽  
Jason Pitts ◽  
Deepak Rajput ◽  
Shankar Rananavare
Keyword(s):  
Formic Acid ◽  
Electrochemical Reduction ◽  
Current Density ◽  
Tin Oxide ◽  
Aqueous Media ◽  
Oxide Nanoparticles ◽  
Faradaic Efficiency ◽  
Electrode Potentials ◽  
Tin Oxide Nanoparticles ◽  
Reduction Of Co2

Gas sensors fabricated with antimony doped tin oxide (ATO) nanomaterials exhibit remarkable sensitivity for detecting oxidizing and reducing gases. This study highlights the enhanced selectivity and stability of the porous ATO nanomaterial electrode made for electrochemical reduction of CO2 in aqueous media. During electrochemical reduction, these electrodes prepared from compressed powders tend to crumble within a few hours in aqueous media. To overcome this electrode disintegration effect, we modified the surface of the doped tin-Oxide nanoparticles with Nafion and a dipodal silane (1,2-Bis(triethoxysilyl)ethane). The electrode characterization studies include Cyclic Voltammetry (CV), and Electrochemical Impedance Spectroscopy (EIS). Scanning electron microscopic investigation of electrode surface morphology and roughness before and after electrochemical CO2 reduction for derivatized and underivatized electrode revealed lower surface roughness for former than the latter.The derivatized electrodes allowed CO2 electrochemical reduction at low overpotentials and high current density without any electrode crumbling over more than 24 hours of continuous operation. Formate/formic acid and methanol were the major products of reduction at electrode potentials ranging from -0.4 to -1.0V vs. RHE in the CO2 saturated 0.1M KHCO3 electrolyte. Higher current density and Faradaic Efficiency of formic acid was observed when compared to planar tin electrode materials and tin oxide nanoparticles deposited on FTO glass.

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