Fabrication and Characterization of a Marine Wet Solar Cell with Titanium Dioxide and Copper Oxides Electrodes

One of the effective ways of utilizing marine environments is to generate energy, power, and hydrogen via the effect of photocatalysts in the seawater. Since the ocean is vast, we are able to use its large area, but the power generation system must be of low cost and have high durability against both force and corrosion. In order to meet those requirements, this study focuses on the fabrication of a novel marine wet solar cell composed of a titanium dioxide photoanode and a copper oxide photocathode. These electrodes were deposited on type 329J4L stainless steel, which possesses relative durability in marine environments. This study focuses on the characterization of the photocatalytic properties of electrodes in seawater. Low-cost manufacturing processes of screen-printing and vacuum vapor deposition were applied to produce the titanium dioxide and copper oxides electrodes, respectively. We investigated the photopotential of the electrodes, along with the electrochemical properties and cell voltage properties of the cell. X-ray diffraction spectroscopy (XRD) of the copper oxides electrode was analyzed in association with the loss of photocatalytic effect in the copper oxides electrode. Although the conversion efficiency of the wet cell was less than 1%, it showed promising potential for use in marine environments with low-cost production. Electrochemical impedance spectroscopy (EIS) of the cell was also conducted, from which impedance values regarding the electrical properties of electrodes and their interfaces of charge-transfer processes were obtained. This study focuses on the early phase of the marine wet solar cell, which should be further studied for long-term stability and in actual marine environmental applications.

The Use of Copper Oxides as Cross-Linking Substances for Chloroprene Rubber and Study of the Vulcanizates Properties. Part II. The Effect of Filler Type on the Properties of CR Products

The properties of rubber materials are dependent on the characteristics of the elastomer matrix, the filler type, the cross-linking agent, the number of ingredients, and their interactions. In the previous article, we showed that chloroprene rubber can be efficiently cross-linked with copper(I) oxide or copper(II) oxide. During the processing of rubber compounds, the incorporation of a filler and a curing substance are two substantial parameters, such as the homogeneity of mixing and cross-linking that significantly affect the properties of the vulcanizates. Therefore, this work aimed to evaluate the curing characteristics, mechanical and dynamical properties, morphology, and flammability of the composites containing chloroprene rubber cross-linked with Cu2O or CuO and filled with different fillers (silica, carbon black, montmorillonite, kaolin, chalk). It was found that the type of filler and curing agent had a significant impact on the degree of cross-linking of the chloroprene rubber and the properties of its vulcanizates. The degree and speed of the cross-linking of filled CR were higher when the CR was cured with copper(II) oxide. Among the fillers used, the presence of carbon black or silica ensured the highest degree of CR cross-linking and the most useful properties. The flammability tests indicated that all produced vulcanizates were characterized by a high oxygen index, which allows them to be classified as non-flammable materials.