A Zn based metal organic framework as a heterogeneous catalyst for C–C bond formation reactions

2019 ◽  
Vol 43 (9) ◽  
pp. 3793-3800 ◽  
Author(s):  
Kanagaraj Madasamy ◽  
Shanmugasundaram Kumaraguru ◽  
Velayutham Sankar ◽  
Subramaniyan Mannathan ◽  
Murugavel Kathiresan
Keyword(s):  
Heterogeneous Catalyst ◽  
Multicomponent Reaction ◽  
Knoevenagel Condensation ◽  
Metal Organic Framework ◽  
Bond Formation ◽  
Metal Organic ◽  
Organic Framework ◽  
Bond Formation Reactions

A Zn-Bp-BTC MOF was synthesized and characterized. The Zn-Bp-BTC MOF was successfully employed as a catalyst for Knoevenagel condensation, a multicomponent reaction and in benzimidazole synthesis.

scholarly journals Synthesis, Characterization and Catalytic Potency of Zn-based MOF for Knoevenagel Condensation Reaction

2021 ◽  
Vol 9 (11) ◽  
pp. 730-735
Author(s):  
Vaishali N. Rathod
Keyword(s):  
Heterogeneous Catalyst ◽  
Present Method ◽  
Solvothermal Method ◽  
Knoevenagel Condensation ◽  
Condensation Reaction ◽  
Metal Organic Framework ◽  
Short Reaction Time ◽  
Metal Organic ◽  
Knoevenagel Condensation Reaction ◽  
Organic Framework

Abstract: A Zn based metal organic framework with pyridine 2, 5-dicarboxylate (Zn-based MOF) were prepared as a reusable heterogeneous catalyst using solvothermal method. Zn-based MOF was used as heterogeneous catalyst for synthesis 5-arylidene malononitrile in ethanol under reflux condition. The attractive features of present method are mild reaction condition, short reaction time, simplicity, easy separation of catalyst and excellent yield. Keywords: Metal organic framework, heterogeneous catalyst, solvothermal method.

scholarly journals En Route to a Heterogeneous Catalytic Direct Peptide Bond Formation by Zr-Based Metal–Organic Framework Catalysts

ACS Catalysis ◽  
2021 ◽  
pp. 7647-7658
Author(s):  
Francisco de Azambuja ◽  
Alexandra Loosen ◽  
Dragan Conic ◽  
Maxime van den Besselaar ◽  
Jeremy N. Harvey ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Bond Formation ◽  
Peptide Bond ◽  
Peptide Bond Formation ◽  
Heterogeneous Catalytic ◽  
Metal Organic ◽  
Organic Framework

Synthesis and click modification of an azido-functionalized Zr(iv) metal–organic framework and a catalytic study

RSC Advances ◽  
2015 ◽  
Vol 5 (2) ◽  
pp. 893-900 ◽  
Author(s):  
Xiu-Chun Yi ◽  
Fu-Gui Xi ◽  
Yan Qi ◽  
En-Qing Gao
Keyword(s):  
Knoevenagel Condensation ◽  
Metal Organic Framework ◽  
Base Catalyst ◽  
Click Reactions ◽  
Metal Organic ◽  
Organic Framework

A new azido-functionalized Zr(iv) MOF was synthesized and further functionalized via post-synthetic click reactions, and the amino-tagged MOF is a base catalyst for Knoevenagel condensation.

A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.

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