Synthesis of poly(ionic liquid)-based nano-objects with morphological transitionsviaRAFT polymerization-induced self-assembly in ethanol

2018 ◽  
Vol 9 (7) ◽  
pp. 824-827 ◽  
Author(s):  
Yongqi Yang ◽  
Jinwen Zheng ◽  
Shoukuo Man ◽  
Xiaolan Sun ◽  
Zesheng An
Keyword(s):  
Ionic Liquid ◽  
Block Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Full Range ◽  
Poly Ionic Liquid

A full range of morphologies including spheres, worms and vesicles was observed in poly(ionic liquid)-based block copolymer nano-objectsviaethanolic dispersion polymerization.

Bulk self-assembly and ionic conductivity of a block copolymer containing an azobenzene-based liquid crystalline polymer and a poly(ionic liquid)

2017 ◽  
Vol 8 (10) ◽  
pp. 1689-1698 ◽  
Author(s):  
Yu-Dong Zhang ◽  
Jing Ping ◽  
Qi-Wei Wu ◽  
Hong-Bing Pan ◽  
Xing-He Fan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Block Copolymer ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
Self Assembly ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Poly Ionic Liquid

A block copolymer containing a liquid crystalline polymer and a poly(ionic liquid) self-assembles and can be used as a solid electrolyte.

All poly(ionic liquid) block copolymer nanoparticles from antagonistic isomeric macromolecular blocks via aqueous RAFT polymerization-induced self-assembly

2021 ◽  
Vol 12 (1) ◽  
pp. 82-91
Author(s):  
Jérémy Depoorter ◽  
Xibo Yan ◽  
Biao Zhang ◽  
Guillaume Sudre ◽  
Aurélia Charlot ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Block Copolymer ◽  
Self Assembly ◽  
Raft Polymerization ◽  
Building Blocks ◽  
Solution Behavior ◽  
Poly Ionic Liquid

All-poly(ionic liquid) block copolymer nanoparticles are prepared by aqueous RAFT PISA using a couple of isomeric ionic liquid monomers leading to macromolecular building blocks with antagonistic solution behavior in water.

Modular polymerized ionic liquid block copolymer membranes for CO2/N2 separation

2014 ◽  
Vol 2 (21) ◽  
pp. 7967-7972 ◽  
Author(s):  
Brian J. Adzima ◽  
Surendar R. Venna ◽  
Steven S. Klara ◽  
Hongkun He ◽  
Mingjiang Zhong ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Block Copolymer ◽  
Polymerized Ionic Liquid ◽  
Copolymer Poly ◽  
Poly Ionic Liquid

A robust and orthogonal approach to access modular block-copolymer poly(ionic liquid)s.

Aqueous Dispersion Polymerization: A New Paradigm for in Situ Block Copolymer Self-Assembly in Concentrated Solution

2011 ◽  
Vol 133 (39) ◽  
pp. 15707-15713 ◽  
Author(s):  
Shinji Sugihara ◽  
Adam Blanazs ◽  
Steven P. Armes ◽  
Anthony J. Ryan ◽  
Andrew L. Lewis
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Aqueous Dispersion ◽  
New Paradigm ◽  
Concentrated Solution

Preparation of poly(ionic liquid) composite particles and function modification with anion exchange

RSC Advances ◽  
2016 ◽  
Vol 6 (37) ◽  
pp. 31574-31579 ◽  
Author(s):  
Masayoshi Tokuda ◽  
Tatsunori Shindo ◽  
Toyoko Suzuki ◽  
Hideto Minami
Keyword(s):  
Ionic Liquid ◽  
Anion Exchange ◽  
Dispersion Polymerization ◽  
Composite Particles ◽  
Seeded Dispersion Polymerization ◽  
Poly Ionic Liquid ◽  
And Function ◽  
Property Modification

Detailed investigation on the synthesis of poly(ionic liquid) composite particles by seeded (dispersion) polymerization and property modification using anion exchange.

Reversible Colloidal Crystallization

MRS Advances ◽  
2020 ◽  
Vol 5 (40-41) ◽  
pp. 2111-2119
Author(s):  
Naveen Kuriakose ◽  
Pallavi Bapat ◽  
Harriet Lindsay ◽  
John Texter
Keyword(s):  
Ionic Liquid ◽  
Self Assembly ◽  
Interparticle Interactions ◽  
Colloidal Crystallization ◽  
Volume Production ◽  
Reversible Melting ◽  
Poly Ionic Liquid ◽  
Diffraction Effects ◽  
Thermal Melting ◽  
Multifunctional Polymers

AbstractWe report 3D colloidal self-assembly (crystallization) of poly(ionic liquid) latexes to produce crystals that exhibit reversible melting and recrystallization in water, due to “classical” interparticle interactions, typical of multifunctional polymers. These new materials are derived from an ionic liquid monomer that is polymerized at room temperature by redox-initiated polymerization. Particle synthesis, self-assembly, thermal properties, and introductory light diffraction effects are reported with a focus on melting. These crystals are distinguishable from classical colloidal crystalline arrays, and are the first such crystals to exhibit thermal melting. This new hydrogel offers promise for engineering large volume production of photonic crystals active in the visible and proximal spectral regions, by crystallization from suspension (solution), characteristic of most useful chemical compounds.

Microwave-assisted synthesis of block copolymer nanoparticles via RAFT with polymerization-induced self-assembly in methanol

2016 ◽  
Vol 7 (2) ◽  
pp. 297-301 ◽  
Author(s):  
Elden T. Garrett ◽  
Yiwen Pei ◽  
Andrew B. Lowe
Keyword(s):  
Block Copolymer ◽  
Comparative Study ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Microwave Assisted Synthesis ◽  
Conductive Heating ◽  
Microwave Assisted

A comparative study of microwave-assisted (MA) and conductive heating in RAFT dispersion polymerization formulations in MeOH that result in polymerization-induced self-assembly is detailed.

Synthesis of star thermoresponsive amphiphilic block copolymer nano-assemblies and the effect of topology on their thermoresponse

2019 ◽  
Vol 10 (3) ◽  
pp. 403-411 ◽  
Author(s):  
Mengjiao Cao ◽  
Huijun Nie ◽  
Yuwen Hou ◽  
Guang Han ◽  
Wangqing Zhang
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Amphiphilic Block Copolymer

Well-defined multi-arm star thermoresponsive block copolymer nano-assemblies of [poly(N-isopropylacrylamide)-block-polystyrene]n [(PNIPAM-b-PS)n] with n = 1, 2, 3 and 4 arms were synthesized by RAFT dispersion polymerization via polymerization-induced self-assembly.

Thin-Film Self-Assembly of Block Copolymers Containing an Azobenzene-Based Liquid Crystalline Polymer and a Poly(ionic liquid)

2020 ◽  
Vol 53 (21) ◽  
pp. 9619-9630
Author(s):  
Longfei Luo ◽  
Xiaolin Lyu ◽  
Zhehao Tang ◽  
Zhihao Shen ◽  
Xing-He Fan
Keyword(s):  
Thin Film ◽  
Ionic Liquid ◽  
Block Copolymers ◽  
Self Assembly ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Poly Ionic Liquid
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