Copper-catalyzed oxidative coupling of arylboronic acids with aryl carboxylic acids: Cu3(BTC)2 MOF as a sustainable catalyst to access aryl esters

2018 ◽  
Vol 5 (15) ◽  
pp. 2322-2331 ◽  
Author(s):  
Nainamalai Devarajan ◽  
Palaniswamy Suresh
Keyword(s):  
Carboxylic Acids ◽  
Oxidative Coupling ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction ◽  
Metal Organic ◽  
Commercially Important ◽  
Organic Framework

A straightforward and sustainable methodology for the synthesis of commercially important aryl esters via a C–O cross-coupling reaction was demonstrated using the Cu3(BTC)2 metal–organic framework.

A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites

2014 ◽  
Vol 50 (37) ◽  
pp. 4810-4812 ◽  
Author(s):  
Honghan Fei ◽  
Seth M. Cohen
Keyword(s):  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Cross Coupling Reaction ◽  
Metal Organic ◽  
Catalytic Metal ◽  
Organic Framework

A highly crystalline Zr(iv)-based metal–organic framework (MOF) containing open 2,2′-bipyridine (bpy) chelating sites has been realized using two synthetic strategies, and readily forms complexes with PdCl2 to produce a MOF that exhibits efficient and recyclable catalysis for the Suzuki–Miyaura cross-coupling reaction.

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