In this paper, the standard procedures for measuring moisture sorption properties of thin film form of polymer materials such as polyethylene terephthalate (PET) using thermo-gravimetry method and permeation method to characterize the moisture diffusion in polymer is presented. Analytical solution of moisture diffusion and FEA implementation using thermal-moisture analogy for comparison with measurements are presented, in which temperature dependent material properties are characterized. The measurement of permeability is used for validation of moisture diffusion characteristics. Nonlinear behavior of moisture diffusion dependent on concentration is investigated using a specimen having diffusion on half side and diffusivity constants are obtained by solving non-Fickian model and minimizing errors of least square with measurement. Application of characterizing moisture sorption properties to moisture effect on the interfacial layer in multi-layered printed circuit board (PCB) and estimation of relative humidity (RH) through permeation of moisture in hermetic sealing of crystal resonator are presented in this paper: i) The discrepancy of moisture concentration at the interlayer in multi-layered PCB was estimated as loading condition varies. ii) Moisture content through sealant based on temperature dependent permeability was estimated using mixture of ideal gases and vapor pressure.
Between single ion magnets and macromolecules: a polymer/transition metal-based semi-solid solution
