Transient photocurrents on catalyst-modified n-Si photoelectrodes: insight from dual-working electrode photoelectrochemistry

2018 ◽  
Vol 2 (9) ◽  
pp. 1995-2005 ◽  
Author(s):  
Forrest A. L. Laskowski ◽  
Jingjing Qiu ◽  
Michael R. Nellist ◽  
Sebastian Z. Oener ◽  
Adrian M. Gordon ◽  
...  
Keyword(s):  
Working Electrode ◽  
Oxidation Reduction ◽  
Catalyst Oxidation

Dual-working-electrode photoelectrochemistry experiments reveal how the most-prominent photocurrent transients are associated with catalyst oxidation/reduction.

Influence of complex formation on the attainment of equilibrium in some oxidation-reduction systems

1933 ◽  
Vol 5 ◽  
pp. 93-102 ◽  
Author(s):  
W. F. Jakób ◽  
M. R. Reżnar
Keyword(s):  
Complex Formation ◽  
Oxidation Reduction

New highly efficient coulometric cell with homogenous potential distribution on the working electrode

1986 ◽  
Vol 51 (3) ◽  
pp. 636-642
Author(s):  
Michal Németh ◽  
Ján Mocák
Keyword(s):  
Chemical Reactions ◽  
Potential Distribution ◽  
Anaerobic Conditions ◽  
Highly Efficient ◽  
Working Electrode ◽  
Constant Potential ◽  
Quantitative Analyses ◽  
Mechanism And Kinetics ◽  
Kinetics Of

A highly efficient coulometric cell was designed and constructed, ensuring a constant potential over the whole surface of the working electrode and suitable for very rapid electrolysis. It consists of concentric cylindrical Teflon parts; also the working and auxiliary electrodes are cylindrical and concentric. Electrolysis can be carried out under anaerobic conditions. Functioning of the cell was tested on the oxidation of hexacyanoferrate(II) and chlorpromazine and reduction of hexacyanoferrate(III). The new cell is suitable for routine quantitative analyses and in studying the mechanism and kinetics of moderately rapid chemical reactions.

Solvation and redox properties of [Co(en)3]3+-[Co(en)3]2+ system

1980 ◽  
Vol 45 (2) ◽  
pp. 335-338 ◽  
Author(s):  
Adéla Kotočová ◽  
Ulrich Mayer
Keyword(s):  
Hydrogen Bond ◽  
Lewis Acid ◽  
Specific Interaction ◽  
Redox Properties ◽  
Solvation Effect ◽  
Interacting Particles ◽  
Acid Base ◽  
Polar Solvents ◽  
Oxidation Reduction ◽  
Solvent Molecules

The solvation effect of a number of nonaqueous polar solvents was studied on the oxidation-reduction properties of the [Co(en)3]3+-[Co(en)3]2+ system. Interactions of these ions with the solvent molecules are discussed in terms of their coordination, which is accompanied by a specific interaction of the Lewis acid-base type, namely formation of a hydrogen bond between the interacting particles. This is the main controlling factor of the redox properties of the studied system.

Dynamics of Electrodiffusion Friction Probes. I. Shape-Dependent Potentiostatic Transient

1997 ◽  
Vol 62 (3) ◽  
pp. 397-419 ◽  
Author(s):  
Ondřej Wein ◽  
Václav Sobolík
Keyword(s):  
Simple Formula ◽  
Flow Direction ◽  
Voltage Step ◽  
Convex Shape ◽  
Exact Theory ◽  
Working Electrode ◽  
Arbitrary Convex

An exact theory is given of the voltage-step transient under limiting diffusion conditions for an electrodiffusion friction probe of arbitrary convex shape. The actual transient courses are given for the strip, circular, elliptic, triangular, and rectangular probes of any orientation with respect to the flow direction. A simple formula for any probe with a single working electrode of convex shape is suggested to facilitate the calibration of electrodiffusion probes based on the voltage-step transient.

Feedback Controlled Chemical Reactor with Feed of Two Reaction Components with Spectrophotometric Indication

1994 ◽  
Vol 59 (3) ◽  
pp. 549-557
Author(s):  
František Skopal ◽  
Václav Dušek
Keyword(s):  
Sulfuric Acid ◽  
Negative Feedback ◽  
Chemical Reactor ◽  
Reduction Reactions ◽  
Oxidation Reduction

Theoretical relationships and simplifying conditions have been derived for the feed of two reaction components into a nonisochoric reactor with ideal stirring. The feed of reaction components is controlled by the negative feedback at a constant absorbance of the reaction mixture. The theoretical relationships have been verified using model 2. order oxidation-reduction reactions of Ce(IV)/V(IV) and Fe(III)/V(III) in 1 M sulfuric acid at 20 °C.

The voltammetric determination of 4-nitrobiphenyl

1991 ◽  
Vol 56 (3) ◽  
pp. 595-601 ◽  
Author(s):  
Jiří Barek ◽  
Gulamustafa Malik ◽  
Jiří Zima
Keyword(s):  
Differential Pulse Voltammetry ◽  
Differential Pulse ◽  
Voltammetric Determination ◽  
Hanging Mercury Drop Electrode ◽  
Optimum Conditions ◽  
Mercury Drop Electrode ◽  
Working Electrode ◽  
Pulse Voltammetry ◽  
Unstirred Solution

Optimum conditions were found for the determination of 4-nitrobiphenyl by fast scan differential pulse voltammetry at a hanging mercury drop electrode in the concentration range 1 . 10-5 to 2 . 10-7 mol l-1. A further increase in sensitivity was attained by adsorptive accumulation of this substance on the surface of the working electrode, permitting determination in the concentration range (2 – 10) . 10-8 mol l-1 with one minute accumulation of the substance in unstirred solution or (2 – 10) . 10-9 mol l-1 with three-minute accumulation in stirred solution. Linear scan voltammetry can be used to determine 4-nitrobiphenyl in the concentration range (2 – 10) . 10-9 mol l-1 with five-minute accumulation in stirred solution, with the advantage of a smoother baseline and smaller interference from substances that yield only tensametric peaks.

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