Reversing C2H2–CO2 adsorption selectivity in an ultramicroporous metal–organic framework platform

2019 ◽  
Vol 55 (76) ◽  
pp. 11354-11357 ◽  
Author(s):  
Hui-Min Wen ◽  
Caijun Liao ◽  
Libo Li ◽  
Ling Yang ◽  
Jing Wang ◽  
...  
Keyword(s):  
Binding Sites ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Fine Tuning ◽  
Adsorption Selectivity ◽  
Pore Sizes ◽  
Metal Organic ◽  
Co2 Adsorption Selectivity ◽  
At Will ◽  
Organic Framework

Fine-tuning the pore sizes, metrics, and binding sites within a MOF platform can reverse the adsorption selectivity between C2H2 and CO2 at will.

Three metal–organic framework isomers of different pore sizes for selective CO2 adsorption and isomerization studies

2020 ◽  
Vol 49 (17) ◽  
pp. 5618-5624
Author(s):  
Rui Zhang ◽  
Ju-Hua Huang ◽  
De-Xian Meng ◽  
Fa-Yuan Ge ◽  
Li-Fei Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Selectivity ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Pore Sizes ◽  
Metal Organic ◽  
Organic Framework

Three MOF isomers including framework-catenation and framework-topological isomers were synthesized for adsorbing carbon dioxide with high selectivity.

A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO2 adsorption properties

RSC Advances ◽  
2015 ◽  
Vol 5 (31) ◽  
pp. 24655-24660 ◽  
Author(s):  
Rong-Ying Chen ◽  
Dan Tian ◽  
Yun-Wu Li ◽  
Ying-Bin Lv ◽  
Hong-Wei Sun ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Metal Organic ◽  
Tunable Emission ◽  
Organic Framework

A 3D porous anionic MOF (1), decorated with -NH2 and N sites, can serve as a host for the encapsulation of lanthanide(iii) cations for emission tuning. Besides, it also shows high adsorption selectivity for CO2 over CH4 and N2 at 273 K.

Selective CO2 adsorption in a microporous metal–organic framework with suitable pore sizes and open metal sites

2015 ◽  
Vol 2 (6) ◽  
pp. 550-557 ◽  
Author(s):  
Bo Liu ◽  
Ya-Hui Jiang ◽  
Zhi-Sen Li ◽  
Lei Hou ◽  
Yao-Yu Wang
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Porous System ◽  
Uptake Capacity ◽  
Pore Sizes ◽  
Open Metal Sites ◽  
Metal Organic ◽  
High Polarity ◽  
Organic Framework

A new microporous framework was constructed from uncommon ternary SBUs with a rare (5,5,5)-connected topology, which contains pores of suitable sizes and a high polarity porous system, exhibits a higher uptake capacity for CO2 and is highly selective for CO2 over N2 and CH4 gases.

Predictive models of gas sorption in a metal–organic framework with open-metal sites and small pore sizes

2017 ◽  
Vol 19 (28) ◽  
pp. 18587-18602 ◽  
Author(s):  
Tony Pham ◽  
Katherine A. Forrest ◽  
Douglas M. Franz ◽  
Zhiyong Guo ◽  
Banglin Chen ◽  
...  
Keyword(s):  
Predictive Models ◽  
Binding Sites ◽  
Metal Organic Framework ◽  
Gas Sorption ◽  
Pore Sizes ◽  
Small Pore ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

Simulations of gas sorption in UTSA-20 using highly accurate polarizable potentials reproduced experimental observables and provided insights into the binding sites in the material.

Selective CO2 Adsorption By Methyl-Functionalized Metal-Organic Framework

2017 ◽  
Vol 2 (26) ◽  
pp. 7821-7826 ◽  
Author(s):  
Deyun Ma ◽  
Zhi Li ◽  
Fei Jiang ◽  
Yanhua Ma ◽  
Wanchun Lin ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A Luminescent Microporous Metal–Organic Framework with Highly Selective CO2 Adsorption and Sensing of Nitro Explosives

2014 ◽  
Vol 53 (18) ◽  
pp. 9457-9459 ◽  
Author(s):  
Yun-Nan Gong ◽  
Yong-Liang Huang ◽  
Long Jiang ◽  
Tong-Bu Lu
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Nitro Explosives ◽  
Metal Organic ◽  
Organic Framework
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