Printed Nanocarbon Heaters for Stretchable Sport and Leisure Garments

The ability to maintain body temperature has been shown to bring about improvements in sporting performance. However, current solutions are limited with regards to flexibility, heating uniformity and robustness. An innovative screen-printed Nanocarbon heater is demonstrated which is robust to bending, folding, tensile extensions of up to 20% and machine washing. This combination of ink and substrate enables the heated garments to safely flex without impeding the wearer. It is capable of producing uniform heating over a 15 × 4 cm area using a conductive ink based on a blend of Graphite Nanoplatelets and Carbon Black. This can be attributed to the low roughness of the conductive carbon coating, the uniform distribution and good interconnection of the carbon particles. The heaters have a low thermal inertia, producing a rapid temperature response at low voltages, reaching equilibrium temperatures within 120 s of being switched on. The heaters reached the 40 °C required for wearable heating applications within 20 s at 12 Volts. Screen printing was demonstrated to be an effective method of controlling the printed layer thickness with good interlayer adhesion and contact for multiple printed layers. This can be used to regulate their electrical properties and hence adjust the heater performance.

Low Temperature Delays Metabolism of Quizalofop in Resistant Winter Wheat and Three Annual Grass Weed Species

Quizalofop-resistant wheat is the core component of the recently commercialized CoAXium™ Wheat Production System. As with other herbicides, quizalofop provides better weed control at early growth stages and under optimum temperature. However, in regions with winter wheat production, quizalofop application may be affected by unpredictable, rapid temperature decreases. Temperature shifts can cause crop injury or impact weed control efficacy. In the following study, we examine the effect of reduced temperature on quizalofop content and metabolism in CoAXium™ winter wheat and three winter weed species: downy brome (Bromus tectorum L.), feral rye (Secale cereale L.), and jointed goatgrass (Aegilops cylindrica Host). Temperature conditions include either 19 or 4.5°C daytime temperatures with tissue sampling over 5 timepoints (1–16 or 18 days after treatment, DAT). Analysis features liquid chromatography coupled to tandem mass spectrometry detection of the active form of quizalofop, quizalofop acid. Quizalofop content trends reveal delayed metabolism under cooler conditions for wheat and weeds. Quizalofop content peaks within 1–2 DAT in the warmer temperatures for all species and decreases thereafter. In contrast, content peaks between 8 and 9 DAT at cooler temperatures except for downy brome. Minimal decreases in content over time generally follow cooler temperature peaks. Further, the absence of differences in maximum quizalofop content in all species suggests absorption and/or de-esterification of quizalofop proherbicide to the active form is not reduced at cooler temperatures. Final dry shoot tissue biomass does not necessarily correspond to differences in metabolism, as biomass of wheat treated with a field rate of quizalofop does not differ between temperatures. Weeds were treated with sublethal doses of quizalofop in order to monitor herbicide metabolism without causing plant death. Under this condition, weed biomass only differs for jointed goatgrass, which has a greater biomass in the cooler temperature.

Major population splits coincide with episodes of rapid climate change in a forest-dependent bird

Climate change influences population demography by altering patterns of gene flow and reproductive isolation. Direct mutation rates offer the possibility for accurate dating on the within-species level but are currently only available for a handful of vertebrate species. Here, we use the first directly estimated mutation rate in birds to study the evolutionary history of pied flycatchers ( Ficedula hypoleuca ). Using a combination of demographic inference and species distribution modelling, we show that all major population splits in this forest-dependent system occurred during periods of increased climate instability and rapid global temperature change. We show that the divergent Spanish subspecies originated during the Eemian–Weichselian transition 115–104 thousand years ago (kya), and not during the last glacial maximum (26.5–19 kya), as previously suggested. The magnitude and rates of climate change during the glacial–interglacial transitions that preceded population splits in pied flycatchers were similar to, or exceeded, those predicted to occur in the course of the current, human-induced climate crisis. As such, our results provide a timely reminder of the strong impact that episodes of climate instability and rapid temperature changes can have on species' evolutionary trajectories, with important implications for the natural world in the Anthropocene.

A Preliminary Numerical Investigation of Thermal Mixing Efficiency in T-Junctions with Different Flow Configurations

When hot and cold fluids flow through a converging T-junction, rapid temperature fluctuations occur in the mixing region due to the thermal mixing of fluids. This temperature fluctuation causes thermal fatigue, which is responsible for the shortening of service life in a T-junction. Hence, the design of T-junction for thermal mixing requires not only superior mixing performance but minimize thermal fluctuation during mixing is also desirable. The objective of the present paper is to determine the thermal mixing performance at the mixing region of T-junction with two different flow configurations. Water, at different inlet temperatures, is used as a working medium and is assumed incompressible. Two types of flow configurations, namely intersecting and colliding regular T-junction with a sidearm pointing at 12 o’clock position have been evaluated in this paper. Realizable k-epsilon turbulence model was assumed, and its validity benchmarked against RANS and RSM-EB turbulence models. The thermal mixing efficiency of both flow configurations is calculated and compared. The results show that the thermal mixing efficiency of both intersecting and colliding mixing tee increases with the increase of distance and time. Intersecting tee shows higher temperature fluctuation than colliding tee at the mixing outlet, but colliding tee shows higher thermal mixing efficiency than intersecting mixing tee.

A Novel Approach to the Facile Growth and Organization of Photothermal Prussian Blue Nanocrystals on Different Surfaces

We report here a novel “one-pot” approach for the controlled growth and organization of Prussian blue nanostructures on three different surfaces: pure Au0, cysteamine-functionalized Au0, and SiO2-supported lipid bilayers with different natures of lipids. We demonstrate that fine control over the size, morphology, and the degree and homogeneity of the surface coverage by Prussian Blue (PB) nanostructures may be achieved by manipulating different parameters, which are the precursor concentration, the nature of the functional groups or the nature of lipids on the surfaces. This allows the growth of isolated PB nanopyramids and nanocubes or the design of thin dense films over centimeter square surfaces. The formation of unusual Prussian blue nanopyramids is discussed. Finally, we demonstrate, by using experimental techniques and theoretical modeling, that PB nanoparticles deposited on the gold surface exhibit strong photothermal properties, permitting a rapid temperature increase up to 90 °C with a conversion of the laser power of almost 50% for power source heat.

The Effect of TiN and DLC Anti-Wear Coatings on the Tribofilm Formation and Frictional Heat Phenomena in Coated Metals vs. WC-Co

The aim of this work was to study the effect of anti-wear coatings on the selected frictional phenomena, i.a., frictional heating and tribofilm formation, of model tribological pairs. For this purpose, three popular metallic substrate materials were selected: AISI 316L and AISI 440B stainless steels, as well as Ti6Al4V two-phase titanium alloy. The substrates were tested in the dry sliding conditions in three states: uncoated, as well as titanium nitride (TiN) or diamond-like-carbon (DLC) coated. According to the results provided, under applied frictional conditions TiN coating, even if it is worn off the sample surface, contributes to excessive frictional heating of a tribological pair by altering the tribofilm formation. The analysis also showed that in some tribological pairs, rapid temperature alteration of a counter sample can be used to approximate the sliding distance after which the TiN coating becomes worn off. On the contrary, in all pairs tested, the DLC film became locally damaged, but it sustained its antifriction properties, contributing to low coefficients of friction (COFs) and the lowest frictional temperatures observed.

Assessing the Risks of Vessel Icing and Aviation Hazards during Downslope Windstorms in the Russian Arctic

Downslope windstorms are known sources of hazardous weather, such as severe gusty winds, rapid temperature changes, ship icing, strong turbulence and others, posing a great danger to people and infrastructure. This paper investigates the risks of ship icing and aviation hazards (rapid changes in the angle of attack and gust load factor) during downslope windstorms in five regions in the Russian Arctic based on observational data, reanalysis, and mesoscale numerical modeling. The highest frequency of ship icing was found during downslope windstorms downstream from Svalbard and Novaya Zemlya. Icing is rare during Tiksi and Wrangel Island downslope windstorms due to almost permanent sea ice cover during the cold season, while icing is absent during very warm Pevek downslope windstorm even in the ice-free conditions. Conditions for heavy icing are rather frequent (up to 5% of cases in winter) during Novaya Zemlya downslope windstorms and less frequent (up to 0.5% in spring) during Svalbard windstorm. The presence of downslope windstorms in those regions causes an increase in the maximum icing rate by about 2 times. Strong aviation turbulence hazardous for light aircraft is typical for all considered regions with downslope windstorms; it is observed mainly at an altitude of 1 to 4 km above the surface. Hazardous turbulence for jet aircraft like Boeing 737 on its cruising flight levels was found on Svalbard and in Tiksi region in 10–15% of cases during strong downslope windstorms.

Eolian sedimentation in central European Auel dry maar from 60 to 13 ka

The climate in central Europe during the last 60 ka is characterized by rapid temperature and moisture changes and strong cold periods (Heinrich events). All these variations are preserved in sediments of marine and also some terrestrial archives. Here we present a continuous, terrestrial sediment record with almost all Greenland stadials and Heinrich events between 60 and 13 ka visible from carbonate roundness of the Eifel Laminated Sediment Archive Dust Stack-20 and CaCO3 data for central Europe. The carbonate roundness data show almost all stadials between 60 and 13 ka. CaCO3 data show a general transport system change with the beginning of Heinrich event 3. Since there are no carbonates west of the Auel Maar, we conclude that the eolian-transported grains were not transported by westerly but easterly winds. These postulated easterly winds during the last glacial maximum are supported by similar findings of previous works.