Optically active triptycenes containing hexa-peri-hexabenzocoronene units

2019 ◽  
Vol 55 (76) ◽  
pp. 11386-11389 ◽  
Author(s):  
Yuya Wada ◽  
Ken-ichi Shinohara ◽  
Tomoyuki Ikai

We have successfully generated both left- and right-handed circularly polarized light using crystals prepared from a racemic triptycene containing hexa-peri-hexabenzocoronene units.

2011 ◽  
Vol 47 (13) ◽  
pp. 3799 ◽  
Author(s):  
Juin-Meng Yu ◽  
Takeshi Sakamoto ◽  
Kento Watanabe ◽  
Seiichi Furumi ◽  
Nobuyuki Tamaoki ◽  
...  

2016 ◽  
Vol 16 (4) ◽  
pp. 3394-3397 ◽  
Author(s):  
Takaaki Manaka ◽  
Mitsumasa Iwamoto

Asymmetric polymerization of polydiacetylene (PDA) from commercially available achiral derivative of diacetylene monomer using circularly polarized pulse laser is demonstrated. Chiral source was only circularly polarized laser, and irradiation of left- and right-circularly polarized light effectively promoted the polymerization of chiral PDAs with opposite handedness. Difference between the laser wavelength and the absorption peak of monomer suggested the contribution of the multiphoton excitation to the photo-polymerization. Laser power dependence of the polymerization rate indicated the possibility of three-photon polymerization.


1971 ◽  
Vol 93 (9) ◽  
pp. 2353-2354 ◽  
Author(s):  
Henri Kagan ◽  
A. Moradpour ◽  
J. F. Nicoud ◽  
Gilbert Balavoine ◽  
G. Tsoucaris

2008 ◽  
Vol 4 (S251) ◽  
pp. 311-312 ◽  
Author(s):  
V. Rosenbush ◽  
N. Kiselev ◽  
L. Kolokolova

AbstractPolarimetric observations demonstrated that all comets with significant values of circular polarization show predominantly left–handed circularly polarized light. We discuss the presence of homochiral organics in cometary materials as a source of the observed circular polarization. We have studied the effect of chirality on light–scattering properties of cometary dust considering particles that possess optical activity. Our investigations show that the cometary dust may include optically active materials which can be prebiological homochiral organics.


Soft Matter ◽  
2015 ◽  
Vol 11 (39) ◽  
pp. 7802-7808 ◽  
Author(s):  
I. Nys ◽  
J. Beeckman ◽  
K. Neyts

A planar liquid crystal (LC) cell is developed in which two photo-alignment layers have been illuminated with respectively a horizontal and a vertical diffraction pattern of interfering left- and right-handed circularly polarized light.


2021 ◽  
Author(s):  
Yuting Wang ◽  
Koji Yazawa ◽  
Qingyu Wang ◽  
Takunori Harada ◽  
Shuhei SHIMODA ◽  
...  

Axial chirality was induced by circularly polarized light (CPL) irradiation to insoluble polymeric covalent organic frameworks (COF’s) as well as soluble hyperbranched polymers (HBP’s) composed of bezene-1,3,5-triyl groups as trigonal...


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