Poly(arylene ether sulfone) crosslinked networks with pillar[5]arene units grafted by multiple long-chain quaternary ammonium salts for anion exchange membranes

2020 ◽  
Vol 56 (6) ◽  
pp. 928-931 ◽  
Author(s):  
Jinwu Peng ◽  
Minhui Liang ◽  
Zhenchao Liu ◽  
Peng Wang ◽  
Chengying Shi ◽  
...  

For the first time, high-molecular-weight pillar[5]arene-containing aromatic polymers were synthesized and further modified for application as anion exchange membranes.

2018 ◽  
Vol 64 (2) ◽  
pp. 165-171 ◽  
Author(s):  
Fei Xu ◽  
Wensen Yuan ◽  
Yuanyuan Zhu ◽  
Xufeng Chu ◽  
Bencai Lin ◽  
...  

Polymer ◽  
2017 ◽  
Vol 121 ◽  
pp. 137-148 ◽  
Author(s):  
Qian Shi ◽  
Pei Chen ◽  
Xueliang Zhang ◽  
Qiang Weng ◽  
Xinbing Chen ◽  
...  

1966 ◽  
Vol 55 (2) ◽  
pp. 187-191 ◽  
Author(s):  
Norman D. Weiner ◽  
Helio C. Parreira ◽  
George Zografi

2019 ◽  
Vol 44 (48) ◽  
pp. 26565-26576 ◽  
Author(s):  
Chenxiao Lin ◽  
Demei Yu ◽  
Jixia Wang ◽  
Yan Zhang ◽  
Dong Xie ◽  
...  

2021 ◽  
Author(s):  
Roel Kleijwegt ◽  
Wyatt Winkenwerder ◽  
Wim Baan ◽  
John van der Schaaf

<div>Surfactants such as quaternary ammonium salts (QAS) have been in increasing demand, for emerging new applications. Recent attempts at process intensification of</div><div>their production, have disclosed the need for a better understanding of QAS thermal stability. This work aims to determine degradation kinetics of various QASs, and the</div><div>associated solvent effects. Degradation kinetics of four methyl carbonate QASs were determined in various</div><div>polar solvents in stainless steel batch autoclaves. <sup>1</sup>H NMR spectrometry was employed for online analysis of the reaction mixtures. The kinetic parameters were then used</div><div>to compare the thermal stability of the four compounds in the polar solvents. Water showed not degradation, and methanol (MeOH) was the solvent that provided the</div><div>second-best stability. Water-MeOH mixtures may provide an overall optimum. More, and longer long-chain substituents increased the degradation rate. Thermogravimetric Analysis was used to obtain the thermal stability in a solid-</div><div>state, i.e. solventless environment. Isoconversional analysis showed that no reliable kinetic parameters could be determined. Nevertheless, the data did allow for a compar-</div><div>ison of the thermal stability of 14 different QASs. Furthermore, the relative instability of the compounds in solid-state demonstrated the challenges of solventless QAS production.</div>


1985 ◽  
Vol 85 ◽  
pp. 147-150 ◽  
Author(s):  
G. Margomenou-Leonidopoulou ◽  
A. Malliaris ◽  
C.M. Paleos

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