Direct enantioselective Mannich reactions of α-azido cyclic ketones: asymmetric construction of chiral azides possessing an α-quaternary stereocenter
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Herein, we report the asymmetric synthesis of chiral azides possessing an α-quaternary stereocenter via chiral phosphoric acid catalysed direct enantioselective Mannich reactions of α-azido cyclic ketones with aldimines.
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2018 ◽
Vol 16
(8)
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pp. 1367-1374
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2019 ◽
Vol 60
(18)
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pp. 1262-1264
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2020 ◽
Vol 59
(6)
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pp. 2333-2337
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