scholarly journals Stabilized open metal sites in bimetallic metal–organic framework catalysts for hydrogen production from alcohols

2021 ◽  
Author(s):  
Jonathan L. Snider ◽  
Ji Su ◽  
Pragya Verma ◽  
Farid El Gabaly ◽  
Joshua D. Sugar ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Metal Organic Framework ◽  
Metal Site ◽  
Highly Active ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Alcohol Dehydrogenation ◽  
Organic Framework

Bimetallic (NixMg1−x)-MOF-74 stabilizes Ni2+ open metal site relative to Ni-MOF-74, resulting in a highly active and selective alcohol dehydrogenation catalyst.

Open metal site (OMS) and Lewis basic site (LBS)-functionalized copper–organic framework with high CO2 uptake performance and highly selective CO2/N2 and CO2/CH4 separation

CrystEngComm ◽  
2020 ◽  
Vol 22 (19) ◽  
pp. 3378-3384 ◽  
Author(s):  
Cheng He ◽  
Chao Hou ◽  
Yu Min Wang ◽  
Xue Yong Gong ◽  
Hong Li Jiang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Basic Site ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Site ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Excellent Selectivity ◽  
Organic Framework

A robust porous metal–organic framework with dual functionalities of open metal sites (OMSs) and O-rich Lewis basic sites (LBSs) has been designed and synthesized, and shows high CO2 uptake and excellent selectivity for CO2 over N2 and CH4.

scholarly journals Stabilized Open Metal Sites in Bimetallic Metal-Organic Framework Catalysts for Hydrogen Production from Alcohols.

2020 ◽  
Author(s):  
Jonathan Snider ◽  
Ji Su ◽  
Pragya Verma ◽  
Farid El Gabaly Marquez ◽  
Joshua Sugar ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Metal Organic Framework ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal–Organic Framework for Highly Selective Gas Adsorption

2012 ◽  
Vol 51 (9) ◽  
pp. 4947-4953 ◽  
Author(s):  
Zhangjing Zhang ◽  
Shengchang Xiang ◽  
Kunlun Hong ◽  
Madhab, C. Das ◽  
Hadi D. Arman ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Mixed Metal ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.

Efficient hydrogen production and photocatalytic reduction of nitrobenzene over a visible-light-responsive metal–organic framework photocatalyst

2013 ◽  
Vol 3 (8) ◽  
pp. 2092 ◽  
Author(s):  
Takashi Toyao ◽  
Masakazu Saito ◽  
Yu Horiuchi ◽  
Katsunori Mochizuki ◽  
Masatoshi Iwata ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Visible Light ◽  
Metal Organic Framework ◽  
Photocatalytic Reduction ◽  
Metal Organic ◽  
Organic Framework

ZIF-8-derived carbon modified g-C3N4 heterostructure with enhanced photocatalytic activity for dyes degradation and hydrogen production

2021 ◽  
Author(s):  
Xin Chang ◽  
Ye Wang ◽  
Xuejiao Zhou ◽  
Yi Song ◽  
Mingyi Zhang
Keyword(s):  
Photocatalytic Activity ◽  
Hydrogen Production ◽  
Metal Organic Framework ◽  
Nitrogen Doped ◽  
Pyrolysis Method ◽  
Metal Organic ◽  
Nitrogen Doped Carbon ◽  
Dyes Degradation ◽  
Organic Framework

In this paper, a metal organic framework (ZIF-8)-derived nitrogen doped carbon (C-ZIF) modified g-C3N4 composite was directly prepared by pyrolysis method. The C-ZIF@g-C3N4 composites with different loadings were prepared by...

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