Functional models of nonheme diiron enzymes: reactivity of the μ-oxo-μ-1,2-peroxo-diiron(iii) intermediate in electrophilic and nucleophilic reactions
The ambiphilic behavior (electrophilic versus nucleophilic character) of the peroxo-diferric complex and its relative reactivity towards aldehydes and phenols have been discussed.
1998 ◽
Vol 178-180
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pp. 1555-1572
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1998 ◽
Vol 120
(46)
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pp. 12153-12154
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1983 ◽
Vol 48
(12)
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pp. 3660-3673
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1980 ◽
Vol 45
(2)
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pp. 406-414
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1992 ◽
Vol 57
(6)
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pp. 1291-1298
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