Metal-free synthesis of gem-silylboronate esters and their Pd(0)-catalyzed cross-coupling with aryliodides
2019 ◽
Vol 17
(23)
◽
pp. 5714-5724
◽
An efficient method for the synthesis of gem-silylboronate esters based on transition-metal-free reaction of arylboronic acids and trimethylsilyldiazomethane is developed, and Suzuki–Miyaura cross-coupling of gem-silylboronate esters with aryliodides is described.