Self-healing and shape-memory solid polymer electrolytes with high mechanical strength facilitated by a poly(vinyl alcohol) matrix

Solid polymer electrolytes (SPEs) based on poly (vinyl alcohol) were prepared with dimethyl sulfoxide as a solvent. Prepared SPEs form the 'fast cationic transport process' and lithium ion hopping through 'fast cationic transport process' is occurred. In this study, we observed the dependence of ionic conductivity on the drying time of solvent and there was particular relationship between ionic conductivity and the amount of residual solvent. Especially, we investigated the influence of solvent on cation mobility in the ‘fast cationic transport process’ and we found that the solvent acted as a bridge to connect neighboring ion aggregates and made the ion hopping easy.

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Development of the PEO Based Solid Polymer Electrolytes for All-Solid State Lithium Ion Batteries

Polymers ◽

10.3390/polym10111237 ◽

2018 ◽

Vol 10 (11) ◽

pp. 1237 ◽

Cited By ~ 39

Author(s):

Yu Jiang ◽

Xuemin Yan ◽

Zhaofei Ma ◽

Ping Mei ◽

Wei Xiao ◽

...

Keyword(s):

Solid State ◽

Lithium Ion Batteries ◽

Polymer Electrolytes ◽

High Performance ◽

Lithium Salt ◽

Rapid Development ◽

Lithium Ion ◽

Solid Polymer Electrolytes ◽

Solid Polymer ◽

Potential Candidate

Solid polymer electrolytes (SPEs) have attracted considerable attention due to the rapid development of the need for more safety and powerful lithium ion batteries. The prime requirements of solid polymer electrolytes are high ion conductivity, low glass transition temperature, excellent solubility to the conductive lithium salt, and good interface stability against Li anode, which makes PEO and its derivatives potential candidate polymer matrixes. This review mainly encompasses on the synthetic development of PEO-based SPEs (PSPEs), and the potential application of the resulting PSPEs for high performance, all-solid-state lithium ion batteries.

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Structural, Vibrational, Thermal And Electrical Characterization Of Gamma Radiation-Crosslinked Poly (Vinyl Alcohol)-Based Solid Polymer Electrolytes Blended With LiOH⋅H[sub 2]O Salt

10.1063/1.2999961 ◽

2008 ◽

Cited By ~ 2

Author(s):

Rasha M. Khafagy ◽

M. Madani ◽

Y. A. Badr ◽

El-Hachemi Amara ◽

Saïd Boudjemai ◽

...

Keyword(s):

Gamma Radiation ◽

Polymer Electrolytes ◽

Vinyl Alcohol ◽

Electrical Characterization ◽

Solid Polymer Electrolytes ◽

Solid Polymer ◽

Poly Vinyl Alcohol

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Contribution Succinonitrile additive for Performa LiTFSi Solid Polymer Electrolytes for Li-Ion Battery

Eksakta Jurnal Ilmu-Ilmu MIPA ◽

10.20885/eksakta.vol1.iss2.art2 ◽

2020 ◽

Vol 20 (2) ◽

Author(s):

Qolby Sabrina ◽

Titik Lestariningsih ◽

Christin Rina Ratri ◽

Achmad Subhan

Keyword(s):

Ionic Conductivity ◽

Polymer Electrolytes ◽

Room Temperature ◽

Lithium Salt ◽

Ionic Conduction ◽

Lithium Ion ◽

Solid Polymer Electrolytes ◽

Solid Polymer ◽

Half Cell ◽

Li Ion

Solid polymer electrolyte (SPE) appropriate to solve packaging leakage and expansion volume in lithium-ion battery systems. Evaluation of electrochemical performance of SPE consisted of mixture lithium salt, solid plasticizer, and polymer precursor with different ratio. Impedance spectroscopy was used to investigate ionic conduction and dielectric response lithium bis(trifluoromethane)sulfony imide (LiTFSI) salt, and additive succinonitrile (SCN) plasticizer. The result showing enhanced high ionic conductivity. In half-cell configurations, wide electrochemical stability window of the SPE has been tested. Have stability window at room temperature, indicating great potential of SPE for application in lithium ion batteries. Additive SCN contribute to forming pores that make it easier for the li ion to move from the anode to the cathode and vice versa for better perform SPE. Pore of SPE has been charaterization with FE-SEM. Additive 5% w.t SCN shows the best ionic conductivity with 4.2 volt wide stability window and pretty much invisible pores.

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Salt Concentration Effect on Electrical and Dielectric Properties of Solid Polymer Electrolytes based Carboxymethyl Cellulose for Lithium-ion Batteries

Biointerface Research in Applied Chemistry ◽

10.33263/briac125.61146123 ◽

2021 ◽

Vol 12 (5) ◽

pp. 6114-6123

Keyword(s):

Dielectric Properties ◽

Ionic Conductivity ◽

Polymer Electrolytes ◽

Carboxymethyl Cellulose ◽

Electrochemical Impedance ◽

Lithium Ion ◽

Lithium Perchlorate ◽

Linear Sweep Voltammetry ◽

Solid Polymer Electrolytes ◽

Solid Polymer

Solid polymer electrolytes (SPEs) based carboxymethyl cellulose (CMC) with lithium perchlorate (LiClO4) were prepared via solution drop-cast technique. The CMC host is complexed by different concentrations of LiClO4 salt. SPEs were characterized by Electrochemical Impedance Spectroscopy (EIS) and Linear Sweep Voltammetry (LSV) in coin cells with lithium metal electrodes. EIS performed unique results based on various ionic conductivity values and dielectric properties. The higher ionic conductivity (1.32 × 10-5 S/cm) was obtained by SPEs 2 following by short-range ionic transport results based on dielectric properties depending on frequency. SPEs with LiClO4 addition are electrochemically stable over 2 V in lithium battery coin cells from LSV results.

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