scholarly journals Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes

RSC Advances ◽  
2019 ◽  
Vol 9 (30) ◽  
pp. 17425-17431 ◽  
Author(s):  
Tatsuki Nagata ◽  
Takeru Inoue ◽  
Xianjin Lin ◽  
Shinya Ishimoto ◽  
Seiya Nakamichi ◽  
...  

A highly efficient and reusable Pd NCs catalyst system for silylation of aryl halides was developed.

Tetrahedron ◽  
2009 ◽  
Vol 65 (47) ◽  
pp. 9737-9741 ◽  
Author(s):  
Yang Feng ◽  
Huifeng Wang ◽  
Fangfang Sun ◽  
Yaming Li ◽  
Xinmei Fu ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 41 (11) ◽  
pp. no-no
Author(s):  
Yang Feng ◽  
Huifeng Wang ◽  
Fangfang Sun ◽  
Yaming Li ◽  
Xinmei Fu ◽  
...  

Synthesis ◽  
2017 ◽  
Vol 49 (18) ◽  
pp. 4372-4382 ◽  
Author(s):  
Mohammed Waheed ◽  
Naseem Ahmed

2-Hydroxyindan-1-ones have been efficiently synthesized and successfully applied as ligands in Pd-catalyzed Ullmann type, Suzuki–Miyaura, and Mizoroki–Heck cross-coupling reactions with aryl tosylates and aryl halides. The ligands are air- and moisture-stable and have shown high catalytic activity with Pd(OAc)2 in these cross-coupling reactions. The system tolerates a variety of functional groups in the product and can be re-used at least three times with maximum efficiency.


ChemInform ◽  
2011 ◽  
Vol 42 (8) ◽  
pp. no-no
Author(s):  
Yaming Li ◽  
Huifeng Wang ◽  
Xiaoying Li ◽  
Tao Chen ◽  
Defeng Zhao

Tetrahedron ◽  
2010 ◽  
Vol 66 (45) ◽  
pp. 8583-8586 ◽  
Author(s):  
Yaming Li ◽  
Huifeng Wang ◽  
Xiaoying Li ◽  
Tao Chen ◽  
Defeng Zhao

Synlett ◽  
2020 ◽  
Vol 31 (15) ◽  
pp. 1501-1506
Author(s):  
Pengfei Liu ◽  
Guobi Chai ◽  
Fengyu Bao ◽  
Zhikai Liu ◽  
Haixin Bai ◽  
...  

A novel and efficient catalyst system was developed for homocoupling reactions of aryl halides. The catalyst system consists of Pd(OAc)2 and the peppery sensory component of tobacco leaves. This is the first time that a sensory component has been used in an organic reaction. Experiments using the catalyst system showed that the reactions proceeded smoothly under air in the absence of both an additional ligand and a reductant. Furthermore, the catalyst system can be applied to the coupling reactions of hetaryl iodides. Many functional groups (including a hydroxy group) are tolerated.


2019 ◽  
Author(s):  
Randolph Escobar ◽  
Jeffrey Johannes

<div>While carbon-heteroatom cross coupling reactions have been extensively studied, many methods are specific and</div><div>limited to a set of substrates or functional groups. Reported here is a method that allows for C-O, C-N and C-S cross coupling reactions under one general methodology. We propose that an energy transfer pathway, in which an iridium photosensitizer produces an excited nickel (II) complex, is responsible for the key reductive elimination step that couples aryl halides to 1° and 2° alcohols, anilines, thiophenols, carbamates and sulfonamides.</div>


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