scholarly journals Transient supramolecular assembly of a functional perylene diimide controlled by a programmable pH cycle

Soft Matter ◽  
2020 ◽  
Vol 16 (3) ◽  
pp. 591-594 ◽  
Author(s):  
Guido Panzarasa ◽  
Alexandre L. Torzynski ◽  
Tianqi Sai ◽  
Katrina Smith-Mannschott ◽  
Eric R. Dufresne

Transient supramolecular self-assembly with tunable lifetime is achieved by coupling an alkali-generating clock reaction to a slow acid generator.

2020 ◽  
Vol 5 (2) ◽  
pp. 445-448 ◽  
Author(s):  
Guido Panzarasa ◽  
Tianqi Sai ◽  
Alexandre L. Torzynski ◽  
Katrina Smith-Mannschott ◽  
Eric R. Dufresne

Coupling an acid-autocatalyzed clock reaction with the hydrolysis of a cyclic ester enables the time-domain programming of supramolecular pH-driven self-assembly.


2010 ◽  
Vol 114 (14) ◽  
pp. 4802-4810 ◽  
Author(s):  
Xiangkui Ren ◽  
Bin Sun ◽  
Chi-Chun Tsai ◽  
Yingfeng Tu ◽  
Siwei Leng ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 41761-41764 ◽  
Author(s):  
M. B. Bijesh ◽  
Rituraj Mishra ◽  
Narayanan D. Kurur ◽  
V. Haridas

Macrocycles containing serine self-assembled into fibres, while threonine induced vesicular self-assembly. Macrocycles with serine can be driven to form vesicular assembly by incorporating a non-planar spacer.


Soft Matter ◽  
2018 ◽  
Vol 14 (31) ◽  
pp. 6415-6418 ◽  
Author(s):  
Guido Panzarasa ◽  
Alina Osypova ◽  
Alba Sicher ◽  
Arie Bruinink ◽  
Eric R. Dufresne

Directed self-assembly of chitosan as tunable-size particles is achieved in the time domain by means of the formaldehyde clock reaction.


Nanoscale ◽  
2020 ◽  
Vol 12 (22) ◽  
pp. 11986-11996
Author(s):  
K. D. M. Rao ◽  
Mozakkar Hossain ◽  
Umesh ◽  
Aniket Roy ◽  
Anudeepa Ghosh ◽  
...  

Fully transparent perovskite microwire arrays passivated with supramolecular assembly for stable and high-performance photodetectors.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Julia Y. Rho ◽  
Henry Cox ◽  
Edward D. H. Mansfield ◽  
Sean H. Ellacott ◽  
Raoul Peltier ◽  
...  

Abstract Self-assembling peptides have the ability to spontaneously aggregate into large ordered structures. The reversibility of the peptide hydrogen bonded supramolecular assembly make them tunable to a host of different applications, although it leaves them highly dynamic and prone to disassembly at the low concentration needed for biological applications. Here we demonstrate that a secondary hydrophobic interaction, near the peptide core, can stabilise the highly dynamic peptide bonds, without losing the vital solubility of the systems in aqueous conditions. This hierarchical self-assembly process can be used to stabilise a range of different β-sheet hydrogen bonded architectures.


2016 ◽  
Vol 52 (75) ◽  
pp. 11195-11198 ◽  
Author(s):  
Gloria Tabacchi ◽  
Gion Calzaferri ◽  
Ettore Fois

Correlated host–guest motions help bulky molecules to enter pores smaller than their size.


RSC Advances ◽  
2015 ◽  
Vol 5 (109) ◽  
pp. 90158-90167 ◽  
Author(s):  
Manoj K. Manna ◽  
Dnyaneshwar B. Rasale ◽  
Apurba K. Das

Optical and self-assembly nature of an aromatic dipeptide Phe-Phe (FF) functionalized benzo[ghi]perylene monoimide (BPI) are studied. Acceptor BPI-FF-OMe molecule shows white light emission upon energy transfer from donor pyrenebutyric acid molecule.


2018 ◽  
Vol 54 (68) ◽  
pp. 9482-9485 ◽  
Author(s):  
Prabhpreet Singh ◽  
Lalit Singh Mittal ◽  
Kapil Kumar ◽  
Poonam Sharma ◽  
Gaurav Bhargava ◽  
...  

We report metallo-supramolecular interlocked hexagonal self-assembly associated with the near-IR detection of Pb2+ ions and thiols in water using a perylene diimide probe.


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