scholarly journals Supramolecular assembly by time-programmed acid autocatalysis

2020 ◽  
Vol 5 (2) ◽  
pp. 445-448 ◽  
Author(s):  
Guido Panzarasa ◽  
Tianqi Sai ◽  
Alexandre L. Torzynski ◽  
Katrina Smith-Mannschott ◽  
Eric R. Dufresne

Coupling an acid-autocatalyzed clock reaction with the hydrolysis of a cyclic ester enables the time-domain programming of supramolecular pH-driven self-assembly.

Soft Matter ◽  
2018 ◽  
Vol 14 (31) ◽  
pp. 6415-6418 ◽  
Author(s):  
Guido Panzarasa ◽  
Alina Osypova ◽  
Alba Sicher ◽  
Arie Bruinink ◽  
Eric R. Dufresne

Directed self-assembly of chitosan as tunable-size particles is achieved in the time domain by means of the formaldehyde clock reaction.


Author(s):  
Guido Panzarasa ◽  
Alexandre L. Torzynski ◽  
Tianqi Sai ◽  
Katrina Smith-Mannschott ◽  
Eric R. Dufresne

<div>Transient self-assembly is a necessary step towards the development of life-like materials. Our approach allows to program pH-driven supramolecular assembly in the time domain with tailorable lag- and life-times, overcoming the limitations of previously described approaches and setting a new standard for active materials design.<br></div><div><br></div>


2019 ◽  
Author(s):  
Guido Panzarasa ◽  
Alexandre L. Torzynski ◽  
Tianqi Sai ◽  
Katrina Smith-Mannschott ◽  
Eric R. Dufresne

<div>Transient self-assembly is a necessary step towards the development of life-like materials. Our approach allows to program pH-driven supramolecular assembly in the time domain with tailorable lag- and life-times, overcoming the limitations of previously described approaches and setting a new standard for active materials design.<br></div><div><br></div>


2020 ◽  
Vol 11 (6) ◽  
pp. 1518-1522 ◽  
Author(s):  
Maria A. Cardona ◽  
Leonard J. Prins

The addition of ATP under dissipative conditions to a complex mixture causes the transient upregulation of hydrazone-bond formation.


1997 ◽  
Vol 62 (1) ◽  
pp. 1-41 ◽  
Author(s):  
Hans Bock

Molecular states are the real building blocks of the chemist, because the structure of a molecule can change considerably as its energy and thus its electron distribution varies within the time-domain of dynamic relaxation. The ever increasing use of measuring methods from the armory of physics to characterize molecules by their molecular state fingerprints and, above all, of computers to rationalize both their properties and their microscopic reaction pathways, provides a wealth of information for the development of chemistry. To deal with the complexity of molecular states, a qualitative model based on the topology and symmetry of their structures as well as of their energies resulting from the electron distribution over the respective effective nuclear potentials is presented and is illustrated by examples of our own efforts to elucidate molecular state properties including time-dependent dynamics, microscopic reaction pathways both in the gas phase and in solution, and the self-assembly of molecules on crystallization. In conclusion, a personal retrospective is summarized and some prospects for the future are outlined.


Soft Matter ◽  
2020 ◽  
Vol 16 (3) ◽  
pp. 591-594 ◽  
Author(s):  
Guido Panzarasa ◽  
Alexandre L. Torzynski ◽  
Tianqi Sai ◽  
Katrina Smith-Mannschott ◽  
Eric R. Dufresne

Transient supramolecular self-assembly with tunable lifetime is achieved by coupling an alkali-generating clock reaction to a slow acid generator.


1992 ◽  
Vol 2 (4) ◽  
pp. 615-620
Author(s):  
G. W. Series
Keyword(s):  

2018 ◽  
Vol 12 (7-8) ◽  
pp. 76-83
Author(s):  
E. V. KARSHAKOV ◽  
J. MOILANEN

Тhe advantage of combine processing of frequency domain and time domain data provided by the EQUATOR system is discussed. The heliborne complex has a towed transmitter, and, raised above it on the same cable a towed receiver. The excitation signal contains both pulsed and harmonic components. In fact, there are two independent transmitters operate in the system: one of them is a normal pulsed domain transmitter, with a half-sinusoidal pulse and a small "cut" on the falling edge, and the other one is a classical frequency domain transmitter at several specially selected frequencies. The received signal is first processed to a direct Fourier transform with high Q-factor detection at all significant frequencies. After that, in the spectral region, operations of converting the spectra of two sounding signals to a single spectrum of an ideal transmitter are performed. Than we do an inverse Fourier transform and return to the time domain. The detection of spectral components is done at a frequency band of several Hz, the receiver has the ability to perfectly suppress all sorts of extra-band noise. The detection bandwidth is several dozen times less the frequency interval between the harmonics, it turns out thatto achieve the same measurement quality of ground response without using out-of-band suppression you need several dozen times higher moment of airborne transmitting system. The data obtained from the model of a homogeneous half-space, a two-layered model, and a model of a horizontally layered medium is considered. A time-domain data makes it easier to detect a conductor in a relative insulator at greater depths. The data in the frequency domain gives more detailed information about subsurface. These conclusions are illustrated by the example of processing the survey data of the Republic of Rwanda in 2017. The simultaneous inversion of data in frequency domain and time domain can significantly improve the quality of interpretation.


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