scholarly journals Fluorination as a route towards unlocking the hydrogen bond donor ability of phenolic compounds in self-assembled monolayers

CrystEngComm ◽  
2020 ◽  
Vol 22 (14) ◽  
pp. 2425-2428
Author(s):  
Harry Pinfold ◽  
Graham Pattison ◽  
Giovanni Costantini
Keyword(s):  
Hydrogen Bond ◽  
Phenolic Compounds ◽  
Building Block ◽  
Self Assembled Monolayers ◽  
Hydrogen Bond Donor ◽  
Assembled Monolayers ◽  
Donor Ability ◽  
Self Assembled ◽  
Effective Hydrogen

Fluorination turns a prototypical diphenol into an effective hydrogen-bond-donating building block for the formation of 2D phenol–pyridine cocrystals.

Synthesis of a disulfide functionalized diacetylenic derivative of carbazole as building-block of polymerizable self-assembled monolayers

2014 ◽  
Vol 68 (2) ◽  
Author(s):  
Sushilkumar Jadhav ◽  
Massimo Maccagno
Keyword(s):  
Building Block ◽  
Metallic Nanostructures ◽  
Self Assembled Monolayers ◽  
Sodium Hydrosulfide ◽  
Synthetic Pathway ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
End Group ◽  
Symmetrical Disulfide ◽  
Made In

AbstractA new symmetrical disulfide containing a diacetylenic unit and bearing a fluorescent carbazolyl end-group forming polymerizable self-assembled monolayers on metallic nanostructures has been synthesized. Suitable modifications of the synthetic steps involved in the synthesis of such derivatives were made in order to assure better synthetic pathway. Conversion of the tosylated derivative into the final symmetrical disulfide is carried out using sodium hydrosulfide (NaSH).

One Building Block, Two Different Nanoporous Self-Assembled Monolayers: A Combined STM and Monte Carlo Study

ACS Nano ◽  
2011 ◽  
Vol 6 (1) ◽  
pp. 897-903 ◽  
Author(s):  
Jinne Adisoejoso ◽  
Kazukuni Tahara ◽  
Shengbin Lei ◽  
Paweł Szabelski ◽  
Wojciech Rżysko ◽  
...  
Keyword(s):  
Monte Carlo ◽  
Building Block ◽  
Monte Carlo Study ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Analysis of structures with saturated hydrogen bonding

2007 ◽  
Vol 63 (1) ◽  
pp. 132-141 ◽  
Author(s):  
James H. Loehlin ◽  
Elizabeth L. N. Okasako
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Self Assembled Monolayers ◽  
Donor And Acceptor ◽  
Assembled Monolayers ◽  
Graph Set ◽  
Hydrogen Bond Patterns ◽  
Self Assembled ◽  
Acceptor Numbers

All simple structures with saturated hydrogen bonding (SHB) are classified into eight categories on the basis of the donor and acceptor numbers on the atoms at each end of the hydrogen bonds. Examples from the literature are included where known, along with seven structures investigated as part of this study (five have SHB). Graph-set descriptions of the hydrogen-bond patterns are given for each of these structures and for some selected literature examples. The structures presented are: piperazine (I), morpholinium chloride (II) and iodide (III) [(II) and (III) are not SHB], three 1:1 cocrystals of diols with 1,4-phenylenediamine (PDA) – PDA·1,8-octane diol (IV), PDA·1,10-decane diol (V), and PDA·1,12-dodecane diol (VI) and 6-amino-1-hexanol (VII). This study discusses some structures that show limitations of the graph-set model, along with possible suggestions to cover these limitations. The cocrystalline PDA·aliphatic diol structures may provide details applicable to the structure of self-assembled monolayers of aliphatic thiol molecules on Au(111) surfaces.

Electrochemical behavior of self-assembled monolayers based on functionalized oligothiophenes

1998 ◽  
Vol 95 (6) ◽  
pp. 1339-1342 ◽  
Author(s):  
R. Michalitsch ◽  
A. El Kassmi ◽  
P. Lang ◽  
A. Yassar ◽  
F. Garnier
Keyword(s):  
Electrochemical Behavior ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Imaging of patterned self-assembled monolayers by scanning photoelectron microscopy

2003 ◽  
Vol 104 ◽  
pp. 459-462 ◽  
Author(s):  
R. Klauser ◽  
M. Zharnikov ◽  
I.-H. Hong ◽  
S.-C. Wang ◽  
A. Gölzhäuser ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Scanning Photoelectron Microscopy ◽  
Self Assembled
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