A facile template method to fabricate strongly coupled 1D sandwich-like C@Fe3O4@C/Ni coaxial microtubes with enhanced catalytic performance

CrystEngComm ◽  
2020 ◽  
Vol 22 (32) ◽  
pp. 5302-5309
Author(s):  
Qian Niu ◽  
Min Zhang ◽  
Libin Liu ◽  
Jing Zheng ◽  
Qunling Fang ◽  
...  

Sandwich-like C@Fe3O4@C/Ni microtubes were well-constructed with MoO3 microrods as a hard template, which manifested excellent catalytic performance and recycling ability in the reduction of 4-nitrophenol.

2020 ◽  
Vol 42 (2) ◽  
pp. 188-188
Author(s):  
Shengnan Guan Shengnan Guan ◽  
Wenzhi Li Wenzhi Li ◽  
Jianru Ma Jianru Ma ◽  
Qingchuan Liu Qingchuan Liu ◽  
Kun Chen and Qi Zhang Kun Chen and Qi Zhang

In this work, three-dimensional mesoporous MnO2, K/MnO2, Pt/MnO2 and K-Pt/MnO2 catalysts were prepared through hard-template method. The additional K/Pt had significantly improved the HCHO oxidation activity. The K-Pt/MnO2 catalyzed complete HCHO oxidation was achieved at 0℃ with space velocity (GHSV) at 50000 ml/(gand#183;h). With the excellent catalytic performance, K-Pt/MnO2 exhibited a higher ratio of Oads(surface adsorbed oxygen)/Olatt(surface lattice oxygen) and Mn3+/Mn4+ ions than the other catalysts. Meanwhile, it was still stable after running a 70h reaction. Overall, the K-Pt/MnO2 was a promising material for HCHO elimination.


2014 ◽  
Vol 29 (2) ◽  
pp. 124-130 ◽  
Author(s):  
Yu-Cheng DU ◽  
Guang-Wei ZHENG ◽  
Qi MENG ◽  
Li-Ping WANG ◽  
Hai-Guang FAN ◽  
...  

Author(s):  
Sajjad Rimaz ◽  
Reza Katal

: In the present study, SAPO-34 particles were synthesized using hydrothermal (HT) and dry gel (DG) conversion methods in the presence of diethyl amine (DEA) as an organic structure directing agent (SDA). Carbon nanotubes (CNT) were used as hard template in the synthesis procedure to introduce transport pores into the structures of the synthesized samples. The synthesized samples were characterized with different methods to reveal effects of synthesis method and using hard template on their structure and catalytic performance in methanol to olefin reaction (MTO). DG conversion method results in smaller particle size in comparison with hydrothermal method, resulting in enhancing catalytic performance. On the other side, using CNT in the synthesis procedure with DG method results in more reduction in particle size and formation of hierarchical structure which drastically improves catalytic performance.


Author(s):  
Cui‐Ping Wu ◽  
Zhao Jin ◽  
Kai Xu ◽  
Wei‐Wei Wang ◽  
Chun‐Jiang Jia

Author(s):  
Yangyang Ren ◽  
Chuanliang Li ◽  
Baosong Li ◽  
Fan Gao ◽  
Xinghua Zhang ◽  
...  

PtPd nanoframes with excellent catalytic properties were obtained by etching Pd@PdPt core–shell RDs with Fe3+ in an acid environment.


Author(s):  
Yafei Liang ◽  
Beibei Gao ◽  
Lipeng Zhou ◽  
Xiaomei Yang ◽  
Tianliang Lu ◽  
...  

A facile approach has been developed to fabricate hierarchical SAPO-34 with large intracrystalline meso/macropores and excellent catalytic performance in the MTO reaction.


Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 974
Author(s):  
Bing Han ◽  
Haihong Meng ◽  
Fengyu Li ◽  
Jingxiang Zhao

Under the current double challenge of energy and the environment, an effective nitrogen reduction reaction (NRR) has become a very urgent need. However, the largest production of ammonia gas today is carried out by the Haber–Bosch process, which has many disadvantages, among which energy consumption and air pollution are typical. As the best alternative procedure, electrochemistry has received extensive attention. In this paper, a catalyst loaded with Fe3 clusters on the two-dimensional material C2N (Fe3@C2N) is proposed to achieve effective electrochemical NRR, and our first-principles calculations reveal that the stable Fe3@C2N exhibits excellent catalytic performance for electrochemical nitrogen fixation with a limiting potential of 0.57 eV, while also suppressing the major competing hydrogen evolution reaction. Our findings will open a new door for the development of non-precious single-cluster catalysts for effective nitrogen reduction reactions.


2019 ◽  
Vol 6 (5) ◽  
pp. 1152-1157 ◽  
Author(s):  
Xia Wang ◽  
Xiurong Zhang ◽  
Kai Zhang ◽  
Xiaokang Wang ◽  
Yutong Wang ◽  
...  

Amino-functionalized Cu-MOF for the efficient purification of methane from light hydrocarbons and excellent catalytic performance.


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