Peculiarities of high-pressure hydrogen adsorption on Pt catalyzed Cu-BTC metal–organic framework

2021 ◽  
Vol 23 (7) ◽  
pp. 4277-4286
Author(s):  
S. V. Chuvikov ◽  
E. A. Berdonosova ◽  
A. Krautsou ◽  
J. V. Kostina ◽  
V. V. Minin ◽  
...  
Keyword(s):  
High Pressure ◽  
High Pressures ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Pt Catalyst ◽  
Metal Organic ◽  
Pt Catalyzed ◽  
Pressure Hydrogen ◽  
Organic Framework

Pt-Catalyst plays a key role in hydrogen adsorption by Cu-BTC at high pressures.

scholarly journals Design Rules for Metal‐Organic Framework Stability in High‐Pressure Hydrogen Environments

ChemPhysChem ◽  
2019 ◽  
Vol 20 (10) ◽  
pp. 1305-1310 ◽  
Author(s):  
Timothy C. Wang ◽  
James L. White ◽  
Binglin Bie ◽  
Hexiang Deng ◽  
Jane Edgington ◽  
...  
Keyword(s):  
High Pressure ◽  
Metal Organic Framework ◽  
Design Rules ◽  
Metal Organic ◽  
Pressure Hydrogen ◽  
Organic Framework

High-pressure hydrogen storage on modified MIL-101 metal-organic framework

2014 ◽  
Vol 38 (12) ◽  
pp. 1562-1570 ◽  
Author(s):  
Semen N. Klyamkin ◽  
Sergey V. Chuvikov ◽  
Nina V. Maletskaya ◽  
Ekaterina V. Kogan ◽  
Vladimir P. Fedin ◽  
...  
Keyword(s):  
High Pressure ◽  
Hydrogen Storage ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Pressure Hydrogen ◽  
Organic Framework

A zwitterionic metal–organic framework with free carboxylic acid sites that exhibits enhanced hydrogen adsorption energies

CrystEngComm ◽  
2013 ◽  
Vol 15 (45) ◽  
pp. 9408 ◽  
Author(s):  
Marianne B. Lalonde ◽  
Rachel B. Getman ◽  
Jeong Yong Lee ◽  
John M. Roberts ◽  
Amy A. Sarjeant ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Metal Organic ◽  
Adsorption Energies ◽  
Organic Framework

scholarly journals In Situ Time-Resolved Decomposition of β-Hydride Phase in Palladium Nanoparticles Coated with Metal-Organic Framework

Metals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 810
Author(s):  
Mikhail V. Kirichkov ◽  
Aram L. Bugaev ◽  
Alina A. Skorynina ◽  
Vera V. Butova ◽  
Andriy P. Budnyk ◽  
...  
Keyword(s):  
Phase Transition ◽  
Particle Size ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Pd Nanoparticles ◽  
Time Resolved ◽  
Metal Organic ◽  
Hydride Phases ◽  
Organic Framework

The formation of palladium hydrides is a well-known phenomenon, observed for both bulk and nanosized samples. The kinetics of hydrogen adsorption/desorption strongly depends on the particle size and shape, as well as the type of support and/or coating of the particles. In addition, the structural properties of hydride phases and their distribution also depend on the particle size. In this work, we report on the in situ characterization of palladium nanocubes coated with HKUST-1 metal-organic framework (Pd@HKUST-1) during desorption of hydrogen by means of synchrotron-based time-resolved X-ray powder diffraction. A slower hydrogen desorption, compared to smaller sized Pd nanoparticles was observed. Rietveld refinement of the time-resolved data revealed the remarkable stability of the lattice parameters of α- and β-hydride phases of palladium during the α- to β- phase transition, denoting the behavior more similar to the bulk materials than nanoparticles. The stability in the crystal sizes for both α- and β-hydride phases during the phase transition indicates that no sub-domains are formed within a single particle during the phase transition.

High pressure studies of metal organic framework materials

2012 ◽  
Vol 9 (1/2) ◽  
pp. 18 ◽  
Author(s):  
Stephen A. Moggach ◽  
Alexander J. Graham ◽  
Anna Muszkiewicz ◽  
Carole A. Morrison
Keyword(s):  
High Pressure ◽  
Metal Organic Framework ◽  
Framework Materials ◽  
High Pressure Studies ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Formulation of Metal–Organic Framework Inks for the 3D Printing of Robust Microporous Solids toward High-Pressure Gas Storage and Separation

2020 ◽  
Vol 12 (9) ◽  
pp. 10983-10992 ◽  
Author(s):  
Jérémy Dhainaut ◽  
Mickaële Bonneau ◽  
Ryota Ueoka ◽  
Kazuyoshi Kanamori ◽  
Shuhei Furukawa
Keyword(s):  
High Pressure ◽  
3D Printing ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
Metal Organic ◽  
Microporous Solids ◽  
Organic Framework
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