Sterically hindered Re- and Mn-CO2 reduction catalysts for solar energy conversion
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M(NN)(CO)3X (M = Re, Mn) complexes with a bulky diimine ligand catalyse electrochemical reduction of CO2 with high TON. A noble-metal free system of the Mn-complex photosensitised by a Zn-porphyrin photocatalytically reduces CO2 under visible light.
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2021 ◽
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2015 ◽
Vol 275
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pp. 8-16
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2016 ◽
Vol 41
(1)
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pp. 139-144
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2014 ◽
Vol 160-161
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pp. 173-178
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