Criteria of active sites in nonradical persulfate activation process from integrated experimental and theoretical investigations: boron–nitrogen-co-doped nanocarbon-mediated peroxydisulfate activation as an example

2020 ◽  
Vol 7 (7) ◽  
pp. 1899-1911 ◽  
Author(s):  
Chunyang Nie ◽  
Zhenhua Dai ◽  
Wenjie Liu ◽  
Xiaoguang Duan ◽  
Chengyin Wang ◽  
...  

Reliable criteria for identifying the intrinsic active sites in carbocatalysts to mediate an electron-transfer mechanism in persulfate activation are presented.

2015 ◽  
Vol 14 (3) ◽  
pp. 563-568 ◽  
Author(s):  
Theodoros S. Symeonidis ◽  
Ioannis Tamiolakis ◽  
Gerasimos S. Armatas ◽  
Ioannis N. Lykakis

Decatungstate supported on mesoporous TiO2 nanoparticle assemblies catalyze the selective and efficient oxidation of aromatic alcohols under “green” oxidation conditions. An electron transfer mechanism was predominated under UV-vis irradiation.


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