scholarly journals Synthesis of poly(stearyl methacrylate)-poly(2-hydroxypropyl methacrylate) diblock copolymer nanoparticles via RAFT dispersion polymerization of 2-hydroxypropyl methacrylate in mineral oil

2020 ◽  
Vol 11 (28) ◽  
pp. 4579-4590 ◽  
Author(s):  
Csilla György ◽  
Saul J. Hunter ◽  
Chloé Girou ◽  
Matthew J. Derry ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Dispersion Polymerization ◽  
Mineral Oil ◽  
Hydroxypropyl Methacrylate ◽  
Stearyl Methacrylate

RAFT dispersion polymerization of 2-hydroxypropyl methacrylate produces diblock copolymer spheres, worms or vesicles in mineral oil; the Pickering emulsifier performance of the spheres is examined.

scholarly journals RAFT dispersion polymerization of glycidyl methacrylate for the synthesis of epoxy-functional block copolymer nanoparticles in mineral oil

2019 ◽  
Vol 10 (5) ◽  
pp. 603-611 ◽  
Author(s):  
Philip J. Docherty ◽  
Matthew J. Derry ◽  
Steven P. Armes
Keyword(s):  
Block Copolymer ◽  
Diblock Copolymer ◽  
Glycidyl Methacrylate ◽  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Mineral Oil ◽  
Functional Block ◽  
Reversible Addition ◽  
Stearyl Methacrylate

Epoxy-functional poly(stearyl methacrylate)-poly(glycidyl methacrylate) (PSMA-PGlyMA) diblock copolymer nanoparticles are synthesized via reversible addition–fragmentation chain transfer (RAFT) dispersion polymerization of glycidyl methacrylate (GlyMA) in mineral oil at 70 °C.

scholarly journals Epoxy-functional diblock copolymer spheres, worms and vesicles via polymerization-induced self-assembly in mineral oil

2020 ◽  
Vol 11 (19) ◽  
pp. 3332-3339
Author(s):  
Philip J. Docherty ◽  
Chloé Girou ◽  
Matthew J. Derry ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Glycidyl Methacrylate ◽  
Dispersion Polymerization ◽  
Mineral Oil ◽  
Stearyl Methacrylate

Epoxy-functional poly(stearyl methacrylate)-poly(glycidyl methacrylate) spheres, worms or vesicles can be prepared by RAFT dispersion polymerization of glycidyl methacrylate in mineral oil at 70 °C.

scholarly journals Semi-crystalline diblock copolymer nano-objects prepared via RAFT alcoholic dispersion polymerization of stearyl methacrylate

2015 ◽  
Vol 6 (10) ◽  
pp. 1751-1757 ◽  
Author(s):  
Mona Semsarilar ◽  
Nicholas J. W. Penfold ◽  
Elizabeth R. Jones ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Local Order ◽  
Dsc Studies ◽  
The Core ◽  
Stearyl Methacrylate

Semi-crystalline diblock copolymer spheres, worms or vesicles are prepared by polymerization-induced self-assembly via RAFT dispersion polymerization of stearyl methacrylate. DSC studies confirm local order for the core-forming poly(stearyl methacrylate) chains.

scholarly journals Industrially-relevant polymerization-induced self-assembly formulations in non-polar solvents: RAFT dispersion polymerization of benzyl methacrylate

2015 ◽  
Vol 6 (16) ◽  
pp. 3054-3062 ◽  
Author(s):  
Matthew J. Derry ◽  
Lee A. Fielding ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Mineral Oil ◽  
Polar Solvents ◽  
One Pot

Diblock copolymer spheres, worms and vesicles are prepared via RAFT dispersion polymerization of benzyl methacrylate in either mineral oil or a poly(α-olefin) using polymerization-induced self-assembly; an efficient ‘one-pot’ protocol is reported for spheres at 30% solids in mineral oil.

scholarly journals Polysulfobetaine-based diblock copolymer nano-objects via polymerization-induced self-assembly

2015 ◽  
Vol 6 (41) ◽  
pp. 7264-7273 ◽  
Author(s):  
Kay E. B. Doncom ◽  
Nicholas J. Warren ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
High Tolerance ◽  
Hydroxypropyl Methacrylate ◽  
Added Salt

A zwitterionic polysulfobetaine-based macro-CTA is used for the synthesis of spheres, worms or vesiclesviaaqueous RAFT dispersion polymerization of 2-hydroxypropyl methacrylate (HPMA). These new diblock copolymer nano-objects exhibit high tolerance of added salt.

scholarly journals Aqueous solution behavior of stimulus-responsive poly(methacrylic acid)-poly(2-hydroxypropyl methacrylate) diblock copolymer nanoparticles

2020 ◽  
Vol 11 (12) ◽  
pp. 2147-2156 ◽  
Author(s):  
Shannon M. North ◽  
Steven P. Armes
Keyword(s):  
Aqueous Solution ◽  
Methacrylic Acid ◽  
Diblock Copolymer ◽  
Dispersion Polymerization ◽  
Aqueous Dispersion ◽  
Solution Temperature ◽  
Solution Ph ◽  
Solution Behavior ◽  
Hydroxypropyl Methacrylate ◽  
Stimulus Responsive

RAFT aqueous dispersion polymerization is used to prepare poly(methacrylic acid)-poly(2-hydroxypropyl methacrylate) diblock copolymer nanoparticles, which exhibit stimulus-responsive behaviour on adjusting the solution temperature and/or solution pH.

Antimicrobial polylysine decorated nano-structures prepared through polymerization induced self-assembly (PISA)

2019 ◽  
Vol 10 (3) ◽  
pp. 336-344 ◽  
Author(s):  
L. Luppi ◽  
T. Babut ◽  
E. Petit ◽  
M. Rolland ◽  
D. Quemener ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Antimicrobial Properties ◽  
Gram Positive ◽  
Gram Positive Bacteria ◽  
Nano Structures ◽  
Hydroxypropyl Methacrylate

Polylysine decorated diblock copolymer nano-objects are prepared by polymerization-induced self-assemblyviaRAFT dispersion polymerization of 2-hydroxypropyl methacrylate. Antimicrobial properties of the resulting nano-objects evaluated using a gram positive bacteria.

Efficient Synthesis of Amine-Functional Diblock Copolymer Nanoparticles via RAFT Dispersion Polymerization of Benzyl Methacrylate in Alcoholic Media

2012 ◽  
Vol 45 (12) ◽  
pp. 5091-5098 ◽  
Author(s):  
Elizabeth R. Jones ◽  
Mona Semsarilar ◽  
Adam Blanazs ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Dispersion Polymerization ◽  
Efficient Synthesis
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