Synthesis of polystyrene living nanoparticles (LNPs) in water via nano-confined free radical polymerization

2020 ◽  
Vol 11 (46) ◽  
pp. 7349-7353
Author(s):  
Wei-Ting Chang ◽  
Jyun-Hao Sie ◽  
Ya-Wen Tsai ◽  
Yi-Wei Chen ◽  
Chi-How Peng ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Chain Extension

Nano-confined free radical polymerization of styrene within the hydrophobic interior of a unimolecular micelle in water was developed to produce living nanoparticles (LNPs) that contain living mono-disperse polystyrenes for further chain extension.

Time-dependent covalent network formation in extrudable hydrogels

2020 ◽  
Vol 11 (43) ◽  
pp. 6910-6918
Author(s):  
Dylan Karis ◽  
Alshakim Nelson
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Network Formation ◽  
Free Radical Polymerization ◽  
Shear Thinning ◽  
Time Dependent ◽  
Chain Extension

Shear-thinning hydrogels that utilize thiol-Michael chain-extension and free radical polymerization have a tunable stretchability.

scholarly journals Synthesis of PMMA-based block copolymers by consecutive irreversible and reversible addition–fragmentation chain transfer polymerizations

2019 ◽  
Vol 10 (48) ◽  
pp. 6630-6640 ◽  
Author(s):  
Cédric Bergerbit ◽  
Bárbara Farías-Mancilla ◽  
Lucie Seiler ◽  
Vincent Monteil ◽  
Simon Harrisson ◽  
...  
Keyword(s):  
Free Radical ◽  
Block Copolymers ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Chain Extension ◽  
Reversible Addition

Xanthate and dithiocarbamate functionalized PMMAs obtained by free radical polymerization in the presence of xanthogen and dithiuram disulfide were used for chain extension with less activated monomers such as vinyl acetate and ethylene.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

Critically evaluated rate coefficients for free-radical polymerization, 3. Propagation rate coefficients for alkyl methacrylates

2000 ◽  
Vol 201 (12) ◽  
pp. 1355-1364 ◽  
Author(s):  
Sabine Beuermann ◽  
Michael Buback ◽  
Thomas P. Davis ◽  
Robert G. Gilbert ◽  
Robin A. Hutchinson ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Propagation Rate ◽  
Rate Coefficients ◽  
Alkyl Methacrylates

Oxygen-Initiated Free-Radical Polymerization of Alkyl Acrylates at High Temperatures

2021 ◽  
Author(s):  
Shi Liu ◽  
Lauren Chua ◽  
Ahmad Arabi Shamsabadi ◽  
Patrick Corcoran ◽  
Abhirup Patra ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
High Temperatures ◽  
Free Radical Polymerization ◽  
Alkyl Acrylates

Development of Novel Colorimetric Thermometer Based on Poly(N-vinylcaprolactam) with Push-π-Pull Tricyanofuran Hydrazone Anion Dye

2021 ◽  
Author(s):  
Meram S Abdelrahman ◽  
Tawfik A Khattab ◽  
Samir Kamel
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization

Thermochromic poly(N-vinylcaprolactam-co-tricyanofuran hydrazone) [Poly(VC-co-TCFH)] gel labeled with halochromic chromophore was developed using traditional free radical polymerization. Novel vinyl-containing tricyanofuran hydrazone (TCFH) halochromic chromophore bearing a hydrazone sensor group was generated...

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