scholarly journals Redox-controlled chalcogen and pnictogen bonding: the case of a sulfonium/stibonium dication as a preanionophore for chloride anion transport

2020 ◽  
Vol 11 (37) ◽  
pp. 10107-10112
Author(s):  
Gyeongjin Park ◽  
François P. Gabbaï
Keyword(s):  
Anion Transport ◽  
Chloride Anion ◽  
Phospholipid Membranes

We describe a sulfonium/stibonium dication that behaves as a preanionophore activatable by glutathione (GSH). Indeed, this dication is reduced by GSH to yield a thioether/stibonium monocation that readily transports Cl− across phospholipid membranes.

Chloride anion transport and copper-mediated DNA cleavage by C-ring functionalized prodigiosenes

2007 ◽  
pp. 2701-2703 ◽  
Author(s):  
Rosa I. Sáez Díaz ◽  
Jasmine Regourd ◽  
Paul V. Santacroce ◽  
Jeffery T. Davis ◽  
David L. Jakeman ◽  
...  
Keyword(s):  
Dna Cleavage ◽  
Anion Transport ◽  
Chloride Anion

scholarly journals Redox-controlled chalcogen-bonding at tellurium: impact on Lewis acidity and chloride anion transport properties

2020 ◽  
Vol 11 (28) ◽  
pp. 7495-7500 ◽  
Author(s):  
Benyu Zhou ◽  
François P. Gabbaï
Keyword(s):  
Transport Properties ◽  
Anion Transport ◽  
Chloride Anion ◽  
Lewis Acidity ◽  
Chalcogen Bond ◽  
Oxidative Alkylation

The oxidative alkylation of diorganotellurides enhances the chalcogen-bond donor properties of the tellurium center, an effect manifested in the enhanced chloride anion affinity and transport properties of the resulting telluronium cations.

Anion transport across phospholipid membranes mediated by a diphosphine–Pd(ii) complex

2014 ◽  
Vol 50 (65) ◽  
pp. 9157 ◽  
Author(s):  
Domenico Milano ◽  
Barnaba Benedetti ◽  
Mariangela Boccalon ◽  
Andrea Brugnara ◽  
Elisabetta Iengo ◽  
...  
Keyword(s):  
Anion Transport ◽  
Phospholipid Membranes

Oligoether-Strapped Calix[4]pyrrole: An Ion-Pair Receptor Displaying Cation-Dependent Chloride Anion Transport

2012 ◽  
Vol 18 (9) ◽  
pp. 2514-2523 ◽  
Author(s):  
In-Won Park ◽  
Jaeduk Yoo ◽  
Bohyang Kim ◽  
Suman Adhikari ◽  
Sung Kuk Kim ◽  
...  
Keyword(s):  
Anion Transport ◽  
Ion Pair ◽  
Chloride Anion

scholarly journals A Novel Cyclic Mobile Transporter Can Induce Apoptosis by Facilitating Chloride Anion Transport into Cells

ACS Omega ◽  
2020 ◽  
Vol 5 (27) ◽  
pp. 16395-16405
Author(s):  
Goutam Kulsi ◽  
Achinta Sannigrahi ◽  
Snehasis Mishra ◽  
Krishna Das Saha ◽  
Sriparna Datta ◽  
...  
Keyword(s):  
Anion Transport ◽  
Chloride Anion

Bicarbonate and chloride anion transport in anion exchange membranes

2016 ◽  
Vol 514 ◽  
pp. 125-134 ◽  
Author(s):  
Alina Amel ◽  
Nir Gavish ◽  
Liang Zhu ◽  
Dario R. Dekel ◽  
Michael A. Hickner ◽  
...  
Keyword(s):  
Anion Exchange ◽  
Anion Transport ◽  
Chloride Anion ◽  
Anion Exchange Membranes

scholarly journals Synthetic ion transporters can induce apoptosis by facilitating chloride anion transport into cells

2014 ◽  
Vol 6 (10) ◽  
pp. 885-892 ◽  
Author(s):  
Sung-Kyun Ko ◽  
Sung Kuk Kim ◽  
Andrew Share ◽  
Vincent M. Lynch ◽  
Jinhong Park ◽  
...  
Keyword(s):  
Anion Transport ◽  
Chloride Anion ◽  
Ion Transporters

Formation and Trapping of the Thermodynamically Unfavoured Inverted-Hemicucurbit[6]uril

2019 ◽  
Author(s):  
Elena Prigorchenko ◽  
Sandra Kaabel ◽  
Triin Narva ◽  
Anastassia Baškir ◽  
Maria Fomitšenko ◽  
...  
Keyword(s):  
Complex Formation ◽  
Combinatorial Chemistry ◽  
Trifluoroacetic Acid ◽  
Chloride Anion ◽  
Binding Affinities ◽  
Dynamic Covalent Chemistry ◽  
Reaction Selectivity ◽  
Low Concentration ◽  
Dynamic Combinatorial Chemistry ◽  
First Time

Amplification of a thermodynamically unfavoured macrocyclic product through the directed shift of the equilibrium between dynamic covalent chemistry library members is difficult to achieve. We show for the first time that during condensation of formaldehyde and <i>cis</i>-<i>N,N'</i>-cyclohexa-1,2-diylurea formation of <i>inverted-cis</i>-cyclohexanohemicucurbit[6]uril (<i>i-cis</i>-cycHC[6]) can be induced at the expense of thermodynamically favoured <i>cis</i>-cyclohexanohemicucurbit[6]uril (<i>cis</i>-cycHC[6]). The formation of <i>i-cis-</i>cycHC[6] is enhanced in low concentration of the templating chloride anion and suppressed in excess of this template. We found that reaction selectivity is governed by the solution-based template-aided dynamic combinatorial chemistry and continuous removal of the formed cycHC[6] macrocycles from the equilibrating solution by precipitation. Notably, the <i>i-cis</i>-cycHC[6] was isolated with 33% yield. Different binding affinities of three diastereomeric <i>i-cis</i>-, <i>cis</i>-cycHC[6] and their chiral isomer (<i>R,R</i>)-cycHC[6] for trifluoroacetic acid demonstrate the influence of macrocycle geometry on complex formation.

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