Efficient modulation of end groups for the asymmetric small molecule acceptors enabling organic solar cells with over 15% efficiency

2020 ◽  
Vol 8 (12) ◽  
pp. 5927-5935 ◽  
Author(s):  
Gang Li ◽  
Dandan Li ◽  
Ruijie Ma ◽  
Tao Liu ◽  
Zhenghui Luo ◽  
...  

Three asymmetric SMAs based on dithieno[3,2-b:2′,3′-d]pyrrole that exhibit a high efficiency of 15.31%, which is the highest value in asymmetric acceptor-based binary organic solar cells.

2018 ◽  
Vol 6 (47) ◽  
pp. 24267-24276 ◽  
Author(s):  
Wenhong Peng ◽  
Guangjun Zhang ◽  
Lin Shao ◽  
Chao Ma ◽  
Bin Zhang ◽  
...  

A novel strategy is proposed to construct simple-structured SMAs using a weakly electron-deficient thiazolothiazole (TTz) core. The highest PCE of 8.77% is recorded for TTz1-based OSCs, which is the highest efficiency to date among non-fullerene OSCs with simple-structured SMAs.


2018 ◽  
Vol 6 (20) ◽  
pp. 9613-9622 ◽  
Author(s):  
Yankang Yang ◽  
Beibei Qiu ◽  
Shanshan Chen ◽  
Qiuju Zhou ◽  
Ying Peng ◽  
...  

An OSC based on a small molecule DR3TBDTT as donor and n-type polymer PZ1 as acceptor was fabricated, and PCE of the device reached 5.86% which is the highest for the OSCs based small molecule donor/polymer acceptor.


2020 ◽  
Vol 63 (9) ◽  
pp. 1246-1255 ◽  
Author(s):  
Rui Sun ◽  
Yao Wu ◽  
Jing Guo ◽  
Zhenghui Luo ◽  
Chuluo Yang ◽  
...  

2020 ◽  
Vol 8 (27) ◽  
pp. 9195-9200
Author(s):  
Jun Zhang ◽  
Jie Lv ◽  
Xiyue Dong ◽  
Tongle Xu ◽  
Xuexin Dai ◽  
...  

Wide-bandgap non-fullerene acceptors (NFAs) are in high demand for constructing efficient ternary or tandem organic solar cells (OSCs), yet the scarcity of them remains an important issue that needs exploration and perfection.


Author(s):  
Ziyun Huang ◽  
Ruimin Zhou ◽  
Min Lv ◽  
Hao Zhang ◽  
Chen Yang ◽  
...  

Constructing high efficiency non-fullerene all-small-molecule ternary organic solar cells by employing structurally similar acceptors.


2020 ◽  
Vol 13 (7) ◽  
pp. 2115-2123 ◽  
Author(s):  
Tao Liu ◽  
Ruijie Ma ◽  
Zhenghui Luo ◽  
Yuan Guo ◽  
Guangye Zhang ◽  
...  

The ternary device achieved an excellent PCE of 15.02% with enhancement in both VOC and JSC by adding a red-absorbing SMA with a high LUMO level.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ruimin Zhou ◽  
Zhaoyan Jiang ◽  
Chen Yang ◽  
Jianwei Yu ◽  
Jirui Feng ◽  
...  

AbstractThe high efficiency all-small-molecule organic solar cells (OSCs) normally require optimized morphology in their bulk heterojunction active layers. Herein, a small-molecule donor is designed and synthesized, and single-crystal structural analyses reveal its explicit molecular planarity and compact intermolecular packing. A promising narrow bandgap small-molecule with absorption edge of more than 930 nm along with our home-designed small molecule is selected as electron acceptors. To the best of our knowledge, the binary all-small-molecule OSCs achieve the highest efficiency of 14.34% by optimizing their hierarchical morphologies, in which the donor or acceptor rich domains with size up to ca. 70 nm, and the donor crystals of tens of nanometers, together with the donor-acceptor blending, are proved coexisting in the hierarchical large domain. All-small-molecule photovoltaic system shows its promising for high performance OSCs, and our study is likely to lead to insights in relations between bulk heterojunction structure and photovoltaic performance.


2020 ◽  
Vol 13 (5) ◽  
pp. 1309-1317 ◽  
Author(s):  
Yulong Wang ◽  
Yang Wang ◽  
Lei Zhu ◽  
Haiqin Liu ◽  
Jin Fang ◽  
...  

A novel small molecule donor based on thiazolo[5,4-d]thiazole (TTz) unit is developed for OSCs application with 13.9% power conversion efficiency and a small non-radiative energy loss of 0.18 eV.


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