Synergism of surface strain and interfacial polarization on Pd@Au core–shell cocatalysts for highly efficient photocatalytic CO2 reduction over TiO2

2020 ◽  
Vol 8 (15) ◽  
pp. 7350-7359 ◽  
Author(s):  
Xiaotong Cai ◽  
Fang Wang ◽  
Ruoxin Wang ◽  
Yamin Xi ◽  
An Wang ◽  
...  

The synergism of surface strain and interfacial polarization has been studied on Pd@Au core–shell cocatalysts for boosting the photocatalytic performance of TiO2 in CO2-to-CO conversion.

2020 ◽  
Vol 56 (27) ◽  
pp. 3851-3854 ◽  
Author(s):  
Xiaomin Chai ◽  
Hai-Hua Huang ◽  
Huiping Liu ◽  
Zhuofeng Ke ◽  
Wen-Wen Yong ◽  
...  

A Co-based complex displayed the highest photocatalytic performance for CO2 to CO conversion in aqueous media.


RSC Advances ◽  
2015 ◽  
Vol 5 (50) ◽  
pp. 40348-40351 ◽  
Author(s):  
Shunhang Wei ◽  
Rong Wu ◽  
Jikang Jian ◽  
Juan Hou ◽  
Fengjuan Chen ◽  
...  

Graphene oxide/core–shell structured TiO2@TiO2−x nanocomposites with outstanding photocatalytic performance were prepared by combining graphene oxide and black titania.


RSC Advances ◽  
2020 ◽  
Vol 10 (45) ◽  
pp. 26639-26645
Author(s):  
Jing Jin ◽  
Wei Song ◽  
Ning Zhang ◽  
Linjia Li ◽  
Hao Liu ◽  
...  

The possible mechanism of enhanced photocatalytic performance of Ag@CDs–TiO2 hybrid NFs.


2020 ◽  
Vol 8 (32) ◽  
pp. 16616-16623
Author(s):  
Jian-Xia Gu ◽  
Xue Zhao ◽  
Yue Sun ◽  
Jie Zhou ◽  
Chun-Yi Sun ◽  
...  

A photo-activated process is cascaded to an electrocatalytic pathway for reducing CO2 to prepare syngas over core–shell ZIF-8@Co/C, exhibiting excellent electrochemical performance and achieving high joule-to-joule conversion efficiency of 5.38%.


2011 ◽  
Vol 115 (20) ◽  
pp. 10180-10186 ◽  
Author(s):  
Chi-Wen Tsai ◽  
Hao Ming Chen ◽  
Ru-Shi Liu ◽  
Kiyotaka Asakura ◽  
Ting-Shan Chan

Author(s):  
De-Huang Zhuo ◽  
Qing-Song Chen ◽  
Xiu-Hui Zhao ◽  
Yin-Long Jiang ◽  
Jian Lu ◽  
...  

Ce-Bi@CeBiOx/C with core-shell structure has been synthesized by pyrolysis of cerium doped bismuth-based metal-organic frameworks. This novel catalyst exhibits excellent performance for electrochemical CO2 reduction to formate with a maximum...


2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>


Author(s):  
Ning Zhang ◽  
Sufen Lin ◽  
Fuchen Wang ◽  
Yongdi Liu ◽  
Jinlong Zhang ◽  
...  

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