Migration of Cations in Layered Oxides for Creating Highly Active Interface toward CO Preferential Oxidation

Author(s):  
Junfang Ding ◽  
Zhibin Geng ◽  
Liping Li ◽  
Ye Wang ◽  
Ying Zuo ◽  
...  

Rationally design and integrate the collaborative active species on the interface is a crucial issue for the development of advanced materials. In this work, we present a simple interlayer cation...

Geo&Bio ◽  
2019 ◽  
Vol 2019 (17) ◽  
pp. 116-135 ◽  
Author(s):  
Vira V. Protopopova ◽  
◽  
Myroslav Shevera

Author(s):  
Liping Zhong ◽  
Mathias Barrea ◽  
Dingkai Chen ◽  
Valérie Caps ◽  
Michael Haevecker ◽  
...  

Fuel ◽  
2021 ◽  
pp. 122491
Author(s):  
Aggeliki Papavasiliou ◽  
Tim Van Everbroeck ◽  
Cataldo Blonda ◽  
Benedetta Oliani ◽  
Elias Sakellis ◽  
...  

Research ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Huanhuan Liu ◽  
Zhenhua Yan ◽  
Xiang Chen ◽  
Jinhan Li ◽  
Le Zhang ◽  
...  

The facile synthesis of highly active and stable bifunctional electrocatalysts to catalyze water splitting is attractive but challenging. Herein, we report the electrodeposition of Pt-decorated Ni(OH)2/CeO2 (PNC) hybrid as an efficient and robust bifunctional electrocatalyst. The graphite-supported PNC catalyst delivers superior hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) activities over the benchmark Pt/C and RuO2, respectively. For overall water electrolysis, the PNC hybrid only requires a cell voltage of 1.45 V at 10 mA cm−2 and sustains over 85 h at 1000 mA cm−2. The remarkable HER/OER performances are attributed to the superhydrophilicity and multiple effects of PNC, in which Ni(OH)2 and CeO2 accelerate HER on Pt due to promoted water dissociation and strong electronic interaction, while the electron-pulling Ce cations facilitate the generation of high-valence Ni OER-active species. These results suggest the promising application of PNC for H2 production from water electrolysis.


2021 ◽  
Vol 484 ◽  
pp. 229181
Author(s):  
Yuhui Zhao ◽  
Kezhen Chen ◽  
Qin Zou ◽  
Jian Fang ◽  
Songshan Zhu ◽  
...  

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