A ring of grids: a giant spin-crossover cluster

2021 ◽  
Author(s):  
Takuya Shiga ◽  
Minami Tachibana ◽  
Hajime Sagayama ◽  
Reiji Kumai ◽  
Graham N. Newton ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Ring Shape ◽  
Shape Structure ◽  
Spin Crossover Complexes

II20 Mononuclear and icosanuclear spin-crossover complexes, [Fe] and [Fe20], were synthesized. [Fe] has a bis-chelate structure, while [Fe20] has a ring-shape structure comprising four [2 × 2] grid moieties and four mononuclear units.

A New Family of Anionic FeIII Spin Crossover Complexes Featuring a Weak-Field N2 O4 Coordination Octahedron

2015 ◽  
Vol 22 (4) ◽  
pp. 1253-1257 ◽  
Author(s):  
Kazuyuki Takahashi ◽  
Kiko Kawamukai ◽  
Mitsunobu Okai ◽  
Tomoyuki Mochida ◽  
Takahiro Sakurai ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Weak Field ◽  
New Family ◽  
Spin Crossover Complexes

On the Mechanism of Ring-Shape Structure of Plasma Bullet

2014 ◽  
Vol 11 (12) ◽  
pp. 1169-1174 ◽  
Author(s):  
YuBin Xian ◽  
YuanFu Yue ◽  
DaWei Liu ◽  
Yong Yang ◽  
XinPei Lu ◽  
...  
Keyword(s):  
Ring Shape ◽  
Shape Structure

Relevance of supramolecular interactions, texture and lattice occupancy in the designer iron(II) spin crossover complexes

2009 ◽  
Vol 182 (6) ◽  
pp. 1365-1376 ◽  
Author(s):  
Anil D. Naik ◽  
Bernard Tinant ◽  
Kai Muffler ◽  
Juliusz A. Wolny ◽  
Volker Schünemann ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Supramolecular Interactions ◽  
Spin Crossover Complexes

Asymmetric Design of Spin-Crossover Complexes to Increase the Volatility for Surface Deposition

2021 ◽  
Author(s):  
Miguel Gakiya-Teruya ◽  
Xuanyuan Jiang ◽  
Duy Le ◽  
Ökten Üngör ◽  
Abdullah J. Durrani ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Surface Deposition ◽  
Spin Crossover Complexes

Targeted structural modification of spin crossover complexes: pyridine vs pyrazine

2017 ◽  
Vol 30 (4) ◽  
pp. 296-304 ◽  
Author(s):  
Humphrey L. C. Feltham ◽  
Matthew G. Cowan ◽  
Jonathan A. Kitchen ◽  
Guy N. L. Jameson ◽  
Sally Brooker
Keyword(s):  
Structural Modification ◽  
Spin Crossover ◽  
Spin Crossover Complexes

scholarly journals CASPT2 molecular geometries of Fe(II) spin-crossover complexes

2021 ◽  
Author(s):  
Brian A. Finney ◽  
Sabyasachi Roy Chowdhury ◽  
Clara Kirkvold ◽  
Bess Vlaisavljevich
Keyword(s):  
Spin Crossover ◽  
Spin Crossover Complexes ◽  
Analytical Gradients

Using fully internally contracted (FIC)-CASPT2 analytical gradients, geometry optimizations of spin-crossover complexes are reported. This approach is tested on a series of Fe(II) complexes with different sizes, ranging from 13...

Preparation of dihydroquinazoline carbohydrazone Fe(ii) complexes for spin crossover

2016 ◽  
Vol 40 (5) ◽  
pp. 4534-4542 ◽  
Author(s):  
Fu-Xing Shen ◽  
Wei Huang ◽  
Takashi Yamamoto ◽  
Yasuaki Einaga ◽  
Dayu Wu
Keyword(s):  
Spin Crossover ◽  
Spin Crossover Complexes

Mononuclear spin-crossover complexes of dihydroquinazoline derivatives were synthesized to enable the spin crossover phenomenon via the variation of the solvent, anion and substituent.

Sign in / Sign up

Export Citation Format

Share Document