Near-Infrared Vapochromism in Lipid-Packaged Mixed-Valence Coordination Polymers

Chemical Communications ◽

10.1039/d1cc06723k ◽

2022 ◽

Author(s):

Yuki Nagai ◽

Masa-aki Morikawa ◽

Nobuo Kimizuka

Keyword(s):

Coordination Polymers ◽

Molecular Orientation ◽

Near Infrared ◽

Mixed Valence ◽

Platinum Complex ◽

Crystallization Water ◽

Organic Vapor

Reversible vapochromism in the NIR region is achieved for a mixed-valence platinum complex with lipid counterions, from which exclusion of crystallization water by organic vapor alters lipid molecular orientation that...

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Rare Self-Luminous Mixed-Valence Eu-MOF with a Self-Enhanced Characteristic as a Near-Infrared Fluorescent ECL Probe for Nondestructive Immunodetection

Analytical Chemistry ◽

10.1021/acs.analchem.1c01531 ◽

2021 ◽

Author(s):

Lu Zhao ◽

Xianzhen Song ◽

Xiang Ren ◽

Dawei Fan ◽

Qin Wei ◽

...

Keyword(s):

Near Infrared ◽

Mixed Valence

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Orthogonal electronic coupling in multicentre arylamine mixed-valence compounds based on a dibenzofulvene–thiophene conjugated bridge

Chemical Communications ◽

10.1039/c7cc03156d ◽

2017 ◽

Vol 53 (64) ◽

pp. 8960-8963 ◽

Cited By ~ 11

Author(s):

A. Beneduci ◽

G. A. Corrente ◽

E. Fabiano ◽

V. Maltese ◽

S. Cospito ◽

...

Keyword(s):

Near Infrared ◽

Mixed Valence ◽

Infrared Region ◽

Optical Modulation ◽

Electronic Coupling ◽

Voltage Dependent ◽

Near Infrared Region ◽

Mixed Valence Compounds

Novel H-shaped tetrarylamine mixed valence compounds showing orthogonal electronic coupling generate voltage-dependent electro-optical modulation in the near infrared region.

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Syntheses, structures and near-infrared luminescent properties of a series of Ln(III) coordination polymers

Journal of Molecular Structure ◽

10.1016/j.molstruc.2012.02.069 ◽

2012 ◽

Vol 1018 ◽

pp. 122-130 ◽

Cited By ~ 9

Author(s):

Yu-Xian Chi ◽

Yu-Juan Liu ◽

Ye Li ◽

Ru Wang ◽

Jing Jin ◽

...

Keyword(s):

Coordination Polymers ◽

Near Infrared ◽

Luminescent Properties

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Dye-sensitized Solar Cells with Halide-bridged Mixed-valence Cu(I)–Cu(II) Coordination Polymers with Hexamethylenedithiocarbamate Ligand

Chemistry Letters ◽

10.1246/cl.2010.792 ◽

2010 ◽

Vol 39 (7) ◽

pp. 792-793 ◽

Cited By ~ 20

Author(s):

Kyung Ho Kim ◽

Takashi Okubo ◽

Naoya Tanaka ◽

Naoto Mimura ◽

Masahiko Maekawa ◽

...

Keyword(s):

Solar Cells ◽

Coordination Polymers ◽

Mixed Valence ◽

Dye Sensitized Solar Cells ◽

Dye Sensitized ◽

Sensitized Solar Cells

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Two mixed-valence copper(i,ii) imidazolate coordination polymers: metal-valence tuning approach for new topological structuresElectronic supplementary information (ESI) available: Synthesis and additional plots for 1 and 2. See http://www.rsc.org/suppdata/cc/b4/b401691b/

Chemical Communications ◽

10.1039/b401691b ◽

2004 ◽

pp. 1100 ◽

Cited By ~ 98

Author(s):

Xiao-Chun Huang ◽

Jie-Peng Zhang ◽

Yan-Yong Lin ◽

Xiao-Lan Yu ◽

Xiao-Ming Chen

Keyword(s):

Coordination Polymers ◽

Mixed Valence ◽

Supplementary Information

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Visible to Near-Infrared Ultrafast Spectroscopy of a Quasi-One-Dimensional Halogen-Bridged Mixed-Valence Metal Complex [Pt(en)2][Pt(en)2Cl2](ClO4)4

The Journal of Physical Chemistry A ◽

10.1021/jp003651q ◽

2002 ◽

Vol 106 (4) ◽

pp. 581-588 ◽

Cited By ~ 1

Author(s):

Atsushi Sugita ◽

Tomoshige Furuhi ◽

Masahiro Yamashita ◽

Takayoshi Kobayashi

Keyword(s):

Metal Complex ◽

Ultrafast Spectroscopy ◽

Near Infrared ◽

Mixed Valence ◽

One Dimensional

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Molecular isomeric engineering of naphthyl-quinoline-containing dinuclear platinum complexes to tune emission from deep red to near infrared

Journal of Materials Chemistry C ◽

10.1039/c8tc05263h ◽

2019 ◽

Vol 7 (3) ◽

pp. 630-638 ◽

Cited By ~ 11

Author(s):

Wenjing Xiong ◽

Fanyuan Meng ◽

Caifa You ◽

Pu Wang ◽

Junting Yu ◽

...

Keyword(s):

Near Infrared ◽

Platinum Complex ◽

Platinum Complexes ◽

Dinuclear Platinum ◽

Dinuclear Platinum Complex ◽

Dinuclear Platinum Complexes ◽

Tunable Emission

A type of isomeric dinuclear platinum complex of (C^N)2Pt2(μ-C8PhOXT)2 is synthesized with different C^N isomers of naphthyl-quinoline. These complexes exhibit tunable emission with different emissive efficiencies.

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Intervalence transfer in a new benzotriazolate bridged ruthenium-iron complex

Canadian Journal of Chemistry ◽

10.1139/v00-195 ◽

2001 ◽

Vol 79 (2) ◽

pp. 145-156

Author(s):

Reginaldo C Rocha ◽

Henrique E Toma

Keyword(s):

Near Infrared ◽

Mixed Valence ◽

Differential Pulse ◽

Iron Complex ◽

Electronic Coupling ◽

Near Ir ◽

Metal Metal ◽

Dinuclear Ruthenium ◽

Pulse Voltammetry ◽

Transfer Properties

The unsymmetrical dinuclear rutheniumiron complexes [(NH3)5RubtaFe(CN)5]n (where bta = benzotriazolate; n = 2, 1, 0) were prepared as solid sodium salts from [RuII(NH3)5(bta)]+ or [RuIII(NH3)5(bta)]2+ and [FeII(CN)5(H2O)]3 and characterized in aqueous solution by means of electrochemical and spectroelectrochemical methods. UV-vis, near-infrared, IR, and cyclic and differential pulse voltammetry data suggest that the related mixed valent species belong to a valence trapped formulation, featuring localized Ru(III) and Fe(II) oxidation states. In spite of the class II categorization in the Robin and Day scheme, this system shows a remarkable metalmetal electronic coupling, as deduced from an intense, low-energy, and very broad intervalence band in the near-IR region. In addition, the mixed valence state displays enhanced stabilization in relation to the isovalent state. The intervalence transfer properties are discussed on the basis of Hush's theory.Key words: ammineruthenium complexes, cyanoiron complexes, mixed valence, intervalence, benzotriazole, benzotriazolate.

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