Photo-responsive Schottky Diode Behavior of a Donor-Acceptor Co-crystal with Violet Blue Light Emission

CrystEngComm ◽  
2021 ◽  
Author(s):  
Sanjay Kumar ◽  
Soumen Singha ◽  
Rajkumar Jana ◽  
RITUPARNA MONDAL ◽  
Partha Pratim Bag ◽  
...  

Herein, we report the crystal structure, supramolecular structure, electronic transport property and optoelectronic behaviour of a co-crystal made of tetrabromoterephthalic acid (TBTA) and quinoxaline (QUIN) (1:1). The sample has been...

2011 ◽  
Vol 58 (4) ◽  
pp. 792-796 ◽  
Author(s):  
Hiroaki Yamada ◽  
Tadahiro Fukushima ◽  
Takeshi Yoshimura ◽  
Norifumi Fujimura

2018 ◽  
Vol 30 (11) ◽  
pp. 115001 ◽  
Author(s):  
Liwei Jiang ◽  
Lanting Feng ◽  
Haibo Yao ◽  
Yisong Zheng

1998 ◽  
Vol 53 (9) ◽  
pp. 1021-1030 ◽  
Author(s):  
Steffen Runge ◽  
Mathias O. Senge

Abstract A series of 5-(benzoquinone)-10,15,20-trialkylporphyrins was synthesized via cross condensation of the respective aldehydes, 2,5-dimethoxybenzaldehyde and pyrrole followed by demethylation with BBr3 and oxidation with PbO2. This method worked reasonably well for compounds bearing the benzoquinone substituent and butyl, isopropyl, 1 -methylpropyl and 2-ethylpropyl residues (2a-d). The free base porphyrin quinones were converted into the zinc(II) complexes (3a-d) all of which showed remarkable stability for porphyrin quinones. The zinc(II) complex 3c bearing isopropyl residues was investigated by X-ray crystallography and showed a supramolecular structure consisting of polymeric chains facilitated by coordina­tion of a benzoquinone oxygen to a neighboring zinc(II) center. Attempts to synthesize a 5-(benzoquinone)-10,15,20-tris(terr-butylporphyrin) resulted in the formation of a yellow porphomethene (4), which could not be oxidized further. A crystal structure analysis of 4, the first for a free base porphomethene, shows an extremely twisted conformation with syn-orientation of the three tert-butyl groups. The results indicate that new methods will have to be developed for the synthesis of nonplanar porphyrin quinones.


2005 ◽  
Vol 105 (1-4) ◽  
pp. 293-298 ◽  
Author(s):  
Qunxiang Li ◽  
Xiaojun Wu ◽  
Jing Huang ◽  
Jinlong Yang

1994 ◽  
Vol 235-240 ◽  
pp. 1323-1324
Author(s):  
J-D. Yu ◽  
M. Itoh ◽  
T. Huang ◽  
Y. Inaguma ◽  
T. Nakamura

2008 ◽  
Vol 22 (03) ◽  
pp. 247-256 ◽  
Author(s):  
SANTANU K. MAITI

Quantum transport for different models of isomer molecules attached with two semi-infinite leads is studied on the basis of the Green's function technique. The electronic transport property is strongly affected by (a) the relative position of the atoms in these molecules and (b) the molecular coupling strength with the leads.


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