Multifunctionality of weak ferromagnetic porphyrin-based MOF: selective adsorption in liquid and gas phase

CrystEngComm ◽  
2021 ◽  
Author(s):  
Eder Amayuelas López ◽  
Paul Iacomi ◽  
Arkaitz Fidalgo-Marijuan ◽  
Begoña Bazan ◽  
Miren-Karmele Urtiaga ◽  
...  
Keyword(s):  
Gas Phase ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Multifunctional Materials ◽  
Design And Development ◽  
Framework Design ◽  
Metal Organic ◽  
Possibility Space ◽  
Environmental Level ◽  
Weak Ferromagnetic

In the endless possibility space of metal organic framework design and development, the quest for new multifunctional materials with desirable properties is still ongoing. At the environmental level, their development...

Selective adsorption and separation of C2 hydrocarbons in a “flexible-robust” metal–organic framework based on a guest-dependent gate-opening effect

2020 ◽  
Vol 56 (41) ◽  
pp. 5520-5523
Author(s):  
Peng-Dan Zhang ◽  
Xue-Qian Wu ◽  
Tao He ◽  
Lin-Hua Xie ◽  
Qiang Chen ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
C2 Hydrocarbons ◽  
Organic Framework

The selective adsorption and separation of C2 hydrocarbons have been achieved in a “flexible-robust” MOF based on a guest-dependent gate-opening effect.

A Zn(II)-based pillar-layered metal–organic framework: Synthesis, structure, and CO2 selective adsorption

Polyhedron ◽  
2019 ◽  
Vol 158 ◽  
pp. 283-289 ◽  
Author(s):  
Ya-Huan Zhang ◽  
Jinquan Bai ◽  
Ya Chen ◽  
Xiang-Jing Kong ◽  
Tao He ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Selective adsorption behaviour of carbon dioxide in OH-functionalized metal–organic framework materials

CrystEngComm ◽  
2017 ◽  
Vol 19 (36) ◽  
pp. 5346-5350 ◽  
Author(s):  
Jinjie Qian ◽  
Jinni Shen ◽  
Qipeng Li ◽  
Yue Hu ◽  
Shaoming Huang
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Adsorption Behaviour ◽  
Weak Hydrogen Bond ◽  
Oh Groups ◽  
Framework Materials ◽  
Metal Organic

The theoretically optimal adsorption locations in hydroxyl (OH)-decorated metal–organic frameworks show that the captured CO2 molecules interact with the cis-μ2-OH groups in an end-on mode, which shows a moderate to weak hydrogen bond.

scholarly journals Band Gap Modulation in Zirconium-Based Metal-Organic Frameworks by Defect Engineering

2019 ◽  
Author(s):  
Marco Taddei ◽  
Giulia M. Schukraft ◽  
Michael E. A. Warwick ◽  
Davide Tiana ◽  
Matthew McPherson ◽  
...  
Keyword(s):  
Band Gap ◽  
Gas Phase ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Benzoic Acids ◽  
Defect Engineering ◽  
Metal Organic ◽  
Band Gap Modulation ◽  
Valence Band Energy ◽  
Defective Sites

We report a defect-engineering approach to modulate the band gap of zirconium-based metal-organic framework UiO-66, enabled by grafting of a range of amino-functionalised benzoic acids at defective sites. Defect engineered MOFs were obtained by both post-synthetic exchange and modulated synthesis, featuring band gap in the 4.1-3.3 eV range. Ab-initio calculations suggest that shrinking of the band gap is mainly due to an upward shift of the valence band energy, as a result of the presence of light-absorbing monocarboxylates. The photocatalytic properties of defect-engineered MOFs towards CO<sub>2</sub> reduction to CO in the gas phase and degradation of Rhodamine B in water were tested, observing improved activity in both cases, in comparison to a defective UiO-66 bearing formic acid as the defect-compensating species.

Nanoporous Cu(I) Metal-Organic Framework: Selective Adsorption of Benzene and Luminescence Sensing of Nitroaromatics

2017 ◽  
Vol 2 (10) ◽  
pp. 3200-3206 ◽  
Author(s):  
Atanu Santra ◽  
Maria Francis ◽  
Srinivasulu Parshamoni ◽  
Sanjit Konar
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Revisiting the MIL-101 Metal-Organic Framework: Design, Synthesis, Modifications, Advances, and Recent Applications

2021 ◽  
Author(s):  
Mahmoud Yosry Zorainy ◽  
Mohamed Ibrahim Garalalm Alkalla ◽  
Serge Kaliaguine ◽  
Daria Camilla Camilla Boffito
Keyword(s):  
Materials Science ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Science And Engineering ◽  
Design Synthesis ◽  
Framework Design ◽  
Metal Organic ◽  
Materials Science And Engineering ◽  
Organic Framework

Metal-organic frameworks (MOFs) have expanded into a burgeoning topic in materials science and engineering. Their success mostly stems from the versatility of their structure that can be diversely designed by...

A novel sustainable metal organic framework as the ultimate aqueous phase sensor for natural hazards: detection of nitrobenzene and F− at the ppb level and rapid and selective adsorption of methylene blue

CrystEngComm ◽  
2020 ◽  
Vol 22 (22) ◽  
pp. 3891-3909 ◽  
Author(s):  
Mantasha I. ◽  
M. Shahid ◽  
Hatem A. M. Saleh ◽  
Khalil M. A. Qasem ◽  
Musheer Ahmad
Keyword(s):  
Methylene Blue ◽  
Natural Hazards ◽  
Aqueous Phase ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Sensing Properties ◽  
Metal Organic ◽  
Phase Sensor ◽  
Organic Framework

A novel metal organic framework (MOF) exhibits good aqueous phase sensing properties towards nitrobenzene and fluoride anions and selective adsorption/separation ability for methylene blue.

A composite metal-organic framework material with high selective adsorption for dibenzothiophene

2019 ◽  
Vol 30 (6) ◽  
pp. 1310-1314 ◽  
Author(s):  
Xu Guan ◽  
Yan Wang ◽  
Wangfeng Cai
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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