Selective adsorption behaviour of carbon dioxide in OH-functionalized metal–organic framework materials

CrystEngComm ◽  
2017 ◽  
Vol 19 (36) ◽  
pp. 5346-5350 ◽  
Author(s):  
Jinjie Qian ◽  
Jinni Shen ◽  
Qipeng Li ◽  
Yue Hu ◽  
Shaoming Huang
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Adsorption Behaviour ◽  
Weak Hydrogen Bond ◽  
Oh Groups ◽  
Framework Materials ◽  
Metal Organic

The theoretically optimal adsorption locations in hydroxyl (OH)-decorated metal–organic frameworks show that the captured CO2 molecules interact with the cis-μ2-OH groups in an end-on mode, which shows a moderate to weak hydrogen bond.

Metal–organic frameworks for radionuclide sequestration from aqueous solution: a brief overview and outlook

2017 ◽  
Vol 46 (47) ◽  
pp. 16381-16386 ◽  
Author(s):  
Chengliang Xiao ◽  
Mark A. Silver ◽  
Shuao Wang
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

137Cs, 90Sr, 238U, 79Se, and 99Tc sequestrations from aqueous solution by metal–organic framework materials are summarized in this Frontier article.

Novel metal–organic framework materials: blends, liquids, glasses and crystal–glass composites

2019 ◽  
Vol 55 (60) ◽  
pp. 8705-8715 ◽  
Author(s):  
Joshua M. Tuffnell ◽  
Christopher W. Ashling ◽  
Jingwei Hou ◽  
Shichun Li ◽  
Louis Longley ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Crystal Glass ◽  
Zeolitic Imidazolate Framework ◽  
Feature Article ◽  
Glass Composites ◽  
Framework Materials ◽  
Recent Advances ◽  
Metal Organic ◽  
Organic Framework

This Feature Article reviews a range of amorphisation mechanisms of Metal–Organic Frameworks (MOFs) and presents recent advances to produce novel MOF materials including porous MOF glasses, MOF crystal–glass composites, flux melted MOF glasses and blended zeolitic imidazolate framework glasses.

Synthesis of a honeycomb-like Cu-based metal–organic framework and its carbon dioxide adsorption behaviour

2013 ◽  
Vol 42 (7) ◽  
pp. 2392-2398 ◽  
Author(s):  
Raúl Sanz ◽  
Fernando Martínez ◽  
Gisela Orcajo ◽  
Lukasz Wojtas ◽  
David Briones
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Framework ◽  
Adsorption Behaviour ◽  
Carbon Dioxide Adsorption ◽  
Metal Organic ◽  
Organic Framework

Metal–organic frameworks utilising an interlocked, hexadentate linker containing a tetra-carboxylate axle and a bis(pyridine) wheel

2017 ◽  
Vol 46 (8) ◽  
pp. 2462-2470 ◽  
Author(s):  
Ghazale Gholami ◽  
Giorgio Baggi ◽  
Kelong Zhu ◽  
Stephen J. Loeb
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

A mechanically interlocked ligand which combines an H-shaped axle containing four terminal 3-carboxyphenyl groups and a macrocyclic wheel with two 4-pyridyl groups was used to create Zn(ii) and Cu(ii) metal–organic framework materials that contain unique frameworks threaded solely due to the interpenetrated nature of the linker.

scholarly journals Enhanced CO2 adsorption capacity of amine-functionalized MIL-100(Cr) metal–organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 430-437 ◽  
Author(s):  
Carlos Palomino Cabello ◽  
Gloria Berlier ◽  
Giuliana Magnacca ◽  
Paolo Rumori ◽  
Gemma Turnes Palomino
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Capacity ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Sorption Properties ◽  
Amine Functionalized ◽  
Carbon Dioxide Sorption ◽  
Metal Organic ◽  
Co2 Adsorption Capacity

Functionalization of the MIL-100(Cr) metal–organic framework with alkylamines (ethylenediamine and N,N′-dimethylethylenediamine) improves carbon dioxide sorption properties, especially in the case of ethylenediamine.

Carbon capture and conversion using metal–organic frameworks and MOF-based materials

2019 ◽  
Vol 48 (10) ◽  
pp. 2783-2828 ◽  
Author(s):  
Meili Ding ◽  
Robinson W. Flaig ◽  
Hai-Long Jiang ◽  
Omar M. Yaghi
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Structure Property ◽  
Property Relationship ◽  
Recent Advances ◽  
Structure Property Relationship ◽  
Metal Organic

This review summarizes recent advances and highlights the structure–property relationship on metal–organic framework-based materials for carbon dioxide capture and conversion.

Excellent photoreduction performance of Cr(vi) over (WO4)2−-doped metal organic framework materials

2020 ◽  
Vol 44 (47) ◽  
pp. 20704-20714
Author(s):  
Xinyun Zhao ◽  
Lamei Wu ◽  
Xi Chen ◽  
Juncheng Hu ◽  
Tsung-hsueh Wu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

Negatively charged (WO4)2− anions doped into 2D layered metal organic frameworks bismuth terephthalate provides a valuable strategy for excellent photoreduction of Cr(vi).

Selective Dual Adsorption Performance of Hexagonal Porous Metal-Organic Framework Rods towards CO2 gas and Organic Dye

2021 ◽  
Author(s):  
Hridoy Jyoti Bora ◽  
Neelotpal Sen Sarma ◽  
Anamika Kalita
Keyword(s):  
Carbon Dioxide ◽  
Present Report ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Adsorption Properties ◽  
Organic Dye ◽  
Co2 Gas ◽  
Adsorption Performance ◽  
Metal Organic

Structurally diverse metal-organic frameworks (MOFs) have drawn much attention as potential adsorbent for many contaminants. Herein, the present report demonstrated the enhanced dual adsorption properties of environmentally concerned carbon dioxide...

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