Thermal decomposition of cyclohexane by flash pyrolysis vacuum ultraviolet photoionization time-of-flight mass spectrometry: a study on the initial unimolecular decomposition mechanism
Keyword(s):
Cyclohexane decomposes mainly via C–C bond rupture producing 1,6-hexyl diradical. The diradical leads to 1-hexene and can also directly dissociate. C6H12 does not decompose to ˙C6H11 + H. Benzene can be formed via sequential H2 eliminations of C6H12.
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