Probing thermal decomposition mechanism of molten nitrite/nitrates salt by time of flight mass spectrometry

Solar Energy ◽  
2019 ◽  
Vol 183 ◽  
pp. 823-828 ◽  
Author(s):  
Zejie Fei ◽  
Yu Zhang ◽  
Min Ge ◽  
Yongtian Wang ◽  
Yanli Li ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Thermal Decomposition ◽  
Time Of Flight ◽  
Decomposition Mechanism ◽  
Thermal Decomposition Mechanism ◽  
Flight Mass Spectrometry

scholarly journals Thermal decomposition of cyclohexane by flash pyrolysis vacuum ultraviolet photoionization time-of-flight mass spectrometry: a study on the initial unimolecular decomposition mechanism

2021 ◽  
Vol 23 (16) ◽  
pp. 9804-9813
Author(s):  
Kuanliang Shao ◽  
Xinghua Liu ◽  
Paul J. Jones ◽  
Ge Sun ◽  
Mariah Gomez ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Thermal Decomposition ◽  
Vacuum Ultraviolet ◽  
Time Of Flight ◽  
Decomposition Mechanism ◽  
Bond Rupture ◽  
Unimolecular Decomposition ◽  
Flash Pyrolysis ◽  
Flight Mass Spectrometry

Cyclohexane decomposes mainly via C–C bond rupture producing 1,6-hexyl diradical. The diradical leads to 1-hexene and can also directly dissociate. C6H12 does not decompose to ˙C6H11 + H. Benzene can be formed via sequential H2 eliminations of C6H12.

scholarly journals Study of the thermal decomposition mechanism of FOX-7 by molecular dynamics simulation and online photoionization mass spectrometry

RSC Advances ◽  
2020 ◽  
Vol 10 (36) ◽  
pp. 21147-21157
Author(s):  
Liping Jiang ◽  
Xiaolong Fu ◽  
Zhongyue Zhou ◽  
Chongmin Zhang ◽  
Jizhen Li ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Molecular Dynamics ◽  
Thermal Decomposition ◽  
Molecular Dynamics Simulation ◽  
Molecular Dynamics Simulations ◽  
Decomposition Mechanism ◽  
Dynamics Simulation ◽  
Thermal Decomposition Mechanism ◽  
Photoionization Mass Spectrometry ◽  
Dynamics Simulations

In this work, the primary thermal decomposition mechanism of 1,1-diamino-2,2-dinitroethylene (FOX-7) was studied by ReaxFF molecular dynamics simulations and online photoionization mass spectrometry.

Mechanism of the thermal decomposition of tetramethylsilane: a flash pyrolysis vacuum ultraviolet photoionization time-of-flight mass spectrometry and density functional theory study

2018 ◽  
Vol 20 (27) ◽  
pp. 18782-18789 ◽  
Author(s):  
Xinghua Liu ◽  
Jingsong Zhang ◽  
Alexis Vazquez ◽  
Daxi Wang ◽  
Shuyuan Li
Keyword(s):  
Mass Spectrometry ◽  
Density Functional Theory ◽  
Thermal Decomposition ◽  
Density Functional ◽  
Vacuum Ultraviolet ◽  
Time Of Flight ◽  
Density Functional Theory Study ◽  
Functional Theory ◽  
Flash Pyrolysis ◽  
Flight Mass Spectrometry

Silene/silyene conversion via 1,2-shift plays an important role in H2 elimination in the process of the thermal decomposition of tetramethylsilane.

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