Extension of van der Waals theory for supersaturated thin films

The vapor/liquid interface properties play an essential role in both fundamental models and practical applications. Here, we describe a thin planar film surrounded by supersaturated vapor using the extension of...

WITHDRAWN: On the van der Waals Theory of the Vapor–Liquid Equilibrium. I. Discussion of a One-Dimensional Model

Mathematical Physics in One Dimension ◽

10.1016/b978-0-12-448750-5.50010-4 ◽

1966 ◽

pp. 53-65

Author(s):

M. KAC ◽

G.E. UHLENBECK ◽

P.C. HEMMER

Keyword(s):

Van Der Waals ◽

Dimensional Model ◽

Liquid Equilibrium ◽

One Dimensional ◽

Van Der Waals Theory ◽

On the van der Waals Theory of the Vapor‐Liquid Equilibrium. I. Discussion of a One‐Dimensional Model

10.1063/1.1703946 ◽

1963 ◽

Vol 4 (2) ◽

pp. 216-228 ◽

Cited By ~ 580

Author(s):

M. Kac ◽

G. E. Uhlenbeck ◽

P. C. Hemmer

Keyword(s):

Van Der Waals ◽

Dimensional Model ◽

Liquid Equilibrium ◽

One Dimensional ◽

Van Der Waals Theory ◽

Molecular Dynamics Simulations of Vapor–Liquid Interface Properties of n-Heptane/Nitrogen at Subcritical and Transcritical Conditions

The Journal of Physical Chemistry B ◽

10.1021/acs.jpcb.1c03037 ◽

2021 ◽

Author(s):

Suman Chakraborty ◽

Haiwen Ge ◽

Li Qiao

Keyword(s):

Molecular Dynamics ◽

Molecular Dynamics Simulations ◽

Liquid Interface ◽

Interface Properties ◽

Dynamics Simulations ◽

WITHDRAWN: On the van der Waals Theory of the Vapor–Liquid Equilibrium. III. Discussion of the Critical Region

Mathematical Physics in One Dimension ◽

10.1016/b978-0-12-448750-5.50011-6 ◽

1966 ◽

pp. 66-80

Author(s):

P.C. HEMMER ◽

M. KAC ◽

G.E. UHLENBECK

Keyword(s):

Critical Region ◽

Van Der Waals ◽

Liquid Equilibrium ◽

Van Der Waals Theory ◽

On the van der Waals Theory of the Vapor‐Liquid Equilibrium. III. Discussion of the Critical Region

10.1063/1.1704065 ◽

1964 ◽

Vol 5 (1) ◽

pp. 60-74 ◽

Cited By ~ 116

Author(s):

P. C. Hemmer ◽

M. Kac ◽

G. E. Uhlenbeck

Keyword(s):

Critical Region ◽

Van Der Waals ◽

Liquid Equilibrium ◽

Van Der Waals Theory ◽

On the van der Waals Theory of the Vapor‐Liquid Equilibrium. IV. The Pair Correlation Function and Equation of State for Long‐Range Forces

10.1063/1.1704066 ◽

1964 ◽

Vol 5 (1) ◽

pp. 75-84 ◽

Cited By ~ 115

Author(s):

P. C. Hemmer

Keyword(s):

Correlation Function ◽

Equation Of State ◽

Long Range ◽

Pair Correlation Function ◽

Pair Correlation ◽

Van Der Waals ◽

Liquid Equilibrium ◽

Van Der Waals Theory ◽

On the van der Waals Theory of the Vapor‐Liquid Equilibrium. II. Discussion of the Distribution Functions

10.1063/1.1703947 ◽

1963 ◽

Vol 4 (2) ◽

pp. 229-247 ◽

Cited By ~ 108

Author(s):

G. E. Uhlenbeck ◽

P. C. Hemmer ◽

M. Kac

Keyword(s):

Van Der Waals ◽

Distribution Functions ◽

Liquid Equilibrium ◽

Van Der Waals Theory ◽

Applications of the augmented van der waals theory of fluids

Journal de Chimie Physique ◽

10.1051/jcp/1978750347 ◽

1978 ◽

Vol 75 ◽

pp. 347-352 ◽

Cited By ~ 11

Author(s):

Aleksander Kreglewski ◽

Stephen S. Chen

Keyword(s):

Van Der Waals ◽

Van Der Waals Theory

A SIMPLIFIED SOLUTION FOR TRANSIENT FILM BOILING WITH CONSTANT HEAT FLUX (Heat Transfer from a Vapor Liquid Interface)

10.1615/ihtc4.360 ◽

1970 ◽

Author(s):

Thomas W. Jackson ◽

Howard H. Yen

Keyword(s):

Heat Transfer ◽

Heat Flux ◽

Constant Heat Flux ◽

Liquid Interface ◽

Film Boiling ◽

Constant Heat ◽

Simplified Solution ◽

Thermodynamic Stability of Hexagonal and Rhombohedral Bn at Cvd Conditions from Van der Waals Corrected First Principles Calculations

10.26434/chemrxiv.8052218.v3 ◽

2019 ◽

Author(s):

Henrik Pedersen ◽

Björn Alling ◽

Hans Högberg ◽

Annop Ektarawong

Keyword(s):

Thin Films ◽

Thermodynamic Stability ◽

First Principles ◽

Thermal Equilibrium ◽

Density Functional ◽

Van Der Waals ◽

Chemical Vapor ◽

First Principles Calculations ◽

Functional Theory ◽

The Stability

Thin films of boron nitride (BN), particularly the sp<sup>2</sup>-hybridized polytypes hexagonal BN (h-BN) and rhombohedral BN (r-BN) are interesting for several electronic applications given band gaps in the UV. They are typically deposited close to thermal equilibrium by chemical vapor deposition (CVD) at temperatures and pressures in the regions 1400-1800 K and 1000-10000 Pa, respectively. In this letter, we use van der Waals corrected density functional theory and thermodynamic stability calculations to determine the stability of r-BN and compare it to that of h-BN as well as to cubic BN and wurtzitic BN. We find that r-BN is the stable sp<sup>2</sup>-hybridized phase at CVD conditions, while h-BN is metastable. Thus, our calculations suggest that thin films of h-BN must be deposited far from thermal equilibrium.