Magnonic superradiant phase transition

In the superradiant phase transition (SRPT), coherent light and matter fields are expected to appear spontaneously in a coupled light–matter system in thermal equilibrium. However, such an equilibrium SRPT is forbidden in the case of charge-based light–matter coupling, known as no-go theorems. Here, we show that the low-temperature phase transition of ErFeO3 at a critical temperature of approximately 4 K is an equilibrium SRPT achieved through coupling between Fe3+ magnons and Er3+ spins. By verifying the efficacy of our spin model using realistic parameters evaluated via terahertz magnetospectroscopy and magnetization experiments, we demonstrate that the cooperative, ultrastrong magnon–spin coupling causes the phase transition. In contrast to prior studies on laser-driven non-equilibrium SRPTs in atomic systems, the magnonic SRPT in ErFeO3 occurs in thermal equilibrium in accordance with the originally envisioned SRPT, thereby yielding a unique ground state of a hybrid system in the ultrastrong coupling regime.

Dynamics of Open Quantum Systems II, Markovian Approximation

A finite-dimensional quantum system is coupled to a bath of oscillators in thermal equilibrium at temperature T>0. We show that for fixed, small values of the coupling constant λ, the true reduced dynamics of the system is approximated by the completely positive, trace preserving Markovian semigroup generated by the Davies-Lindblad generator. The difference between the true and the Markovian dynamics is O(|λ|1/4) for all times, meaning that the solution of the Gorini-Kossakowski-Sudarshan-Lindblad master equation is approximating the true dynamics to accuracy O(|λ|1/4) for all times. Our method is based on a recently obtained expansion of the full system-bath propagator. It applies to reservoirs with correlation functions decaying in time as 1/t4 or faster, which is a significant improvement relative to the previously required exponential decay.

Механизм термической ионизации уротропина на поверхности интерметаллида NaAu-=SUB=-x-=/SUB=-

Thermal ionization of methenamine (C6H12N4) on the surface of the NaAux intermetallic compound has been studied. It has been established that the processes of decomposition, desorption and ionization of adsorbed compounds, thermally stimulated on the surface, proceed due to the accumulation of energy at the degrees of freedom of the adsorption complex, including the adsorbed compound and a solid, by the mechanism of monomolecular decomposition reactions. In this case, the decomposition of the adsorption complex is accompanied by the desorption of ions that are not in thermal equilibrium with the solid. The uniformity of the temperature dependences of the ion current and their distribution over two groups allowed us to conclude that ions are desorbed from the surface, which correspond to the decays of individual adsorbed molecules, as well as the decays of dimers formed on the surface. The decay of methenamine molecules during thermal ionization occurs in the same way as their decay in vacuum during electron ionization, which indicates the preservation of the bulk structure of methenamine molecules during adsorption and a significant lifetime of the excited state of compounds on NaAux.

Hot atom chemistry: oxygen at stepped platinum surfaces

It is a paradigm in chemistry that chemical reaction are mainly governed by thermodynamics. Within this assumption, reaction rates can be derived from transition state theory which requires a quasi-equilibrium between reactants and activated transition state complexes that is achieved through friction. However, to reach thermal equilibrium through friction takes some time. Here we show, based on ab initio molecular dynamics simulations of the interaction of molecular oxygen with stepped Pt surfaces, that chemical reactions in heterogeneous catalysis can occur in a non-equilibrium fashion when the excess kinetic energy upon entering the potential well of a reaction intermediate is large enough.

An Entropic Approach to Classical Density Functional Theory

The classical Density Functional Theory (DFT) is introduced as an application of entropic inference for inhomogeneous fluids in thermal equilibrium. It is shown that entropic inference reproduces the variational principle of DFT when information about the expected density of particles is imposed. This process introduces a family of trial density-parametrized probability distributions and, consequently, a trial entropy from which the preferred one is found using the method of Maximum Entropy (MaxEnt). As an application, the DFT model for slowly varying density is provided, and its approximation scheme is discussed.

Dynamic study of Weyl tensor corrected f(R) gravity

We investigate the cosmological and thermodynamic aspects of Weyl tensor corrected [Formula: see text] gravity. For this purpose, we assume some well-known cosmological bouncing scenarios such as symmetric bounce cosmology, oscillatory cosmology, matter bounce cosmology, little rip cosmology, superbounce cosmology and develop some cosmological parameters. For instance, the equation of state parameter [Formula: see text] describes the quintessence phase for symmetric bounce cosmology, vacuum phase for oscillatory, little rip and matter bounce cosmology while it gives both quintessence and vacuum phases for matter bounce cosmology. It is also observed that the squared speed of sound [Formula: see text] gives positive behavior for all models resulting in that the models assumed are stable. We evaluate generalized second law of thermodynamics which remains valid for all cosmological models except symmetric bounce cosmology. Moreover, we also investigate the thermal equilibrium condition [Formula: see text] and found its validity for all models except symmetric bounce cosmological model.

Thermal non-equilibrium of porous flow in a resting matrix applicable to melt migration: a parametric study

Fluid flow through rock occurs in many geological settings on different scales, at different temperature conditions and with different flow velocities. Depending on these conditions the fluid will be in local thermal equilibrium with the host rock or not. To explore the physical parameters controlling thermal non-equilibrium the coupled heat equations for fluid and solid phases are formulated for a fluid migrating through a resting porous solid by Darcy flow. By non-dimensionalizing the equations three non-dimensional numbers can be identified controlling thermal non-equilibrium: the Peclet number Pe describing the fluid velocity, the heat transfer number A describing the local interfacial heat transfer from the fluid to the solid, and the porosity ϕ. The equations are solved numerically for the fluid and solid temperature evolution for a simple 1D model setup with constant flow velocity. Three stages are observed: a transient stage followed by a stage with maximum non-equilibrium fluid to solid temperature difference, ∆Tmax, and a stage approaching the steady state. A simplified time-independent ordinary differential equation for depth-dependent (Tf – Ts) is derived and analytically solved. From these solutions simple scaling laws of the form (Tf – Ts) = f (Pe, A, ϕ, H), where H is the non-dimensional model height, are derived. The solutions for ∆Tmax and the scaling laws are in good agreement with the numerical solutions. The parameter space Pe, A, ϕ, H is systematically explored. In the Pe – A – parameter space three regimes can be identified: 1) at high Pe (> 1) strong thermal non-equilibrium develops independently of Pe and A; 2) at low Pe (< 1) and low A (< 1) non-equilibrium decreases proportional to decreasing Pe; 3) at low Pe (<1) and large A (>1) non-equilbrium scales with Pe/A and thus becomes unimportant. The porosity ϕ has only a minor effect on thermal non-equilibrium. The time scales for reaching thermal non-equilibrium scale with the advective time-scale in the high Pe-regime and with the interfacial diffusion time in the other two low Pe – regimes. Applying the results to natural magmatic systems such as mid-ocean ridges can be done by estimating appropriate orders of Pe and A. Plotting such typical ranges in the Pe – A regime diagram reveals that a) interstitial melt flow is in thermal equilibrium, b) melt channelling as e.g. revealed by dunite channels may reach moderate thermal non-equilibrium, and c) the dyke regime is at full thermal non-equilibrium.

Casimir Forces Out of Thermal Equilibrium Near A Superconducting Transition

We present a comprehensive analysis of the out-of-equilibrium Casimir pressure between two high-T c superconducting plates, each kept at a different temperature. Two interaction regimes can be distinguished. While the zero-point energy dominates in the near field, thermal effects become important at large interplate separations causing a drop in the force’s magnitude compared with the usual thermal-equilibrium case. Our detailed calculations highlight the competing role played by propagating and evanescent modes. Moreover, as one of the plates undergoes the superconducting transition, we predict a sudden discontinuity in the force for any plate distance, which has not been previously observed in other systems. The sensitivity of the dielectric function of the high-T c superconductors makes them ideal systems for a possible direct measurement of the out-of-equilibrium Casimir pressure.