scholarly journals Experimental and Theoretical Studies of the Gas-Phase Reactions of O(1D) with H2O and D2O at Low Temperature

2021 ◽  
Author(s):  
Kevin M. Hickson ◽  
Somnath Bhowmick ◽  
Yury V. Suleimanov ◽  
João Brandão ◽  
Daniela V. Coelho
Keyword(s):  
Low Temperature ◽  
Gas Phase ◽  
Room Temperature ◽  
Theoretical Study ◽  
Theoretical Studies ◽  
Gas Phase Reactions ◽  
Experimental And Theoretical Studies

Here we report the results of an experimental and theoretical study of the gas-phase reactions between O(1D) and H2O and O(1D) and D2O at room temperature and below. On the...

Experimental and Theoretical Studies of the Gas-Phase Reactions of "Bare" Iron(I) with Tetralin

1995 ◽  
Vol 14 (9) ◽  
pp. 4409-4414 ◽  
Author(s):  
Katrin Seemeyer ◽  
Roland H. Hertwig ◽  
Jan Hrusak ◽  
Wolfram Koch ◽  
Helmut Schwarz
Keyword(s):  
Gas Phase ◽  
Theoretical Studies ◽  
Gas Phase Reactions ◽  
Experimental And Theoretical Studies

Theoretical Study of the Gas-Phase Reactions of Iodine Atoms (2P3/2) with H2, H2O, HI, and OH

2010 ◽  
Vol 114 (34) ◽  
pp. 9270-9288 ◽  
Author(s):  
Sébastien Canneaux ◽  
Bertrand Xerri ◽  
Florent Louis ◽  
Laurent Cantrel
Keyword(s):  
Gas Phase ◽  
Theoretical Study ◽  
Gas Phase Reactions

An experimental study of the reactivity of the hydroxide anion in the gas phase at room temperature, and its perturbation by hydration

1981 ◽  
Vol 59 (11) ◽  
pp. 1615-1621 ◽  
Author(s):  
Scott D. Tanner ◽  
Gervase I. Mackay ◽  
Diethard K. Bohme
Keyword(s):  
Experimental Study ◽  
Proton Transfer ◽  
Gas Phase ◽  
Rate Constants ◽  
Room Temperature ◽  
Gas Phase Reactions ◽  
Flowing Afterglow ◽  
Hydroxide Anion

Flowing afterglow measurements are reported which provide rate constants and product identifications at 298 ± 2 K for the gas-phase reactions of OH− with CH3OH, C2H5OH, CH3OCH3, CH2O, CH3CHO, CH3COCH3, CH2CO, HCOOH, HCOOCH3, CH2=C=CH2, CH3—C≡CH, and C6H5CH3. The main channels observed were proton transfer and solvation of the OH−. Hydration with one molecule of H2O was observed either to reduce the rate slightly and lead to products which are the hydrated analogues of the "nude" reaction, or to stop the reaction completely, k ≤ 10−12 cm3 molecule−1 s−1. The reaction of OH−•H2O with CH3—C≡CH showed an uncertain intermediate behaviour.

Experimental and theoretical studies of the gas-phase protonation of aliphatic phosphine oxides and phosphoramides

1985 ◽  
Vol 107 (19) ◽  
pp. 5352-5358 ◽  
Author(s):  
J. C. Bollinger ◽  
R. Houriet ◽  
C. W. Kern ◽  
D. Perret ◽  
J. Weber ◽  
...  
Keyword(s):  
Gas Phase ◽  
Theoretical Studies ◽  
Phosphine Oxides ◽  
Experimental And Theoretical Studies
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