Complexes of transition metal carbonyl clusters with tin(II) phthalocyanine in neutral and radical anion states: methods of synthesis, structures and properties

2022 ◽  
Author(s):  
Nikita R. Romanenko ◽  
Alexey V. Kuzmin ◽  
Salavat S. Khasanov ◽  
Maxim A. Faraonov ◽  
Evgeniya I. Yudanova ◽  
...  
Keyword(s):  
Transition Metal ◽  
Radical Anion ◽  
Metal Carbonyl ◽  
Direct Interaction ◽  
Crystalline Complex ◽  
Carbonyl Clusters ◽  
Structures And Properties ◽  
Metal Carbonyl Clusters ◽  
Methods Of Synthesis

Coordination of tin(II) phthalocyanine to transition metal carbonyl clusters in neutral {Sn(II){Pc(2-)}}(0) or radical anion {Sn(II){Pc(•3-)}}(-) states is reported. Direct interaction of Co4(CO)12 with {Sn(II){Pc(2-)}}(0) yields crystalline complex {Co4(CO)11·Sn(II){Pc(2-))} (1)....

scholarly journals The Categorization and Structural Prediction of Transition Metal Carbonyl Clusters Using 14n Series Numerical Matrix

2016 ◽  
Vol 8 (1) ◽  
pp. 109
Author(s):  
Enos Masheija Rwantale Kiremire
Keyword(s):  
Transition Metal ◽  
Valence Electron ◽  
Metal Carbonyl ◽  
Electron Content ◽  
Constant Number ◽  
Carbonyl Clusters ◽  
Structural Prediction ◽  
Metal Carbonyl Clusters ◽  
The Matrix ◽  
Special Case

<p>A matrix table of valence electron content of carbonyl clusters has been created using the 14n-based series. The numbers so generated form an array of series which conform precisely with valence electron contents of carbonyl clusters. The renowned 18 electron rule is a special case of 14n+4 series. Similarly, the 16 electron rule is another special case of the 14n+2 series. Categorization of the carbonyl clusters using the matrix table of series has been demonstrated. The table is so organized that clusters numerically represented can easily be compared and analyzed. The numbers that are diagonally arranged from right to left represent capping series. The row from right to left represents a decrease in valence electron content with increase in cluster linkages. The variation of cluster shapes of constant number of skeletal elements especially four or more may be monitored or compared with the variation with the valence electron content.</p>

The emergence of paramagnetism in transition-metal carbonyl clusters

1987 ◽  
Vol 139 (3-4) ◽  
pp. 336-344 ◽  
Author(s):  
S.R. Drake ◽  
P.P. Edwards ◽  
B.F.G. Johnson ◽  
J. Lewis ◽  
E.A. Marseglia ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters

scholarly journals Altering Charges on Heterobimetallic Transition‐Metal Carbonyl Clusters

2020 ◽  
Vol 26 (54) ◽  
pp. 12373-12381
Author(s):  
Wiebke Unkrig ◽  
Konstantin Kloiber ◽  
Burkhard Butschke ◽  
Daniel Kratzert ◽  
Ingo Krossing
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters
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