Electrochemically mediated gradient metallic film generation

2021 ◽  
Vol 45 (4) ◽  
pp. 1809-1813
Author(s):  
Xiaoqian Ma ◽  
Huan Song ◽  
Junfeng Yan

Metallic films with a controlled gradient can be fabricated on substrates via electrochemically induced metallic ion deposition.

It is well known that when thin leaves of gold or silver are mounted upon glass and heated to a temperature which is well below a red heat, a remarkable change of properties takes place, whereby the continuity of the metallic film is destroyed. The result is that white light is now freely transmitted, reflection is correspondingly diminished, while the electric resistivity is enormously increased. A simple method of illustrating this extraordinary change is to mount a sheet of silver leaf between two clean lantern plates, clip them lightly together by means of wire paper fasteners or other suitable means, and then heat gradually to a temperature of not more than 500°C. This can be done con­veniently by placing the plates on a thin fire-brick in a cold gas muffle, and then raising the temperature to the desired point. The gas should now be turned off, and the glass plates allowed to cool slowly, so as to avoid cracking. They can then be bound with strips like an ordinary lantern plate, and a permanent example of transparent silver is obtained. It will be found that such a plate transmits the light of the electric lantern almost as readily as ordinary glass, and does not produce any change of colour. The great trans­parency of the film may be shown by placing the plate upon printing or writing, and photographing the characters through the plate. Every detail of the characters can be reproduced with remarkable clearness. At first sight it is perhaps difficult to conceive that so distinct an impression could be obtained through what was originally a perfectly opaque sheet of silver, and which has only been once heated to a moderate temperature.


2009 ◽  
Vol 79-82 ◽  
pp. 557-560
Author(s):  
Jian Feng Di ◽  
Wen Qin Du ◽  
Fei Yu ◽  
Hong Jin Qi

In order to prepare a time decay-resistant electromagnetic shielding (ES) fabric with good handle, moisture permeability and antibacterial properties, Cu, Ag, Ag/Cu and Ag/Cu/Ag films were deposited on PET non-woven by sputtering in screening experiment. Considering the post continues processing, this study focuses on discharge parameters optimum for a limited short time. Relationship was studied between deposited rate and ES effectiveness (ESE) for the four metallic films on various substrates. The metal deposit greatly relays on the chemical nature of the substrate and target metal category. The deposited metal rate on metal is larger than that on PET. In comparison with single metallic film, the dB value of multi-metallic film obtained for same time even for more time remarkably dropped. Therefore, an Ag-coated PET no-woven was finally fabricated as the multi-functional fabric with anti-decay ESE. The multi-functional PET no-woven with good handle obtained for 3min. by optimizing other parameters exhibits higher ESE, good anti-bacterial and moisture permeability.


Author(s):  
J. Silcox ◽  
R. H. Wade

Recent work has drawn attention to the possibilities that small angle electron scattering offers as a source of information about the micro-structure of vacuum condensed films. In particular, this serves as a good detector of discontinuities within the films. A review of a kinematical theory describing the small angle scattering from a thin film composed of discrete particles packed close together will be presented. Such a model could be represented by a set of cylinders packed side by side in a two dimensional fluid-like array, the axis of the cylinders being normal to the film and the length of the cylinders becoming the thickness of the film. The Fourier transform of such an array can be regarded as a ring structure around the central beam in the plane of the film with the usual thickness transform in a direction normal to the film. The intensity profile across the ring structure is related to the radial distribution function of the spacing between cylinders.


1991 ◽  
Vol 16 (6) ◽  
pp. 623-638 ◽  
Author(s):  
P.A. Badoz ◽  
F. Arnaud d'Avitaya ◽  
E. Rosencher

2018 ◽  
Author(s):  
Julia Sun ◽  
Benjamin Almquist

For decades, fabrication of semiconductor devices has utilized well-established etching techniques to create complex nanostructures in silicon. Of these, two of the most common are reactive ion etching in the gaseous phase and metal-assisted chemical etching (MACE) in the liquid phase. Though these two methods are highly established and characterized, there is a surprising scarcity of reports exploring the ability of metallic films to catalytically enhance the etching of silicon in dry plasmas via a MACE-like mechanism. Here, we discuss a <u>m</u>etal-<u>a</u>ssisted <u>p</u>lasma <u>e</u>tch (MAPE) performed using patterned gold films to catalyze the etching of silicon in an SF<sub>6</sub>/O<sub>2</sub> mixed plasma, selectively increasing the rate of etching by over 1000%. The degree of enhancement as a function of Au catalyst configuration and relative oxygen feed concentration is characterized, along with the catalytic activities of other common MACE metals including Ag, Pt, and Cu. Finally, methods of controlling the etch process are briefly explored to demonstrate the potential for use as a liquid-free fabrication strategy.


Shinku ◽  
1963 ◽  
Vol 6 (5) ◽  
pp. 182-188
Author(s):  
Hisashi HORIKOSHI ◽  
Noriko TAMURA
Keyword(s):  

2007 ◽  
Vol 9 (10) ◽  
pp. 391-391 ◽  
Author(s):  
D Malterre ◽  
B Kierren ◽  
Y Fagot-Revurat ◽  
S Pons ◽  
A Tejeda ◽  
...  

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