Preparation of N-doped graphite oxide for supercapacitors by NH3 cold plasma

In this work, N-doped graphite oxide (GO-P) was prepared by cold plasma treatment of GO using a mixture of NH3 and Ar as the working gas. When the ratios of NH3:Ar were 1:2, 1:3, and 1:4, the specific capacitances of the GO-P(NH3:Ar1:2), GO-P(NH3:Ar1:3), and GO-P(NH3:Ar1:4) were 124.5, 187.7, and 134.6 Fg−1, respectively, which were 4.7, 7.1, and 5.1 times that of GO at the current density of 1 Ag−1. The capacitance retention of the GO-P(NH3:Ar1:3) was 80% when it was cycled 1000 times. The characterization results showed that the NH3 cold plasma could effectively produce N-doped GO and generate more active defects. The N/C ratio and the contents of pyridinic nitrogen and graphitic nitrogen of the GO-P(NH3:Ar1:3) were the highest. These were conducive to providing pseudocapacitance and reducing the internal resistance of the electrode. In addition, the ID/IG of the GO-P(NH3:Ar=1:3) (1.088) was also the highest, indicating the highest number of defects. The results of discharge parameters measurement and in situ optical emission spectroscopy diagnosis of NH3 plasma showed that the discharge is the strongest when the ratio of NH3:Ar was 1:3, thereby the generated nitrogen active species can effectively promote N-doping. The N-doping and abundant defects were the keys to the excellent electrochemical performance of the GO-P(NH3:Ar1:3). NH3 cold plasma is a simple and rapid method to prepare N-doped GO and regulate the N-doping to prepare high-performance supercapacitors.

Dust-Acoustic Nonlinear Waves in a Nanoparticle Fraction of Ultracold (2K) Multicomponent Dusty Plasma

The nonlinear dust-acoustic instability in the condensed submicron fraction of dust particles in the low-pressure glow discharge at ultra-low temperatures is experimentally and theoretically investigated. The main discharge parameters are estimated on the basisof the dust-acoustic wave analysis. In particular, the temperature and density of ions, as well as the Debye radius, are determined. It is shown that the ion temperature exceeds the temperature of the neutral gas. The drift characteristics of all plasma fractions are estimated. The reasons for the instability excitation are considered.

Developing Shunt-Current Minimized Soluble-Lead-Redox-Flow-Batteries

Shunt currents in membraneless soluble-lead-redox-flow-batteries (SLRFB) are observed in open-circuit condition and found to depend on size of the stack, manifolds, flow rates and charge/discharge parameters. Ramifications of shunt currents on the performance of membraneless SLRFB stacks with internal and external manifolds are reported. In the case of stacks with 3, 5 and 7-cells and internal manifold design, the charge current for the middle cell decreases by 3.3%, 6%, and 8.5%, while the discharge current increases by 2.6%, 5.5%, and 6.6% , respectively, for 3 A charge/discharge current. By contrast, no such adverse effect is observed for external manifold design. The current – potential studies show that while the stacks comprising 3 and 5-cells deliver a maximum power density of 35 mW/cm2, which declines to 15 mW/cm2 for the 7-cell stack with internal manifold design, while the power density remains invariant at 50 mW/cm2 for stacks with external manifold design. An 8-cell stack of 12 V, 50 mAh/cm2 specific capacity and 273 Wh energy storage capacity with 64% energy efficiency is also reported which shows good cyclability over 100 cycles with 95% coulombic efficiency when cycled at 20 mA/cm2 current density for 1h duration.

Alignments of a Microparticle Pair in a Glow Discharge

Stability of a vertically aligned microparticle pair in a stratified glow DC discharge is experimentally investigated. Using laser perturbations, it is shown that, for the same discharge parameters, a pair of microparticles can be suspended in two stable configurations: vertical and horizontal. The interparticle interaction and the electric field of the stratum in the region of particle levitation are quantitatively investigated for the first time. The decharging effect of the lower (downstream) particle by the ion flow wake is also observed for the first time in a glow discharge. The obtained experimental data made it possible to check the analytical criteria for the configurational stability of the system.

Study by Optical Spectroscopy of Bismuth Emission in a Nanosecond-Pulsed Discharge Created in Liquid Nitrogen

Time-resolved optical emission spectroscopy of nanosecond-pulsed discharges ignited in liquid nitrogen between two bismuth electrodes is used to determine the main discharge parameters (electron temperature, electron density and optical thickness). Nineteen lines belonging to the Bi I system and seven to the Bi II system could be recorded by directly plunging the optical fibre into the liquid in close vicinity to the discharge. The lack of data for the Stark parameters to evaluate the broadening of the Bi I lines was solved by taking advantage of the time-resolved information supported by each line to determine them. The electron density was found to decrease exponentially from 6.5 ± 1.5 × 1016 cm−3 200 ns after ignition to 1.0 ± 0.5 × 1016 cm−3 after 1050 ns. The electron temperature was found to be 0.35 eV, close to the value given by Saha’s equation.

Numerical investigations of 2-D planar magnetic nozzle effects on pulsed plasma plumes

This paper presents a study of a novel type of magnetic nozzle that allows for three-dimensional (3-D) steering of a plasma plume. Numerical simulations were performed using Tech-X’s USim® software to quantify the nozzle’s capabilities. A 2-D planar magnetic nozzle was applied to plumes of a nominal pulsed inductive plasma (PIP) source with discharge parameters similar to those of Missouri S&T’s Missouri Plasmoid Experiment (MPX). Argon and xenon plumes were considered. Simulations were verified and validated through a mesh convergence study as well as comparison with available experimental data. Periodicity was achieved over the simulation run time and phase angle samples were taken to examine plume evolution over pulse cycles. The resulting pressure, velocity, and density fields were analysed for nozzle angles from 0° to 14°. It was found that actual plume divergence was small compared to the nozzle angle. Even with an offset angle of 14° for the magnetic nozzle, the plume vector angle was only about 2° for argon and less than 1° for xenon. The parameters that had the most effect on the vectoring angle were found to be the coil current and inlet velocity.

Efficiency of electron beam extraction to the atmosphere in an accelerator based on ion-electron emission

The use of a modern element base makes it possible to create power supplies with a transition from a direct mode of generation of an auxiliary discharge to a pulse-periodic mode with a pulse repetition rate at the level of several tens of kHz. This allows for a more flexible adjustment of the discharge parameters, keeping the average value of its current, but changing its amplitude with a corresponding change in the pulse duty cycle. In this work, using an electron accelerator based on ion-electron emission, generating a wide-aperture electron beam, we research the effect of auxiliary discharge generation mode (direct and pulse-periodic) on the efficiency of electron beam extraction into the ambient atmosphere. It is shown that, in a direct mode of electron beam generation at an accelerating voltage of 150 kV, the beam extraction coefficient does not exceed 0.25. The possibility of increasing the extraction coefficient to K = 0.55 at the same accelerating voltage of 150 kV was demonstrated without making changes to the design of the accelerator, but switching to a pulsed-periodic mode of emission plasma generation.

Deposition of boron films using a discharge system with a hot boron anode

This work describes a discharge system for heating and evaporation of a boron powder target based on a non-self-sustained arc discharge with a filament, a hollow cathode and a hot combined anode. The measurements of the current-voltage characteristics of the discharge with a hot anode and the dependence of the anode temperature on the discharge parameters are presented. The modes of deposition of boron films have been determined.

Influence of the surface DBD parameters on the streaks development in the boundary layer

The effect of the filamentary barrier discharge parameters on the boundary layer streaks generation and instability was studied. The streaks are formed near the constricted discharge channels due to vortices formation driven by spanwise Coulomb volume force. The secondary instability of the streaky structures can lead to the laminar-turbulent transition of the boundary layer. This work demonstrates that supply voltage parametrs affect the period of the constricted channels and thus the streaks transversal period within the boundary layer. For the various streaks periods, different modes of streak instability are shown to dominate.