One-pot synthesis of cyclohexylamine and N-aryl pyrroles via hydrogenation of nitroarenes over the Pd0.5Ru0.5-PVP catalyst

2021 ◽  
Author(s):  
Chandan Chaudhari ◽  
Katsutoshi Sato ◽  
Yasuyuki Ikeda ◽  
Kenji Terada ◽  
Naoya Abe ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
One Pot ◽  
One Pot Synthesis

The direct synthesis of cyclohexylamine via hydrogenation of nitrobenzene over monometallic (Pd, Ru or Rh) and bimetallic (PdxRu1−x) catalysts was studied.

Molybdenum-Mediated One-Pot Synthesis of Pyrazoles from Isoxazoles

Synthesis ◽  
2019 ◽  
Vol 51 (20) ◽  
pp. 3796-3804 ◽  
Author(s):  
Marine Rey ◽  
Stéphane Beaumont
Keyword(s):  
Bond Cleavage ◽  
Direct Synthesis ◽  
Molybdenum Complex ◽  
One Pot ◽  
One Pot Synthesis ◽  
Wide Range ◽  
Hydrolysis Of ◽  
Substituted Pyrazoles

A one-pot approach for the direct synthesis of substituted pyrazoles from isoxazoles is reported. The process involves isoxazole N–O bond cleavage mediated by a molybdenum complex, in situ hydrolysis of the resulting β-amino enone to the corresponding 1,3-diketone, followed by pyrazole formation in the presence of hydrazine or substituted hydrazine. Good to excellent yields and regioselectivities are obtained with nonsymmetric isoxazoles. By using readily available starting materials, a wide range of substituted pyrazoles may be synthesized by this method.

One-pot synthesis of carbon-coated Fe3O4 nanoparticles with tunable size for production of gasoline fuels

2018 ◽  
Vol 42 (13) ◽  
pp. 10861-10867 ◽  
Author(s):  
Junling Tu ◽  
Jiaojiao Yuan ◽  
Shimin Kang ◽  
Yongjun Xu ◽  
Tiejun Wang
Keyword(s):  
Fe3o4 Nanoparticles ◽  
Direct Synthesis ◽  
Catalytic Performance ◽  
One Pot ◽  
One Pot Synthesis ◽  
Carbon Coated ◽  
Excellent Catalytic Performance

Fe3O4@C nanoparticles with tunable size exhibit excellent catalytic performance in the direct synthesis of gasoline fuels.

scholarly journals Direct synthesis of anilines and nitrosobenzenes from phenols

2016 ◽  
Vol 14 (24) ◽  
pp. 5520-5524 ◽  
Author(s):  
A. H. St. Amant ◽  
C. P. Frazier ◽  
B. Newmeyer ◽  
K. R. Fruehauf ◽  
J. Read de Alaniz
Keyword(s):  
Direct Synthesis ◽  
Aromatic Substitution ◽  
One Pot ◽  
One Pot Synthesis ◽  
Ar Process

A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso-oxidative aromatic substitution (iSOAr) process.

A cascade reaction for the new and direct synthesis of indolofuroquinoxalines

RSC Advances ◽  
2016 ◽  
Vol 6 (28) ◽  
pp. 23489-23497 ◽  
Author(s):  
Satish P. Nikumbh ◽  
Akula Raghunadh ◽  
T. Srinivasa Rao ◽  
V. Narayana Murthy ◽  
Suju C. Joseph ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
Cascade Reaction ◽  
One Pot ◽  
One Pot Synthesis ◽  
Quinoxaline Derivatives

A cascade reaction has been developed for the direct and one-pot synthesis of 7H-indolo[3′,2′:4,5]furo[2,3-b]quinoxaline derivatives.

Radical-Hydroboration-Involved One-Pot Synthesis of Boron-Handled Glycol Derivatives

Synlett ◽  
2020 ◽  
Author(s):  
Feng-Lian Zhang ◽  
Yi-Feng Wang ◽  
Bi-Yang Zhuang ◽  
Ji-Kang Jin
Keyword(s):  
Ring Opening ◽  
Direct Synthesis ◽  
One Pot ◽  
One Pot Synthesis ◽  
Direct Formation

A one-pot two-step protocol for the direct synthesis of boron-handled glycol derivatives is reported. The procedure starts by an NHC–boryl-radical-promoted regioselective hydroboration of glycol-protected cinnamaldehydes. After that, the reaction mixture is treated with pinacol in the presence of HCl, leading to the direct formation of pinacol boronate handled glycol monoalkyl ethers. In this acid-triggered conversion, a reductive ring-opening of glycol-derived acetal moiety takes place, during which an NHC–borane unit serves as the hydride source.

ONE-POT SYNTHESIS OF HYDROPHILIC AND HYDROPHOBIC FERROFLUID

2009 ◽  
Vol 08 (01n02) ◽  
pp. 65-69 ◽  
Author(s):  
DIPAK MAITY ◽  
JUN DING ◽  
JUN-MIN XUE
Keyword(s):  
Magnetic Properties ◽  
Ethylene Glycol ◽  
Direct Synthesis ◽  
Blocking Temperature ◽  
High Quality ◽  
One Pot ◽  
Single Crystalline ◽  
Stabilizing Agent ◽  
One Pot Synthesis ◽  
Tga Analysis

High-quality hydrophobic or hydrophilic ferrofluid based on magnetite ( Fe 3 O 4) nanoparticles can be synthesized by one-pot direct synthesis which involves thermolysis of Iron(III) acetylacetonate, Fe ( acac )3 in hydrophobic or hydrophilic stabilizing agent, respectively. The structure of the nanoparticles dispersed in the ferrofluid was studied using XRD, FTIR, XPS, and TGA analysis, while morphology and size of the nanoparticles were determined by TEM. The magnetic properties of the samples were measured using VSM and SQUID measurement. The results show that oleylamine (OM) and tri(ethylene glycol) (TREG) coated Fe 3 O 4 nanoparticles which are well stabilized in hydrophobic and hydrophilic ferrofluid, respectively, are relatively monodisperse, single crystalline and superparamagnetic in nature with the blocking temperature at around 100 K.

Aryne insertion into the PO bond: one-pot synthesis of quaternary phosphonium triflates

2019 ◽  
Vol 17 (26) ◽  
pp. 6450-6460 ◽  
Author(s):  
Kashmiri Neog ◽  
Dhiraj Dutta ◽  
Babulal Das ◽  
Pranjal Gogoi
Keyword(s):  
Transition Metal ◽  
Phosphine Oxide ◽  
Direct Synthesis ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis ◽  
Synthetic Strategy

A novel transition-metal free synthetic strategy for the direct synthesis of quaternary phosphonium triflates via insertion of aryne into phosphine oxide.

Direct synthesis of poly(benzoxazine imide) from an ortho-benzoxazine: its thermal conversion to highly cross-linked polybenzoxazole and blending with poly(4-vinylphenol)

2018 ◽  
Vol 9 (14) ◽  
pp. 1815-1826 ◽  
Author(s):  
Ahmed F. M. El-Mahdy ◽  
Shiao-Wei Kuo
Keyword(s):  
Thermal Treatment ◽  
Direct Synthesis ◽  
Thermal Conversion ◽  
One Pot ◽  
Subsequent Thermal Treatment ◽  
One Pot Synthesis

A facile one-pot synthesis of a poly(benzoxazine imide), NDOPoda Bz, was prepared without the need for either the preparation of an amino-functionalized benzoxazine or subsequent thermal treatment.

scholarly journals Direct synthesis of N-sulfinyl- and N-sulfonylimines via copper/l-proline-catalyzed aerobic oxidative cascade reaction of alcohols with sulfinamides or sulfonamides

RSC Advances ◽  
2017 ◽  
Vol 7 (16) ◽  
pp. 9431-9435 ◽  
Author(s):  
Guofu Zhang ◽  
Shengjun Xu ◽  
Xiaoqiang Xie ◽  
Chengrong Ding ◽  
Shang Shan
Keyword(s):  
Direct Synthesis ◽  
Cascade Reaction ◽  
One Pot ◽  
One Pot Synthesis

An efficient one-pot synthesis of N-sulfinyl- and N-sulfonylimines directly from alcohols with sulfinamides or sulfonamides.

Heterogeneous catalysis for the direct synthesis of chemicals by borrowing hydrogen methodology

2015 ◽  
Vol 5 (3) ◽  
pp. 1412-1427 ◽  
Author(s):  
Ken-ichi Shimizu
Keyword(s):  
Heterogeneous Catalysis ◽  
Transition Metal ◽  
Hydrogen Transfer ◽  
Direct Synthesis ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
One Pot ◽  
One Pot Synthesis ◽  
Borrowing Hydrogen ◽  
The One

This review summarizes the recent examples of hydrogen transfer-type reactions using supported transition metal catalysts with special emphasis on the one-pot synthesis of chemicals by borrowing hydrogen methodology.

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