Palladium-catalyzed synthesis of α-aryl acetophenones from styryl ethers and aryl diazonium salts via regioselective Heck arylation at room temperature

2021 ◽  
Vol 19 (36) ◽  
pp. 7832-7837
Author(s):  
Rapelly Venkatesh ◽  
Adesh Kumar Singh ◽  
Yong Rok Lee ◽  
Jeyakumar Kandasamy

Synthesis of α-aryl acetophenones from styryl ethers and aryldiazonium salts is described at room temperature. The reaction is catalyzed by palladium acetate in the absence of ligands and base.

2010 ◽  
Vol 31 (10) ◽  
pp. 1277-1280
Author(s):  
Chun LIU ◽  
Qijian NI ◽  
Pingping HU ◽  
Hao YUAN ◽  
Zilin JIN

2020 ◽  
Vol 18 (9) ◽  
pp. 1812-1819 ◽  
Author(s):  
Elene Tatunashvili ◽  
Bun Chan ◽  
Philippe E. Nashar ◽  
Christopher S. P. McErlean

Hantzsch esters and oxygen convert diazonium salts into aryl radicals, enabling rapid radical reactions to be performed in open flasks at room temperature.


2015 ◽  
Vol 21 (31) ◽  
pp. 11006-11009 ◽  
Author(s):  
Preston M. MacQueen ◽  
Alicia J. Chisholm ◽  
Breanna K. V. Hargreaves ◽  
Mark Stradiotto

2016 ◽  
Vol 52 (80) ◽  
pp. 11893-11896 ◽  
Author(s):  
Shi-Meng Wang ◽  
Hai-Xia Song ◽  
Xiao-Yan Wang ◽  
Nan Liu ◽  
Hua-Li Qin ◽  
...  

The first Pd-catalyzed Mizoroki–Heck-type cross-coupling of phenylsulfonium salts with alkenes was disclosed at room temperature.


2009 ◽  
Vol 121 (10) ◽  
pp. 1862-1865 ◽  
Author(s):  
Chris E. Houlden ◽  
Marc Hutchby ◽  
Chris D. Bailey ◽  
J. Gair Ford ◽  
Simon N. G. Tyler ◽  
...  

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