Towards modulating colour hues of isoindigo-based electrochromic polymers through variation of thiophene-based donor groups

2022 ◽  
Author(s):  
Ming Hui Chua ◽  
Sheng Heng Gerald Toh ◽  
Pin Jin Ong ◽  
Zhuang Mao Png ◽  
Qiang Zhu ◽  
...  

Conjugated polymers containing isoindigo electron acceptor groups have gained attention for electrochromic (EC) applications in recent years. To obtain a deeper fundamental understanding of the EC properties of isoindigo-based conjugated...

2018 ◽  
Vol 6 (47) ◽  
pp. 13049-13058 ◽  
Author(s):  
Lanchao Ma ◽  
Bing Chen ◽  
Yunlong Guo ◽  
Yongri Liang ◽  
Dongmei Zeng ◽  
...  

A novel bisthiophene-fused diketopyrrolopyrrole unit (4,11-bis(2-octyldodecyl)-7H,14H-thieno[3′,2′:7,8]indolizino[2,1-a]thieno[3,2-g]indolizine-7,14-dione, BTI) has been designed as an electron acceptor and used to copolymerize with thiophene and bithiophene as electron donors to construct two D–A conjugated polymers, P1 and P2via Stille coupling, respectively.


2020 ◽  
Vol 8 (40) ◽  
pp. 20998-21006
Author(s):  
Junhui Miao ◽  
Hongxiang Li ◽  
Tao Wang ◽  
Yanchun Han ◽  
Jun Liu ◽  
...  

A series of D–A type conjugated polymers based on alternating BNBP unit and oligothiophene units of various length were developed and served as from electron acceptor to electron donor.


RSC Advances ◽  
2018 ◽  
Vol 8 (38) ◽  
pp. 21252-21264 ◽  
Author(s):  
Yan Zhang ◽  
Lingqian Kong ◽  
Xiuping Ju ◽  
Hongmei Du ◽  
Jinsheng Zhao ◽  
...  

Two novel neutral green D–A type conjugated polymers were synthesized, illustrating satisfactory electrochromic properties, such as low band gaps, desirable color switches, excellent solubility and favorable thermal stability.


Author(s):  
Jing-Ju Huang ◽  
Hsing-An Lin ◽  
Chi Chen ◽  
Po-Wen Tang ◽  
Shyh-Chyang Luo

π−Conjugated polymers have received increasing attention in electrochromic material research because their color change can be altered over a wide range by introducing electron-donor (D) and electron-acceptor (A) moieties. In...


2015 ◽  
Vol 3 (17) ◽  
pp. 4464-4470 ◽  
Author(s):  
Wei Hong ◽  
Chang Guo ◽  
Bin Sun ◽  
Yuning Li

(3Z,3′Z)-3,3′-(Hydrazine-1,2-diylidene)bis(indolin-2-one) (HBI) is found to be a promising novel building block for polymer semiconductors.


2014 ◽  
Vol 2 (21) ◽  
pp. 4289-4296 ◽  
Author(s):  
Chang Guo ◽  
Bin Sun ◽  
Jesse Quinn ◽  
Zhuangqing Yan ◽  
Yuning Li

Indigo is used as an electron acceptor for constructing polymer semiconductors that show n-channel behaviour in organic thin film transistors.


2014 ◽  
Vol 26 (20) ◽  
pp. 3304-3309 ◽  
Author(s):  
Weiwei Li ◽  
W. S. Christian Roelofs ◽  
Mathieu Turbiez ◽  
Martijn M. Wienk ◽  
René A. J. Janssen

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Kuan Liu ◽  
Yang Li ◽  
Mujie Yang

AbstractNovel electron-acceptor materials based on poly(thienylene ethynylene) derivatives (PTE-BT and PTE-DCNTB) were synthesized and characterized by FTIR spectroscopy. Their thermal, electrochemical and optical properties were investigated. The π-conjugated polymers are soluble in common organic solvents. The maximum UV-Vis absorptions of PTE-BT and PTE-DCNTB in solution are observed at 460 and 390 nm, respectively. The electrochemical band gap was found to be 1.89 eV for PTE-BT and 2.01 eV for PTE-DCNTB. Both polymers are promising as electron-acceptor materials for photovoltaic applications.


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