Sequential Single-Crystal-to-Single-Crystal Vapochromic inclusion in non-porous coordination polymer: Unravelling dynamic rearrangement for selective pyridine sensing

2021 ◽  
Author(s):  
Estefania Fernandez-Bartolomé ◽  
Esther Resines-Urien ◽  
Maria Murillo-Vidal ◽  
Lucia Piñeiro-Lopez ◽  
Jose Sanchez Costa
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Covalent Organic Frameworks ◽  
Potential Applications ◽  
Metal Organic ◽  
Porous Coordination Polymer

Alternative porous materials beyond zeolites, such as metal-organic frameworks (MOF) or covalent organic frameworks (COF), have provided a variety of materials with potential applications ranging from sensing to catalysis. However,...

Controlled Growth of the Non-centrosymmetric Zn(3-ptz)2 and Zn(Oh)(3-ptz) Metal-organic Frameworks

2019 ◽  
Author(s):  
javier enriquez ◽  
Ignacio Chi-Duran ◽  
Carolina Manquian ◽  
Felipe Herrera ◽  
Ruben Fritz ◽  
...  
Keyword(s):  
Single Crystal ◽  
Nonlinear Optical ◽  
Metal Organic Frameworks ◽  
Molar Ratio ◽  
Thermal Synthesis ◽  
Small Crystals ◽  
Alkaline Environments ◽  
Potential Applications ◽  
Metal Organic ◽  
Long Rod

Non-centrosymmetric single-crystal metal-organic frameworks (MOF) are promising candidates for phase-matched nonlinear optical communication, but typical hydrothermal synthesis produces small crystals with relatively low transmittance and poor phase matching. We study the effect of the metal-to-ligand molar ratio and reaction pH on the hydro-thermal synthesis of the non-centrosymmetric Zn(3-ptz)<sub>2</sub> and Zn(OH)(3-ptz) MOFs with <i>in-situ </i>ligand formation. In acidic environments, we find that decreasing the amount of ligand below the stoichiometric molar ratio 1:2 also produces highly transparent single-crystal octahedrons of <b>Zn(3-ptz)<sub>2</sub></b>. In alkaline environments, we obtain long rod-like <b>Zn(OH)(3-ptz) </b>crystals whose length exceeds previous reports by up to four orders of magnitude. Potential applications of these results in the development of MOF-based nonlinear optical devices are discussed.

A robust ethane-selective hypercrosslinked porous organic adsorbent with high ethane capacity

2022 ◽  
Author(s):  
Hyein Park ◽  
Minjung Kang ◽  
Dong Won Kang ◽  
Chang Seop Hong
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Covalent Organic Frameworks ◽  
Separation Technology ◽  
Preferential Adsorption ◽  
Metal Organic ◽  
Hydrogen Bonded

While preferential adsorption of ethane (C2H6) over ethylene (C2H4) is more advantageous in industrial separation technology, most porous materials such as metal-organic frameworks, covalent-organic frameworks, and hydrogen-bonded organic frameworks provide...

Controlled Growth of the Non-centrosymmetric Zn(3-ptz)2 and Zn(Oh)(3-ptz) Metal-organic Frameworks

2019 ◽  
Author(s):  
javier enriquez ◽  
Ignacio Chi-Duran ◽  
Carolina Manquian ◽  
Felipe Herrera ◽  
Ruben Fritz ◽  
...  
Keyword(s):  
Single Crystal ◽  
Nonlinear Optical ◽  
Metal Organic Frameworks ◽  
Molar Ratio ◽  
Thermal Synthesis ◽  
Small Crystals ◽  
Alkaline Environments ◽  
Potential Applications ◽  
Metal Organic ◽  
Long Rod

Non-centrosymmetric single-crystal metal-organic frameworks (MOF) are promising candidates for phase-matched nonlinear optical communication, but typical hydrothermal synthesis produces small crystals with relatively low transmittance and poor phase matching. We study the effect of the metal-to-ligand molar ratio and reaction pH on the hydro-thermal synthesis of the non-centrosymmetric Zn(3-ptz)<sub>2</sub> and Zn(OH)(3-ptz) MOFs with <i>in-situ </i>ligand formation. In acidic environments, we find that decreasing the amount of ligand below the stoichiometric molar ratio 1:2 also produces highly transparent single-crystal octahedrons of <b>Zn(3-ptz)<sub>2</sub></b>. In alkaline environments, we obtain long rod-like <b>Zn(OH)(3-ptz) </b>crystals whose length exceeds previous reports by up to four orders of magnitude. Potential applications of these results in the development of MOF-based nonlinear optical devices are discussed.

Heterostructured hybrids of metal–organic frameworks (MOFs) and covalent–organic frameworks (COFs)

2022 ◽  
Author(s):  
Chuanpan Guo ◽  
Fenghe Duan ◽  
Shuai Zhang ◽  
Linghao He ◽  
Minghua Wang ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Metal Organic Frameworks ◽  
Covalent Organic Frameworks ◽  
Gas Sorption ◽  
Potential Applications ◽  
Metal Organic

MOF/COF-based hybrids show the properties of precisely tunable compositions and structures, and provide a broad range of potential applications in gas sorption and separation, catalysis, energy transfer, biomedicine, etc.

scholarly journals Large breathing effect induced by water sorption in a remarkably stable nonporous cyanide-bridged coordination polymer

2021 ◽  
Author(s):  
Michal Magott ◽  
Bartłomiej A. Gaweł ◽  
Marcin Sarewicz ◽  
Mateusz Reczyński ◽  
Karolina Ogorzały ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Materials ◽  
Prussian Blue ◽  
Water Sorption ◽  
Metal Organic Frameworks ◽  
Cutting Edge ◽  
Sorption Properties ◽  
Metal Organic ◽  
Prussian Blue Analogs

While metal-organic frameworks (MOFs) are at the forefront of cutting-edge porous materials, extraordinary sorption properties can also be observed in Prussian Blue Analogs (PBAs) and related materials comprising extremely short...

Emerging crystalline porous materials as a multifunctional platform for electrochemical energy storage

2017 ◽  
Vol 46 (22) ◽  
pp. 6927-6945 ◽  
Author(s):  
Junwen Zhou ◽  
Bo Wang
Keyword(s):  
Energy Storage ◽  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Electrochemical Energy Storage ◽  
Covalent Organic Frameworks ◽  
Metal Organic ◽  
Multifunctional Platform ◽  
Electrochemical Energy

This review highlights the functions of metal–organic frameworks and covalent-organic frameworks in batteries and supercapacitors.

Recent advances in AIEgen-based luminescent metal–organic frameworks and covalent organic frameworks

2017 ◽  
Vol 1 (12) ◽  
pp. 2474-2486 ◽  
Author(s):  
Li Ma ◽  
Xiao Feng ◽  
Shan Wang ◽  
Bo Wang
Keyword(s):  
Metal Organic Frameworks ◽  
Covalent Organic Frameworks ◽  
Photoluminescence Properties ◽  
Recent Advances ◽  
Potential Applications ◽  
Metal Organic

This review gives a brief introduction to AIEgen-based MOFs and COFs and focuses on their photoluminescence properties and potential applications.

scholarly journals Construction of Isostructural Hydrogen-bonded Organic Frameworks: Limitations and Possibilities of Pore Expansion

2021 ◽  
Author(s):  
Yuto Suzuki ◽  
MARIO GUTIÉRREZ ◽  
Senri Tanaka ◽  
Eduardo Gomez Garcia ◽  
Norimitsu Tohnai ◽  
...  
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Covalent Organic Frameworks ◽  
Systematic Survey ◽  
Metal Organic ◽  
Pore Expansion ◽  
Hydrogen Bonded

Library of isostructural porous frameworks enables systematic survey to optimize the structure and functionality of porous materials. Contrary to metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), a handful of...

scholarly journals New Microporous Lanthanide Organic Frameworks. Synthesis, Structure, Luminescence, Sorption, and Catalytic Acylation of 2-Naphthol

Molecules ◽  
2020 ◽  
Vol 25 (13) ◽  
pp. 3055
Author(s):  
Dana Bejan ◽  
Lucian Gabriel Bahrin ◽  
Sergiu Shova ◽  
Narcisa Laura Marangoci ◽  
Ülkü Kökҫam-Demir ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Catalytic Activity ◽  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
X Ray ◽  
Surface Areas ◽  
Potential Applications ◽  
Metal Organic ◽  
Solvothermal Conditions

New metal-organic frameworks (MOF) with lanthanum(III), cerium(III), neodymium(III), europium(III), gadolinium(III), dysprosium(III), and holmium(III)] and the ligand precursor 1,3,5-tris(4-carboxyphenyl)-2,4,6-trimethylbenzene (H3L) were synthesized under solvothermal conditions. Single crystal x-ray analysis confirmed the formation of three-dimensional frameworks of [LnL(H2O)2]n·xDMF·yH2O for Ln = La, Ce, and Nd. From the nitrogen sorption experiments, the compounds showed permanent porosity with Brunauer-Emmett-Teller (BET) surface areas of about 400 m2/g, and thermal stability up to 500 °C. Further investigations showed that these Ln-MOFs exhibit catalytic activity, paving the way for potential applications within the field of catalysis.

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