Single-Entity Electrocatalysis at Electrode Ensembles Prepared by Template Synthesis

Nanoelectrode ensembles (NEEs), prepared by Au template synthesis, are presented as a proof-of-concept sample platform to study individual electrodeposited materials by scanning electrochemical cell microscopy (SECCM). With this platform, the non-conductive membrane support does not contribute to the electrocatalytic activity recorded at each electrode. Use of low-density template membranes results in electrodes that are isolated because initial membrane pores are typically separated by significant (microscale) distances. Electrodeposition of catalytic nanoparticles onto the electrodes of the array and observation of electrocatalytic activity are demonstrated to be suitable for correlative SECCM voltammetric mapping and electron microscopy. Suitability of NEEs for studies of surface Au oxidation, hydrazine oxidation, and hydrogen evolution (hydrogen evolution reaction, HER), and at Pt particles on NEEs (Pt-NEEs) for HER is demonstrated.

Fabrication of a High Water Flux Conductive MWCNTs/PVC Composite Membrane with Effective Electrically Enhanced Antifouling Behavior

Membrane fouling is a major issue that deteriorates the performance of membrane filtration systems. The electrically assisted membrane filtration process is proven to be effective for alleviating membrane fouling. In this study, we synthesized an electrically conductive membrane by incorporating multiwalled carbon nanotubes (MWCNTs) into polyvinyl chloride (PVC). The synthesized membranes have larger porosity than the PVC membrane (incorporating polyethylene glycol (PEG)), and thus possess much higher water flux under the same testing conditions. The initial and stable water fluxes are 2033 L/(m2·h) and 750 L/(m2·h), respectively, which are much higher than that of the pure PVC membrane. More importantly, the membrane has higher surface charge density and excellent electrical conductivity, but the surface hydrophilicity and toughness decreased with the addition of the MWCNTs. The 25 wt % MWCNTs/PVC composite membrane possesses suitable electrical conductivity of 0.128 S/m. The same membrane shows electro-enhanced antifouling performance during the antifouling test with yeast as a model foulant because the external electric field (−2 V) impulses a strong repulsion force while producing some micro bubbles to repel the foulant; thus, the membrane fouling is suppressed. In the current study, we develop a simple method to fabricate the electrically conductive membrane for application in the electrically assisted membrane filtration process.

Preparation and Characterization of MWCNTs/PVDF Conductive Membrane with Cross-Linked Polymer PVA and Study on Its Anti-Fouling Performance

Based on carboxylated multi-walled carbon nanotubes (MWCNTs-COOH), a MWCNTs/PVDF conductive membrane was prepared by a vacuum filtration cross-linking method. The surface compositions and morphology of conductive membranes were studied by X-ray photoelectron spectroscopy and high-resolution field emission scanning electron microscopy, respectively. The effects of cross-linked polymeric polyvinyl alcohol (PVA) on the conductive membrane properties such as the porosity, pore size distribution, pure water flux, conductivity, hydrophilicity, stability and antifouling properties were investigated. Results showed that the addition of PVA to the MWCNTs/PVDF conductive membrane decreased the pure water flux, porosity and the conductivity. However, the hydrophilicity of the modified MWCNTs/PVDF conductive membrane was greatly improved, and the contact angle of pure water was reduced from 70.18° to 25.48° with the addition of PVA contents from 0 wt% to 0.05 wt%. Meanwhile, the conductive membranes with higher content had a relatively higher stability. It was found that the conductive functional layer of the conductive membrane had an average mass loss rate of 1.22% in the 30 min ultrasonic oscillation experiment. The tensile intensity and break elongation ratio of the conductive membrane are improved by the addition of PVA, and the durability of the conductive membrane with PVA was superior to that without PVA added. The electric assisted anti-fouling experiments of modified conductive membrane indicated that compared with the condition without electric field, the average flux attenuation of the conductive membrane was reduced by 11.2%, and the membrane flux recovery rate reached 97.05%. Moreover, the addition of PVA could accelerate the clean of the conductive membranes.